Bathymetry and Sediment Geochemistry of Lake Hazen (Quttinirpaaq National Park, Ellesmere Island, Nunavut)

Arctic lakes can provide a long-term perspective on environmental change, including trends in long-range atmospheric transport and deposition of contaminants, inferred from studies of sediment cores. In this study, we conducted the first detailed bathymetric survey of Lake Hazen (Quttinirpaaq National Park, Ellesmere Island, Nunavut), the world’s largest lake north of 74˚ latitude. With these data we were able to determine optimal locations for sediment coring and to collect and analyze profundal sediment cores. A bathymetric map of Lake Hazen was developed on the basis of 362 spot soundings obtained with GPS-coupled sounding equipment placed directly on the ice combined with additional soundings from a small boat. The deepest point in the lake (81˚49.5ʹ N; 70˚42.8ʹ W) was found to be 267 m deep. The lake volume was estimated to be 5.14 × 1010 m3, about 10% larger than previous estimates. Using estimates of the discharge of Lake Hazen from the Water Survey of Canada, we estimated the water retention time to be 89 years. Sediment cores were dated using 210Pb and 137Cs. Sedimentation rates at the deep point, estimated using the Constant Rate of Supply model for excess 210Pb, were relatively high (1260 g m-2yr-1) in the period 2005 – 1963 and lower (650 ± 100 g m-2yr-1) in horizons dated to 1950 – 1880. The majority of elements measured in sediment (24 of 29 consistently above detection limits), as well as organic carbon, showed less than 20% variation in concentrations in the top 10 cm (compacted depth), which represent deposition over approximately 140 years. Geochemical characteristics of the sediment suggest that erosional inputs from annual glacial melting are the major source of essentially all elements and that anthropogenic inputs from long-range transport of toxic metals such as mercury and lead are very low.Les lacs de l’Arctique peuvent fournir une perspective à long terme en matière de changement environnemental, notamment en ce qui a trait aux tendances relatives au transport atmosphérique et au dépôt de contaminants sur de longues périodes, tendances inférées à partir d’études de carottes de sédiments. Dans le cadre de la présente étude, nous avons effectué le premier levé bathymétrique détaillé du lac Hazen (parc national Quttinirpaaq, île d’Ellesmere, Nunavut), le plus grand lac de la planète situé au nord de 74˚ de latitude. Grâce aux données prélevées, nous avons réussi à déterminer les meilleurs emplacements pour le prélèvement de carottes de sédiments de même que pour la collecte et l’analyse de carottes de sédiments profonds. Une carte bathymétrique du lac Hazen a été dressée en fonction de 362 sondages obtenus au moyen de matériel d’appareils phoniques dotés de GPS placés directement sur la glace et supplémentés par des sondages recueillis à partir d’un petit bateau. Le point le plus profond du lac (81˚49,5ʹ N; 70˚42,8ʹ O) a été trouvé à 267 m de profondeur. Le volume du lac a été évalué à 5,14 × 1010 m3, soit 10 % de plus que les évaluations précédentes. À l’aide d’estimations du déversement du lac Hazen obtenues auprès de la Division des relevés hydrologiques du Canada, nous avons évalué que la durée de rétention de l’eau était de 89 ans. La datation des carottes de sédiments a été faite à l’aide de 210Pb et de 137Cs. Les taux de sédimentation au point profond, estimés en s’appuyant sur le modèle CRS (Constant Rate of Supply) pour l’excédent 210Pb, étaient relativement élevés (1260 g m-2an-1) pour la période allant de 2005 à 1963, et moins élevés (650 ± 100 g m-2an-1) pour la période de 1950 à 1880. La majorité des éléments mesurés dans les sédiments (24 sur 29 étaient uniformément au-dessus des seuils de détection) ainsi que dans le carbone organique ont produit une variation de concentrations de moins de 20 % dans les 10 cm supérieurs (profondeur compactée), ce qui représente des dépôts s’échelonnant sur environ 140 ans. Les caractéristiques géochimiques des sédiments laissent présumer que les matières d’érosion découlant de la fonte glaciaire annuelle constituent la source principale de sensiblement tous les éléments, et que les matières anthropiques provenant du transport à grande distance de métaux toxiques, tels que le mercure et le plomb, sont très faibles

Adsorption and reaction of CO on (Pd–)Al2O3 and (Pd–)ZrO2: vibrational spectroscopy of carbonate formation

γ-Alumina is widely used as an oxide support in catalysis, and palladium nanoparticles supported by alumina represent one of the most frequently used dispersed metals. The surface sites of the catalysts are often probed via FTIR spectroscopy upon CO adsorption, which may result in the formation of surface carbonate species. We have examined this process in detail utilizing FTIR to monitor carbonate formation on γ-alumina and zirconia upon exposure to isotopically labelled and unlabelled CO and CO2. The same was carried out for well-defined Pd nanoparticles supported on Al2O3 or ZrO2. A water gas shift reaction of CO with surface hydroxyls was detected, which requires surface defect sites and adjacent OH groups. Furthermore, we have studied the effect of Cl synthesis residues, leading to strongly reduced carbonate formation and changes in the OH region (isolated OH groups were partly replaced or were even absent). To corroborate this finding, samples were deliberately poisoned with Cl to an extent comparable to that of synthesis residues, as confirmed by Auger electron spectroscopy. For catalysts prepared from Cl-containing precursors a new CO band at 2164 cm−1 was observed in the carbonyl region, which was ascribed to Pd interacting with Cl. Finally, the FTIR measurements were complemented by quantification of the amount of carbonates formed via chemisorption, which provides a tool to determine the concentration of reactive defect sites on the alumina surface

"Safe" Coulomb Excitation of 30Mg

We report on the first radioactive beam experiment performed at the recently commissioned REX-ISOLDE facility at CERN in conjunction with the highly efficient gamma spectrometer MINIBALL. Using 30Mg ions accelerated to an energy of 2.25 MeV/u together with a thin nat-Ni target, Coulomb excitation of the first excited 2+ states of the projectile and target nuclei well below the Coulomb barrier was observed. From the measured relative de-excitation gamma ray yields the B(E2; 0+ -> 2+) value of 30Mg was determined to be 241(31) e2fm4. Our result is lower than values obtained at projectile fragmentation facilities using the intermediate-energy Coulomb excitation method, and confirms the theoretical conjecture that the neutron-rich magnesium isotope 30Mg lies still outside the ``island of inversion''

Lifetime measurements in 80^{80}Br and a new region for observation of chiral electromagnetic selection rules

Level lifetimes for the candidate chiral doublet bands of 80Br were extracted by means of the Doppler-shift attenuation method. The absolute transition probabilities derived from the lifetimes agree well with the M1 and E2 chiral electromagnetic selection rules, and are well reproduced by the triaxial particle rotor model calculations. Such good agreements among the experimental data, selection rules of chiral doublet bands and theoretical calculations are rare and outstanding in researches of nuclear chirality. Besides odd-odd Cs isotopes, odd-odd Br isotopes in the A≈ 80 mass region represent another territory that exhibits the ideal selection rules expected for chiral doublet bands

Prevalence and molecular characteristics of methicillin-resistant Staphylococcus aureus (MRSA) among pigs on German farms and import of livestock-related MRSA into hospitals

The aim of this study was to evaluate the prevalence and molecular characteristics of methicillin-resistant Staphylococcus aureus (MRSA) among pigs and estimate the impact of this animal reservoir on human healthcare. Nasal swabs were derived from 1,600 pigs at 40 German farms. The MRSA were characterized using S. aureus protein A (spa) typing, multilocus sequence typing (MLST) and detection of toxin genes. In a retrospective case control study, we compared risk factors for the carriage of MRSA between patients carrying spa types found among regional pigs and patients with other MRSA molecular types. Pigs carrying MRSA were identified on 70% of the farms (spa types t011, t034, t108, t1451 and t2510, all associated with MLST sequence type ST398). Contact to pigs and cattle were independent risk factors for the carriage of these spa types in patients at hospital admission. Our results indicate that livestock represents a relevant reservoir for the import of MRSA into regional German hospitals

Single-Nucleotide Polymorphism Genotyping Identifies a Locally Endemic Clone of Methicillin-Resistant Staphylococcus aureus

We developed, tested, and applied a TaqMan real-time PCR assay for interrogation of three single-nucleotide polymorphisms that differentiate a clade (termed ‘t003-X’) within the radiation of methicillin-resistant Staphylococcus aureus (MRSA) ST225. The TaqMan assay achieved 98% typeability and results were fully concordant with DNA sequencing. By applying this assay to 305 ST225 isolates from an international collection, we demonstrate that clade t003-X is endemic in a single acute-care hospital in Germany at least since 2006, where it has caused a substantial proportion of infections. The strain was also detected in another hospital located 16 kilometers away. Strikingly, however, clade t003-X was not found in 62 other hospitals throughout Germany nor among isolates from other countries, and, hence, displayed a very restricted geographical distribution. Consequently, our results show that SNP-typing may be useful to identify and track MRSA clones that are specific to individual healthcare institutions. In contrast, the spatial dissemination pattern observed here had not been resolved by other typing procedures, including multilocus sequence typing (MLST), spa typing, DNA macrorestriction, and multilocus variable-number tandem repeat analysis (MLVA)

Population Structure of Staphylococcus aureus from Remote African Babongo Pygmies

Staphylococcus aureus is a bacterium that colonizes humans worldwide. The anterior nares are its main ecological niche. Carriers of S. aureus are at a higher risk of developing invasive infections. Few reports indicated a different clonal structure and profile of virulence factors in S. aureus isolates from Sub-Saharan Africa. As there are no data about isolates from remote indigenous African populations, we conducted a cross-sectional survey of S. aureus nasal carriage in Gabonese Babongo Pygmies. The isolates were characterized regarding their susceptibility to antibiotic agents, possession of virulence factors and clonal lineage. While similar carriage rates were found in populations of industrialized countries, isolates that encode the genes for the Panton-Valentine leukocidin (PVL) were clearly more prevalent than in European countries. Of interest, many methicillin-susceptible S. aureus isolates from Babongo Pygmies showed the same genetic background as pandemic methicillin-resistant S. aureus (MRSA) clones. We advocate a surveillance of S. aureus in neglected African populations to control the development of resistance to antibiotic drugs with particular respect to MRSA and to assess the impact of the high prevalence of PVL-positive isolates