Earth’s Outgoing Longwave Radiation Variability Prior to M ≥6.0 Earthquakes in the Taiwan Area During 2009–2019

This paper proposes an analysis method, using the National Oceanic and Atmospheric Administration satellite data, to trace variations in outgoing longwave radiation (OLR) for finding the precursors of earthquakes. The significance of these observations is investigated using data sets of recent M ≥6.0 earthquakes around the Taiwan area from 2009 to 2019. We suggest that the precursory signal could be an EIndex anomaly (EA) in the form of substantial thermal releases distributed near the epicenter. The consecutive appearances of OLR EAs are observed as precursors 2–15 days before significant earthquakes, and we refer to this as a pre-earthquake OLR EIndex anomaly (POEA). We interpret these thermal sources as possibly originating from electromagnetics together with gas emissions associated with pre-seismic processes. This study highlights the potential of OLR anomalous changes in earthquake precursor studies, at least in the Taiwan region

Catalytic reduction of NO on copper/MCM-41 studied by in situ EXAFS and XANES

Abstract Speciation of copper in the channels of MCM-41 during reduction of NO with CO at 473-773 K was studied by in situ extended X-ray absorption fine structural (EXAFS) and X-ray absorption near edge structural (XANES) spectroscopies in the present work. The component fitted (in situ) XANES spectra of the catalyst showed that about 72% of metallic copper (Cu(0)) in MCM-41 was oxidized to higher oxidation state coppers (Cu(II) (46%) and Cu(I) (26%)) during the NO reduction process (at 473 K). By EXAFS, we also found that in the NO reduction process, oxygen was inserted into the metallic copper matrix and led to a formation of the copper oxide species with a Cu-O bond distance of 1.93 A A which was greater than that of the model compound Cu 2 O (typically 1.86 A A). At 573-673 K, mainly Cu(II) was found in the channels of MCM-41. Nevertheless, at a higher temperature (e.g., 773 K), about 61% Cu(I), 31% Cu(II), and 8% Cu(O) with averaged Cu-Cu and Cu-O bond distances of 3.04 and 1.88 A A, respectively were observed, that might account for the high selectivity-to-decomposition (S/D) ratios for yields of N 2 and CO 2 in the catalytic reduction of NO with CO

Catalytic reduction of NO on copper/MCM-41 studied by in situ EXAFS and XANES

Abstract Speciation of copper in the channels of MCM-41 during reduction of NO with CO at 473-773 K was studied by in situ extended X-ray absorption fine structural (EXAFS) and X-ray absorption near edge structural (XANES) spectroscopies in the present work. The component fitted (in situ) XANES spectra of the catalyst showed that about 72% of metallic copper (Cu(0)) in MCM-41 was oxidized to higher oxidation state coppers (Cu(II) (46%) and Cu(I) (26%)) during the NO reduction process (at 473 K). By EXAFS, we also found that in the NO reduction process, oxygen was inserted into the metallic copper matrix and led to a formation of the copper oxide species with a Cu-O bond distance of 1.93 A A which was greater than that of the model compound Cu 2 O (typically 1.86 A A). At 573-673 K, mainly Cu(II) was found in the channels of MCM-41. Nevertheless, at a higher temperature (e.g., 773 K), about 61% Cu(I), 31% Cu(II), and 8% Cu(O) with averaged Cu-Cu and Cu-O bond distances of 3.04 and 1.88 A A, respectively were observed, that might account for the high selectivity-to-decomposition (S/D) ratios for yields of N 2 and CO 2 in the catalytic reduction of NO with CO

KCNN2 polymorphisms and cardiac tachyarrhythmias

Potassium calcium-activated channel subfamily N member 2 (KCNN2) encodes an integral membrane protein that forms small-conductance calcium-activated potassium (SK) channels. Recent studies in animal models show that SK channels are important in atrial and ventricular repolarization and arrhythmogenesis. However, the importance of SK channels in human arrhythmia remains unclear. The purpose of the present study was to test the association between genetic polymorphism of the SK2 channel and the occurrence of cardiac tachyarrhythmias in humans. We enrolled 327 Han Chinese, including 72 with clinically significant ventricular tachyarrhythmias (VTa) who had a history of aborted sudden cardiac death (SCD) or unexplained syncope, 98 with a history of atrial fibrillation (AF), and 144 normal controls. We genotyped 12 representative tag single nucleotide polymorphisms (SNPs) across a 141-kb genetic region containing the KCNN2 gene; these captured the full haplotype information. The rs13184658 and rs10076582 variants of KCNN2 were associated with VTa in both the additive and dominant models (odds ratio [OR] 2.89, 95% confidence interval [CI] = 1.505-5.545, P = 0.001; and OR 2.55, 95% CI = 1.428-4.566, P = 0.002, respectively). After adjustment for potential risk factors, the association remained significant. The population attributable risks of these 2 variants of VTa were 17.3% and 10.6%, respectively. One variant (rs13184658) showed weak but significant association with AF in a dominant model (OR 1.91, CI = 1.025-3.570], P = 0.042). There was a significant association between the KCNN2 variants and clinically significant VTa. These findings suggest an association between KCNN2 and VTa; it also appears that KCNN2 variants may be adjunctive markers for risk stratification in patients susceptible to SCD

Aluminate red phosphor in light-emitting diodes : theoretical calculations, charge varieties and high-pressure luminescence analysis

This work was supported by the Ministry of Science and Technology of Taiwan (Contract Nos. MOST 104-2113-M- 002-012-MY3 and MOST 104-2923-M-002-007-MY3). This research was also supported by National Centre for Re- search and Development, Poland (Grant No. PL- TW2/8/2015).Searching for a non-rare earth-based oxide red-emitting phosphor is crucial for phosphor-converted light- emitting diodes (LEDs). In this study, we optimized a blue and UV-light excited Sr4Al14O25:Mn phosphor exhibiting red emission peaked at ~653 nm, which was successfully synthesized by solid-state reaction. The crystal structure, micromorphology, and luminescent properties of Sr4Al14O25:Mn phosphors were characterized by X-ray Rietveld refinement, high-resolution transmission electron microscopy, and photoluminescence spectra. The band gap and electronic structure of Sr4Al14O25 were analyzed by density functional theory calculation using the hybrid exchange- correlation functional. The crystal field environment effect of Al sites from introducing activator Mn ions was investigated with the aid of Raman 27Al nuclear magnetic resonance spectra and electron spin resonance. The pressure dependent on the luminescent properties and decay time of this compound were presented. The tricolor display spectrum by combining blue InGaN chips, commercial β-SiAlON:Eu2+ green phosphor, and Sr4Al14O25:Mn red phosphor were evaluated for commercial applications: using the present Sr4Al14O25:Mn red phosphor converted LED as backlighting source.PostprintPeer reviewe

Dealloyed Pt_(2)Os nanoparticles for enhanced oxygen reduction reaction in acidic electrolytes

Carbon-supported Pt2Os (Pt_(2)Os/C) nanoparticles in 3.55 nm sizes are synthesized from a wet chemical reflux process. Subsequently, the Pt_(2)Os/C undergoes a dealloying treatment in which multiple cyclic voltammetric scans are imposed to dissolve the Os atoms selectively from the surface of the Pt_(2)Os nanoparticles. X-ray diffraction signals from the dealloyed sample (DA–Pt_(2)Os/C) indicate a fcc phase and composition analysis suggests Pt4Os. Line scans from the scanning transmission electron microscope confirm that the surface of Pt_(4)Os is depleted with the Os atoms. This agrees with our quantum mechanics (Density Funtional theory) calculations, which predict for the Pt_(3)Os composition that the surface skin layer is pure Pt. The DA–Pt_(2)Os/C shows impressive electrocatalytic behaviors (0.29 mA μgPt^(−1) in mass activity and 1.03 mA cmPt^(−2) in specific activity) for the oxygen reduction reaction (ORR) in oxygen-saturated 0.1 M aqueous HClO_4 solution, as compared to those of commercially available Pt/C and as-synthesized Pt_(2)Os/C. In stability test, the DA–Pt_(2)Os/C demonstrates a better retention of ORR activities and a smaller loss of electrochemical active surface area. We verify experimentally that a four-electron step is responsible for the ORR process occurring on the DA–Pt_(2)Os/C

Surface Electron-Hole Rich Species Active in the Electrocatalytic Water Oxidation.

Iridium and ruthenium and their oxides/hydroxides are the best candidates for the oxygen evolution reaction under harsh acidic conditions owing to the low overpotentials observed for Ru- and Ir-based anodes and the high corrosion resistance of Ir-oxides. Herein, by means of cutting edge operando surface and bulk sensitive X-ray spectroscopy techniques, specifically designed electrode nanofabrication and ab initio DFT calculations, we were able to reveal the electronic structure of the active IrOx centers (i.e., oxidation state) during electrocatalytic oxidation of water in the surface and bulk of high-performance Ir-based catalysts. We found the oxygen evolution reaction is controlled by the formation of empty Ir 5d states in the surface ascribed to the formation of formally IrV species leading to the appearance of electron-deficient oxygen species bound to single iridium atoms (μ1-O and μ1-OH) that are responsible for water activation and oxidation. Oxygen bound to three iridium centers (μ3-O) remains the dominant species in the bulk but do not participate directly in the electrocatalytic reaction, suggesting bulk oxidation is limited. In addition a high coverage of a μ1-OO (peroxo) species during the OER is excluded. Moreover, we provide the first photoelectron spectroscopic evidence in bulk electrolyte that the higher surface-to-bulk ratio in thinner electrodes enhances the material usage involving the precipitation of a significant part of the electrode surface and near-surface active species