598 research outputs found
Superconductivity in a Molecular Metal Cluster Compound
Compelling evidence for band-type conductivity and even bulk
superconductivity below K has been found in
Ga-NMR experiments in crystalline ordered, giant Ga
cluster-compounds. This material appears to represent the first realization of
a theoretical model proposed by Friedel in 1992 for superconductivity in
ordered arrays of weakly coupled, identical metal nanoparticles.Comment: 5 pages, 4 figure
Magnetic dipolar ordering and relaxation in the high-spin molecular cluster compound Mn6
Few examples of magnetic systems displaying a transition to pure dipolar
magnetic order are known to date, and single-molecule magnets can provide an
interesting example. The molecular cluster spins and thus their dipolar
interaction energy can be quite high, leading to reasonably accessible ordering
temperatures, provided the crystal field anisotropy is sufficiently small. This
condition can be met for molecular clusters of sufficiently high symmetry, as
for the Mn6 compound studied here. Magnetic specific heat and susceptibility
experiments show a transition to ferromagnetic dipolar order at T_{c} = 0.16 K.
Classical Monte-Carlo calculations indeed predict ferromagnetic ordering and
account for the correct value of T_{c}. In high magnetic fields we detected the
contribution of the ^{55}Mn nuclei to the specific heat, and the characteristic
timescale of nuclear relaxation. This was compared with results obtained
directly from pulse-NMR experiments. The data are in good mutual agreement and
can be well described by the theory for magnetic relaxation in highly polarized
paramagnetic crystals and for dynamic nuclear polarization, which we
extensively review. The experiments provide an interesting comparison with the
recently investigated nuclear spin dynamics in the anisotropic single molecule
magnet Mn12-ac.Comment: 19 pages, 11 eps figures. Contains extensive discussions on dipolar
ordering, specific heat and nuclear relaxation in molecular magnet
An automated and versatile ultra-low temperature SQUID magnetometer
We present the design and construction of a SQUID-based magnetometer for
operation down to temperatures T = 10 mK, while retaining the compatibility
with the sample holders typically used in commercial SQUID magnetometers. The
system is based on a dc-SQUID coupled to a second-order gradiometer. The sample
is placed inside the plastic mixing chamber of a dilution refrigerator and is
thermalized directly by the 3He flow. The movement though the pickup coils is
obtained by lifting the whole dilution refrigerator insert. A home-developed
software provides full automation and an easy user interface.Comment: RevTex, 10 pages, 10 eps figures. High-resolution figures available
upon reques
Field induced long-range-ordering in an S=1 quasi-one-dimensional Heisenberg antiferromagnet
We have measured the heat capacity and magnetization of the spin one
one-dimensional Heisenberg antiferromagnet NDMAP and constructed a magnetic
field versus temperature phase diagram. We found a field induced long-range
magnetic ordering. We have been successful in explaining the phase diagram
theoretically.Comment: 6 pages, 18 figure
Magnetic and thermal properties of 4f-3d ladder-type molecular compounds
We report on the low-temperature magnetic susceptibilities and specific heats
of the isostructural spin-ladder molecular complexes L[M(opba)]_{3\cdot
xDMSOHO, hereafter abbreviated with LM (where L =
La, Gd, Tb, Dy, Ho and M = Cu, Zn). The results show that the Cu containing
complexes (with the exception of LaCu) undergo long range magnetic
order at temperatures below 2 K, and that for GdCu this ordering is
ferromagnetic, whereas for TbCu and DyCu it is probably
antiferromagnetic. The susceptibilities and specific heats of TbCu
and DyCu above have been explained by means of a model
taking into account nearest as well as next-nearest neighbor magnetic
interactions. We show that the intraladder L--Cu interaction is the predominant
one and that it is ferromagnetic for L = Gd, Tb and Dy. For the cases of Tb, Dy
and Ho containing complexes, strong crystal field effects on the magnetic and
thermal properties have to be taken into account. The magnetic coupling between
the (ferromagnetic) ladders is found to be very weak and is probably of dipolar
origin.Comment: 13 pages, 15 figures, submitted to Phys. Rev.
New quantum phase transitions in the two-dimensional J1-J2 model
We analyze the phase diagram of the frustrated Heisenberg antiferromagnet,
the J1-J2 model, in two dimensions. Two quantum phase transitions in the model
are already known: the second order transition from the Neel state to the spin
liquid state at (J_2/J_1)_{c2}=0.38, and the first order transition from the
spin liquid state to the collinear state at (J_2/J_1)_{c4}=0.60. We have found
evidence for two new second order phase transitions: the transition from the
spin columnar dimerized state to the state with plaquette type modulation at
(J_2/J_1)_{c3}=0.50(2), and the transition from the simple Neel state to the
Neel state with spin columnar dimerization at (J_2/J_1)_{c1}=0.34(4). We also
present an independent calculation of (J_2/J_1)_{c2}=0.38 using a new approach.Comment: 3 pages, 5 figures; added referenc
Suppression of Dimer Correlations in the Two-Dimensional - Heisenberg Model: an Exact Diagonalization Study
We present an exact diagonalization study of the ground state of the
spin-half model. Dimer correlation functions and the susceptibility
associated to the breaking of the translational invariance are calculated for
the and the clusters. These results -- especially when
compared to the one dimensional case, where the occurrence of a dimerized phase
for large enough frustration is well established -- suggest either a
homogeneous spin liquid or, possibly, a dimerized state with a rather small
order parameter
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