Confinement effects on glass forming liquids probed by DMA

Many molecular glass forming liquids show a shift of the glass transition T-g to lower temperatures when the liquid is confined into mesoporous host matrices. Two contrary explanations for this effect are given in literature: First, confinement induced acceleration of the dynamics of the molecules leads to an effective downshift of T-g increasing with decreasing pore size. Second, due to thermal mismatch between the liquid and the surrounding host matrix, negative pressure develops inside the pores with decreasing temperature, which also shifts T-g to lower temperatures. Here we present dynamic mechanical analysis measurements of the glass forming liquid salol in Vycor and Gelsil with pore sizes of d=2.6, 5.0 and 7.5 nm. The dynamic complex elastic susceptibility data can be consistently described with the assumption of two relaxation processes inside the pores: A surface induced slowed down relaxation due to interaction with rough pore interfaces and a second relaxation within the core of the pores. This core relaxation time is reduced with decreasing pore size d, leading to a downshift of T-g proportional to 1/d in perfect agreement with recent differential scanning calorimetry (DSC) measurements. Thermal expansion measurements of empty and salol filled mesoporous samples revealed that the contribution of negative pressure to the downshift of T-g is small (<30%) and the main effect is due to the suppression of dynamically correlated regions of size xi when the pore size xi approaches

Towards reviving post-Olympic Athens as a cultural destination

This paper examines the effects of global change on the status and qualities of the Greek national capital, Athens, focusing on how they affect the development of cultural tourism in the city. Although Athens constituted one of the most significant destinations for Greek tourism in the past, in recent years it started to weaken. Athens is characterised by a series of problems, among them are the degradation of its environment and quality of life and traffic congestion. However, in terms of tourism development, the Olympic Games helped in re-imaging the city and upgrading its infrastructure. This study based on semi-structured interviews with top officials reveals how global change has affected Athens’ socio-cultural/economic status, identity and image. Despite the tourism policy/planning responses to global changes, Athens’ tourism continues to decline leaving unexplored potential such as its rich cultural heritage, new multicultural identity and the New Acropolis Museum. The paper suggests that cultural elements of capital cities must be multidimensional including a variety of attractions and amenities. The use of cultural heritage assets needs to be in line with global developments in order for cities to effectively leverage heritage for cultural tourism

The impacts of foot and mouth disease on a peripheral tourism area: the role and effect of crisis management.

This study reports on the consequences of endemic cattle and sheep disease (2001) on two separate areas on the tourist industry; (a) the Grampian Region of Scotland (indirectly affected) and (b) Cumbria in England (directly affected), and secondly on the effects of various crisis management strategies to alleviate the ensuing problems in both areas. Data were collected by a survey of a sample of 200 tourism orientated SME operators in Grampian and 170 businesses in Cumbria. The results show two forms of impact caused by the disease, direct and those less obvious or tangible. Direct impact was the dramatic loss of trade, most dramatically experienced by the lack of tourists visiting the areas. Indirect effects included loss of supply, change to the product offered and cuts in future investment. In the combination of these impacts, it was clear that the effects would have longevity far beyond the period of the actual crisis. Although the actual presence of the disease was geographically limited in Grampian, the consequences rippled out to affect areas that had no direct connection. In Cumbria, the effects were only slightly more severe but the response more direct and initially effective. Significantly the data also demonstrated a perception of minimal effort by the government to limit the consequences to the farming industry especially in Grampian. We conclude that the tourist industry in peripheral regions is fragile and highly vulnerable to any external shocks. However, we also note the ability of small rural firms to respond to such catastrophes and to avert the worst impacts of crisis

Breaking bad, making good: notes on a televisual tourist industry

This article explores emerging intersections between the consumption of mediated popular culture and the real and imagined topographies within which those representations are framed. Through an examination of the ‘televisual tourism’ centred around the successful TV series Breaking Bad, we scrutinise the multiple modes of sensorial and embodied travel experience enjoyed by fans of the show as they consume their way around the show’s sites, scenes, and tastes in the city of Albuquerque . This exploitation of media textuality through fan tourism is, we suggest, centred upon a carefully managed commodification of crime, criminality and transgression

‘You can never cross the same river twice’: climbers’ embodied quests for ‘original adventure’ in southern Thailand

This article presents ethnographic research into individual narratives of adventure in a small, undeveloped bay called Ton Sai in southern Thailand’s Krabi Province. Ton Sai is extremely popular with Western rock climbers and increasingly with other adventure seekers and backpackers questing for ‘authentic’ Thailand, yet is subject to almost no representation in the commercial sense. It is an example of a destination that is not on the corporate ‘radar’, yet, as will be seen, is famed, desired and produced by ‘niche’ tourists seeking very specifically valued tropical adventures. This research aims to interrogate how such a destination becomes, and remains, valued as adventurous by climbers and therefore shed some light on individual, subjective production of adventure in specific Developing World contexts. Drawing on original interview and other ethnographic data collected during winter 2012/2013, this article argues that even when third-party commercial mediators are absent, the powers of quest for authenticity and adventure are powerful enough to turn the wheels of mediation themselves. In the ‘elite circles’ in which this group manoeuvres, notions of ideal adventure space run deep and are reproduced discursively and through embodied performances in an exoticised environment that is valued for its ‘primitive timelessness’. The implications of this for locals are explored