Correlation between structure and physical properties of chalcogenide glasses in the AsxSe1-x system

International audiencePhysical properties of chalcogenide glasses in the AsxSe1−x system have been measured as a function of composition including the Young's modulus E, shear modulus G, bulk modulus K, Poisson's ratio ν, the density ρ, and the glass transition Tg. All these properties exhibit a relatively sharp extremum at the average coordination number ⟨r⟩=2.4. The structural origin of this trend is investigated by Raman spectroscopy and nuclear magnetic resonance. It is shown that the reticulation of the glass structure increases continuously until x=0.4 following the "chain crossing model" and then undergoes a transition toward a lower dimension pyramidal network containing an increasing number of molecular inclusions at x>0.4. Simple theoretical estimates of the network bonding energy confirm a mismatch between the values of mechanical properties measured experimentally and the values predicted from a continuously reticulated structure, therefore corroborating the formation of a lower dimension network at high As content. The evolution of a wide range of physical properties is consistent with this sharp structural transition and suggests that there is no intermediate phase in these glasses at room temperature

SEGUE : a spectroscopic survey of 240,000 stars with g=14-20

The Sloan Extension for Galactic Understanding and Exploration (SEGUE) Survey obtained approximate to 240,000 moderate-resolution (R similar to 1800) spectra from 3900 angstrom to 9000 angstrom of fainter Milky Way stars (14.0 10 per resolution element, stellar atmospheric parameters are estimated, including metallicity, surface gravity, and effective temperature. SEGUE obtained 3500 deg(2) of additional ugriz imaging (primarily at low Galactic latitudes) providing precise multicolor photometry (sigma(g, r, i) similar to 2%), (sigma(u, z) similar to 3%) and astrometry (approximate to 0 ''.1) for spectroscopic target selection. The stellar spectra, imaging data, and derived parameter catalogs for this survey are publicly available as part of Sloan Digital Sky Survey Data Release 7

The First Data Release of the Sloan Digital Sky Survey

The Sloan Digital Sky Survey (SDSS) has validated and made publicly available its First Data Release. This consists of 2099 deg2 of five-band (u, g, r, i, z) imaging data, 186,240 spectra of galaxies, quasars, stars and calibrating blank sky patches selected over 1360 deg2 of this area, and tables of measured parameters from these data. The imaging data go to a depth of r ≈ 22.6 and are photometrically and astrometrically calibrated to 2% rms and 100 mas rms per coordinate, respectively. The spectra cover the range 3800–9200 Å, with a resolution of 1800–2100. This paper describes the characteristics of the data with emphasis on improvements since the release of commissioning data (the SDSS Early Data Release) and serves as a pointer to extensive published and on-line documentation of the survey.Astronom