Ammonia emissions from deciduous forest after leaf fall

The understanding of biochemical feedback mechanisms in the climate system is lacking knowledge in relation to bi-directional ammonia (NH3) exchange between natural ecosystems and the atmosphere. We therefore study the atmospheric NH3 fluxes during a 25-day period during autumn 2010 (21 October to 15 November) for the Danish beech forest Lille Bøgeskov to address the hypothesis that NH3 emissions occur from deciduous forests in relation to leaf fall. This is accomplished by using observations of vegetation status, NH3 fluxes and model calculations. Vegetation status was observed using plant area index (PAI) and leaf area index (LAI). NH3 fluxes were measured using the relaxed eddy accumulation (REA) method. The REA-based NH3 concentrations were compared to NH3 denuder measurements. Model calculations of the atmospheric NH3 concentration were obtained with the Danish Ammonia MOdelling System (DAMOS). The relative contribution from the forest components to the atmospheric NH3 flux was assessed using a simple two-layer bi-directional canopy compensation point model. A total of 57.7% of the fluxes measured showed emission and 19.5% showed deposition. A clear tendency of the flux going from deposition of −0.25 ± 0.30 μg NH3-N m−2 s−1 to emission of up to 0.67 ± 0.28 μg NH3-N m−2 s−1 throughout the measurement period was found. In the leaf fall period (23 October to 8 November), an increase in the atmospheric NH3 concentrations was related to the increasing forest NH3 flux. Following leaf fall, the magnitude and temporal structure of the measured NH3 emission fluxes could be adequately reproduced with the bi-directional resistance model; it suggested the forest ground layer (soil and litter) to be the main contributing component to the NH3 emissions. The modelled concentration from DAMOS fits well the measured concentrations before leaf fall, but during and after leaf fall, the modelled concentrations are too low. The results indicate that the missing contribution to atmospheric NH3 concentration from vegetative surfaces related to leaf fall are of a relatively large magnitude. We therefore conclude that emissions from deciduous forests are important to include in model calculations of atmospheric NH3 for forest ecosystems. Finally, diurnal variations in the measured NH3 concentrations were related to meteorological conditions, forest phenology and the spatial distribution of local anthropogenic NH3 sources. This suggests that an accurate description of ammonia fluxes over forest ecosystems requires a dynamic description of atmospheric and vegetation processes

Positron annihilation induced Auger electron spectroscopy

Recently, Weiss et al. have demonstrated that it is possible to excite Auger transitions by annihilating core electrons using a low energy (less than 30eV) beam of positrons. This mechanism makes possible a new electron spectroscopy, Positron annihilation induced Auger Electron Spectroscopy (PAES). The probability of exciting an Auger transition is proportional to the overlap of the positron wavefunction with atomic core levels. Since the Auger electron energy provides a signature of the atomic species making the transition, PAES makes it possible to determine the overlap of the positron wavefunction with a particular element. PAES may therefore provide a means of detecting positron-atom complexes. Measurements of PAES intensities from clean and adsorbate covered Cu surfaces are presented which indicate that approx. 5 percent of positrons injected into CU at 25eV produce core annihilations that result in Auger transitions

Embedding massive flavor in ABJM

We add massive fundamental matter to the ABJM model by adding D6-branes wrapped asymptotically over RP3. We find two types of solutions at finite temperature, one that enters the black hole and one that ends before the black hole. We analyze the behavior of the free energy as a function of temperature, and find that the system exhibits a phase transition between the two types of solutions, similar to what happens in the D3-D7 system. We also analyze the meson spectrum in the model and find several massive scalar modes, again, quite like the D3-D7 system. We end with a calculation of the conductivities in the two phases.Comment: 26 pages, 6 figures; version published in JHE

Spitzer bright, UltraVISTA faint sources in COSMOS: the contribution to the overall population of massive galaxies at z=3-7

We have analysed a sample of 574 Spitzer 4.5 micron-selected galaxies with [4.5]24 (AB) over the UltraVISTA ultra-deep COSMOS field. Our aim is to investigate whether these mid-IR bright, near-IR faint sources contribute significantly to the overall population of massive galaxies at redshifts z>=3. By performing a spectral energy distribution (SED) analysis using up to 30 photometric bands, we have determined that the redshift distribution of our sample peaks at redshifts z~2.5-3.0, and ~32% of the galaxies lie at z>=3. We have studied the contribution of these sources to the galaxy stellar mass function (GSMF) at high redshifts. We found that the [4.5]24 galaxies produce a negligible change to the GSMF previously determined for Ks_auto<24 sources at 3=<z<4, but their contribution is more important at 4=~50% of the galaxies with stellar masses Mst>~6 x 10^10 Msun. We also constrained the GSMF at the highest-mass end (Mst>~2 x 10^11 Msun) at z>=5. From their presence at 5=<z<6, and virtual absence at higher redshifts, we can pinpoint quite precisely the moment of appearance of the first most massive galaxies as taking place in the ~0.2 Gyr of elapsed time between z~6 and z~5. Alternatively, if very massive galaxies existed earlier in cosmic time, they should have been significantly dust-obscured to lie beyond the detection limits of current, large-area, deep near-IR surveys.Comment: 18 pages, 15 figures, 4 tables. Updated to match version in press at the Ap

Decay rate measurement of the first vibrationally excited state of MgH+^+ in a cryogenic Paul trap

We present a method to measure the decay rate of the first excited vibrational state of simple polar molecular ions being part of a Coulomb crystal in a cryogenic linear Paul trap. Specifically, we have monitored the decay of the $|\nu$=$1,J$=$1 \rangle_X$ towards the $|\nu$=$0,J$=$0 \rangle_X$ level in MgH$^+$ by saturated laser excitation of the $|\nu$=$0,J$=$2 \rangle_X$-$|\nu$=$1,J$=$1 \rangle_X$ transition followed by state selective resonance enhanced two-photon dissociation out of the $|\nu$=$0,J$=$2 \rangle_X$ level. The technique enables the determination of decay rates, and thus absorption strengths, with an accuracy at the few percent level.Comment: 5 pages, 4 figure