Stability and degradation in triple cation and methyl ammonium lead iodide perovskite solar cells mediated viaAu andAg electrodes

Article states that perovskite solar cells (PSCs), particularly based on the methyl ammonium lead iodide (MAPbI3) formulation, have been of intense interest for the past decade within the photovoltaics (PV) community, but their long-term stability under operational conditions and environmental storage are still prime challenges to be overcome towards their commercialization. The authors have conducted a comprehensive analysis on the impact of the electrode collector layer, specifically Ag and Au, on the degradation mechanism associated with the MAPbI3 and a triple cation absorber. The authors hypothesize the mechanism of degradation, arising from the Ag interaction with the absorber through the formation of AgI in the PSCs, leads to corrosion of the perovskite absorber, as opposed to the benign AuI when Au electrodes are used in the solar cell stack