Recent developments in fire retardation and fire protection of fibre-reinforced composites

This article reviews recent work on fire retardation and fire protection of fibre-reinforced composites carried out in the laboratories of the Fire Materials Group at the University of Bolton. This work has concentrated mainly on the effects of fire-retardant additives and coatings on the fire performance of unsaturated polyester, vinyl ester and epoxy resin composites reinforced with glass fibres

Beyond the Property Tax: Local Government Revenue Diversification

Local governments in the U.S. rely less on the property tax than they have historically. This long-term trend has been accompanied by important shifts in the composition of local revenues. While the property tax still serves as one primary source of local government revenue, increasingly other sources are used to pay for local government. This paper first examines that trend, the forces behind it, and its regional impact. We then explore trends in three central states- Iowa, Nebraska, and Arkansas -- that have experienced substantial revenue shifts in recent years. A concluding section discusses the options for the future

Devolution, Fiscal Federalism, and Changing Patterns of Municipal Revenues: The Mismatch between Theory and Reality

Theories of fiscal federalism, such as those propounded by Musgrave, Tiebout, and Brennan and Buchanan, prescribe assignment of revenue sources among federal, state, and local governments. In this article, we demonstrate that the recent diversification of municipal revenue sources in response to devolutionary forces does not follow the expectations of the fiscal federalism theories. Our analysis suggests that the use of an institutional approach to the study of fiscal federalism would help to reduce the mismatch between theory and reality

Organophosphorus and organo-inorganic hybrid fire retardant coatings for polymers

Thin coatings of crosslinked poly(vinylphosphonic acid) display good adhesion and excellent fire-retardant barrier properties when applied to the surfaces of a typical thermoplastic, such as poly(methyl methacrylate), but perform relatively poorly in water-soak tests. Water-soak test performance can be significantly improved however by various hydrophobic modifications without detriment to fire performance

Fire-resistant flax - reinforced polypropylene / polylactic acid composites with optimised fire and mechanical performances

Fabrics from commingled natural (flax) –thermoplastic (polypropylene (PP) / poly lactic acid (PLA) polymeric fibres were fire retarded with an oragnophosphonate flame retardant (FR). The fire retarded flax/PP and flax/PLA fabrics were melt pressed to prepare respective thermoplastic composites. The effect of FR concentration on the fire and mechanical properties of composites were studied and the results analysed in terms of concentration of FR elements in the composites. While the UL-94 test was used as a benchmark to achieve a V-0 rating, cone calorimetric parameters were used for in-depth analysis of fire performance. The results show that flax/PP and flax/PLA composites require a minimum 0.9 and 0.6 % phosphorus (P), respectively to achieve a V-0 rating in the UL-94 test. Mechanical properties, evaluated in tensile and flexural modes are however slightly impaired, most probably due to the acidity of the FR solution (pH = 3.2). In order to improve the mechanical properties, a buffer solution was used to change the pH to 6.0, which while having a minimal effect on mechanical properties of flax/PP, significantly reduced those of flax/PLA, and increased flammability of both composites and hence overall showed no benefit

Unintended and accidental medical radiation exposures in radiology: guidelines on investigation and prevention

This paper sets out guidelines for managing radiation exposure incidents involving patients in diagnostic and interventional radiology. The work is based on collation of experiences from representatives of international and national organizations for radiologists, medical physicists, radiographers, regulators, and equipment manufacturers, derived from an International Atomic Energy Agency Technical Meeting. More serious overexposures can result in skin doses high enough to produce tissue reactions, in interventional procedures and computed tomography, most notably from perfusion studies. A major factor involved has been deficiencies in training of staff in operation of equipment and optimization techniques. The use of checklists and time outs before procedures commence, and dose alerts when critical levels are reached during procedures can provide safeguards to reduce risks of these effects occurring. However, unintended and accidental overexposures resulting in relatively small additional doses can take place in any diagnostic or interventional X-ray procedure and it is important to learn from errors that occur, as these may lead to increased risks of stochastic effects. Such events may involve the wrong examinations, procedural errors, or equipment faults. Guidance is given on prevention, investigation and dose calculation for radiology exposure incidents within healthcare facilities. Responsibilities should be clearly set out in formal policies, and procedures should be in place to ensure that root causes are identified and deficiencies addressed. When an overexposure of a patient or an unintended exposure of a foetus occurs, the foetal, organ, skin and/or effective dose may be estimated from exposure data. When doses are very low, generic values for the examination may be sufficient, but a full assessment of doses to all exposed organs and tissues may sometimes be required. The use of general terminology to describe risks from stochastic effects is recommended rather than calculation of numerical values, as these are misleading when applied to individuals

On the utility of thermogravimetric analysis for exploring the kinetics of thermal degradation of lignins

The kinetics of pyrolysis of organosolv (TcA) and hydroxypropyl-modified (TcC) lignins have been investigated using thermogravimetric analysis (TGA). Three isothermal models (single first order, Guggenheim and Avrami-Erofeev) and one non-isothermal model (Kissinger) were used to analyse the mass-loss data. Sensible derived kinetic parameters, i.e., activation energy and pre-exponential factor, were obtained only for the initial stages of pyrolysis where the kinetics were approximately first order. Models that analysed TGA data beyond the initial stage gave inconsistent results, indicating the complexity of subsequent decomposition steps occurring at higher temperatures and/or longer times. The kinetics of the initial stage are important for designing routes to lignin's valorisation into useful products, such as carbon fibres, activated carbons, polymer additives, etc. TcC had a higher activation energy (41.5 kJ/mol) for initial decomposition than TcA (39 kJ/mol), consistent with its greater thermal stability observed previously during conversion of lignin-based fibres into carbon fibres

Thermal stability, flammability and mechanical performances of unsaturated polyester–melamine resin blends and of glass fibre-reinforced composites based on them

A novel blend of unsaturated polyester (UP) resin with an inherently flame-retardant and char-forming melamine formaldehyde (MF) resin has been prepared with the aim of reducing the flammability of the former. MF resin, sourced as a spray-dried resin, was dissolved in diethyleneglycol solvent; the dissolved resin and the UP-MF blend were autocured by heating under conditions normally used for curing UP, i.e., room temperature for 24 h and post-curing at 80 ◦C for 12–24 h. The cured UP-MF blends, although heterogeneous in nature, were rigid materials having fire performances superior to those of the cured UP alone. The blends also burned, but with a much reduced smoke output compared with that from UP. Although the heterogeneity of the blends helped in improving the fire performances of the blends in terms of the MF domains forming a semi-protective char, acting as thermal barriers for the adjoining UP domains, and hence reducing their thermal degradation, the mechanical properties of composites based on them were impaired. Nevertheless, whilst UP/MF blends may not be suitable for use as matrices in glass-reinforced composites in load-bearing applications, they may lend themselves to applications as fire-retardant gel coats, especially in view of their low-smoke, char-forming attributes

Thermal degradation analysis and XRD characterisation of fibre-forming synthetic polypropylene containing nanoclay

Flammability of synthetic fibres is significantly worse than that of bulk polymers because of the high surface area to volume ratio and the low tolerance to high filler loadings in the fibre production process. Introducing nanocomposite structures has the potential to enhance the char formation at relatively low loadings of nanoparticulate fillers and hence can reduce the flammability of synthetic polymers and fibres. This paper reports thermal degradation analysis results in conjunction with TG analysis under different atmospheres and further studies of X-ray diffraction characterisation of fibre-forming polypropylene containing selected dispersed nanoclays. The concentrations of hydrocarbons, carbon monoxide and carbon dioxide released during the TG analysis have been monitored and analysed by using a combined electrochemical infrared analyser. The intensity changes of the crystallinity peaks and nanoclay peaks in the polymer and composites are discussed

Novel flame retardant thermoset resin blends derived from a free-radically cured vinylbenzylated phenolic novolac and an unsaturated polyester for marine composites

A phenolic novolac resin has been chemically reacted with 4-vinylbenzyl chloride to introduce polymerizable vinyl benzyl groups. The modified novolac spontaneously polymerizes like styrene, is physically and chemically compatible with a typical unsaturated polyester (UP) resin, and can be free-radically cured (crosslinked) alone and in mixtures with UP using styrene as a reactive diluent. The cured vinylbenzylated novolac and co-cured blends of it with UP show superior flame retardance to cured UP alone and have potential applications as matrix resins in glass-reinforced composite laminates especially for marine structures