Optical Absorption Spectra of Ag11 Isomers by First-Principles Theoretical Spectroscopy with Time-dependent Density Functional Theory

The optical absorption spectrum of the three most stable isomers of the Ag11 system was calculated using the time-dependent density functional theory, with the generalized gradient approximation for the exchange and correlation potential, and a relativistic pseudopotential parametrization for the modelling of the ion-electron interaction. The computational scheme is based on a real space code, where the photoabsorption spectrum is calculated by using the formalism developed by Casida. The significantly different spectra of the three isomers permit the identification of the ground-state configuration predominantly present in the laboratory beams in base to a comparison between the calculated photoabsorption spectrum of the most stable configuration of Ag11 and the measured spectra of medium-size silver clusters trapped in noble gas Ar and Ne matrices at different temperatures. This assignment is confirmed by the fact that this isomer has the lowest calculated energy.Comment: 6 pages, 3 color figures, submitted to Chem. Phys. Let

The use of ecosystem-based adaptation practices by smallholder farmers in Central America

There is growing interest in promoting the use of Ecosystem-based Adaptation (EbA) practices to help smallholder farmers adapt to climate change, however there is limited information on how commonly these practices are used by smallholder farmers and what factors influence their use. Using participatory mapping and field surveys, we examined the prevalence and characteristics of EbA practices on 300 smallholder coffee and maize farmers in six landscapes in Central America and explored the socioeconomic and biophysical factors associated with their use. The prevalence of individual EbA practices varied across smallholder farms. Common EbA practices included live fences, home gardens, shade trees in coffee plantations, and dispersed trees in maize fields. We found a mean of 3.8 EbA practices per farm. Factors that were correlated with the total number of EbA practices on farms included the mean area of coffee plantations, farmer age, farmer experience, the farm type and the landscape in which farms were located. Factors associated with the presence or characteristics of individual EbA practices included the size of coffee plantations, farmer experience, farmer education, land tenure, landscape and farm type. Our analysis suggests that many smallholder farmers in Central America are already using certain EbA practices, but there is still scope for greater implementation. Policy makers, donors and technicians can encourage the broader use of EbA by smallholder farmers by facilitating farmer-to-farmer exchanges to share knowledge on EbA implementation, assessing the effectiveness of EbA practices in delivering adaptation benefits, and tailoring EbA policies and programs for smallholder farmers in different socioeconomic and biophysical contexts. (Résumé d'auteur

Properties of aluminium nodules foamed with concentrated solar energy

Commercial aluminium foam filled structures and sandwich panels are available for structural applications. As alternative to these materials, small granular foamed pieces are proposed to fill structures as well as sandwich panels. On the present work, foam precursors are obtained by Powder Metallurgy (PM) route, using natural calcium carbonate as foaming agent instead of titanium hydride. Extruded precursor bars were cut into small pieces (around 4.5 mm long and 5mm in diameter). Foaming treatment was carried out on two different ways: electrical preheated furnace and by solar furnace. Foamed nodules presented a low cell size, density e.g. 0.67 g/cm3 to 0.88 g/cm3 and a height/diameter ratio between 0.72 and 0.84 as a function of precursor size. These properties depend on the foaming particle size, foaming cycle and precursor dimensions. Carbonate precursors are easily foamed by concentrated solar energy, due to the lower risk of cell collapse than with hydride precursors, resulting from cell stabilization by oxide skin formation into cells and a low degree of foamed nodules bonding

Tratamiento térmico de espumación de precursores de aluminio-silicio en horno solar de lecho fluidificado

La fabricación de espumas de aluminio de poro cerrado mediante técnicas pulvimetalúrgias, conlleva una etapa de calentamiento del material (precursor) hasta su fusión y la formación de la espuma. En el presente trabajo, como continuación de los trabajos con energía solar concentrada aplicada directamente a la espumación de precursores Al10Si+0.8%TiH2, se han sometido al tratamiento de espumación en un horno solar de lecho fluidificado con el objetivo de obtener un tratamiento en volumen más homogéneo y uniforme, de manera que se puedan determinar la viabilidad del tratamiento, el procedimiento y los tiempos de residencia necesarios para llevar a cabo este proceso de manera discontinua o preindustrial. Así se han obtenido espumas 0,68 g/cm3 de densidad sin colapso de poros o decantación de aluminio, si bien como consecuencia del calentamiento preferencial por la base del molde, las espumas obtenidas presentan un tamaño de poro ligeramente más grande en la base de la espuma

Associations between olfactory pathway gene methylation marks, obesity features and dietary intakes

Abstract Background Olfaction is an important sense influencing food preferences, appetite, and eating behaviors. This hypothesis-driven study aimed to assess associations between olfactory pathway gene methylation signatures, obesity features, and dietary intakes. Methods A nutriepigenomic analysis was conducted in 474 adults from the Methyl Epigenome Network Association (MENA) project. Anthropometric measurements, clinical data, and serum metabolic profiles of the study population were obtained from structured databases of the MENA cohorts. Habitual dietary intake was assessed using a validated semiquantitative food frequency questionnaire. DNA methylation was measured in circulating white blood cells by microarray (Infinium Human Methylation 450 K BeadChips). FDR values (p < 0.0001) were used to select those CpGs that showed the best correlation with body mass index (BMI) and waist circumference (WC). Pathway analyses involving the characterization of genes involved in the olfactory transduction system were performed using KEGG and pathDIP reference databases. Results Overall, 15 CpG sites at olfactory pathway genes were associated with BMI (p < 0.0001) and WC (p < 0.0001) after adjustments for potential confounding factors. Together, methylation levels at the15 CpG sites accounted for 22% and 20% of the variability in BMI and WC (r 2 = 0.219, p < 0.001, and r 2 = 0.204, p < 0.001, respectively). These genes encompassed olfactory receptors (OR4D2, OR51A7, OR2T34, and OR2Y1) and several downstream signaling molecules (SLC8A1, ANO2, PDE2A, CALML3, GNG7, CALML6, PRKG1, and CAMK2D), which significantly regulated odor detection and signal transduction processes within the complete olfactory cascade, as revealed by pathway enrichment analyses (p = 1.94 × 10–10). Moreover, OR4D2 and OR2Y1 gene methylation patterns strongly correlated with daily intakes of total energy (p < 0.0001), carbohydrates (p < 0.0001), protein (p < 0.0001), and fat (p < 0.0001). Conclusions The results of this study suggest novel relationships between olfactory pathway gene methylation signatures, obesity indices, and dietary intakes

Induced Superconductivity in Hybrid Au/YBa2Cu3O7-x Electrodes on Vicinal Substrates

Superconducting electrodes are an integral part of hybrid Josephson junctions used in many applications including quantum technologies. We report on the fabrication and characterization of superconducting hybrid Au/YBa2Cu3O7-x (YBCO) electrodes on vicinal substrates. In these structures, superconducting CuO2-planes face the gold film, resulting in a higher value and smaller variation of the induced energy gap compared to the conventional Au/YBCO electrodes based on films with the c-axis normal to the substrate surface. Using scanning tunneling microscopy, we observe an energy gap of about 10-17 meV at the surface of the 15- nm-thick gold layer deposited in situ atop the YBCO film. To study the origin of this gap, we fabricate nanoconstrictions from the Au/YBCO heterostructure and measure their electrical transport characteristics. The conductance of the nanoconstrictions shows a series of dips due to multiple Andreev reflections in YBCO and gold providing clear evidence of the superconducting nature of the gap in gold. We consider the Au/YBCO electrodes to be a versatile platform for hybrid Josephson devices with a high operating temperature

Hacer es pensar: el aprendizaje a través del inventariado y el dibujo del patrimonio arquitectónico

Las materias de la Composición Arquitectónica (Historia, Teoría, Crítica y Patrimonio de Arquitectura), por sus fuertes dosis humanísticas, parece que se nutran, fundamentalmente, de textos escritos y reflexiones teóricas. Sin embargo, todas estas fuentes hermenéuticas se refieren, en primera y última instancia, a la realidad, a los hechos que fueron o son: ciudades y arquitecturas. Así pues, los contenidos docentes que abordan las teorías de intervención en el patrimonio arquitectónico se sustentan sobre la base de la existencia de inventarios y de textos teóricos. ¿Cómo podemos ampliar las bases de este conocimiento y verificar el aprendizaje de los principios que rigen los criterios de actuación sobre el patrimonio? En atención a esta reflexión y a la máxima de que “Hacer es Pensar”, se propone redirigir la asignatura de Composición Arquitectónica 6 (Grado de Arquitectura) hacia las labores de investigación mediante los trabajos de campo de inventariado de arquitecturas, su documentación gráfica y cartográfica (levantamientos) y la aplicación al mismo de propuestas de intervención individuales y de conjunto. Aprender supondrá investigar ampliando los inventarios con trabajos de campo y tomando estos documentos gráficos como punto de partida de los proyectos de intervención en el patrimonio urbano y arquitectónico