Estimating precipitation on early Mars using a radiative-convective model of the atmosphere and comparison with inferred runoff from geomorphology

We compare estimates of atmospheric precipitation during the Martian Noachian-Hesperian boundary 3.8 Gyr ago as calculated in a radiative-convective column model of the atmosphere with runoff values estimated from a geomorphological analysis of dendritic valley network discharge rates. In the atmospheric model, we assume CO2-H2O-N2 atmospheres with surface pressures varying from 20 mb to 3 bar with input solar luminosity reduced to 75% the modern value. Results from the valley network analysis are of the order of a few mm d-1 liquid water precipitation (1.5-10.6 mm d-1, with a median of 3.1 mm d-1). Atmospheric model results are much lower, from about 0.001-1 mm d-1 of snowfall (depending on CO2 partial pressure). Hence, the atmospheric model predicts a significantly lower amount of precipitated water than estimated from the geomorphological analysis. Furthermore, global mean surface temperatures are below freezing, i.e. runoff is most likely not directly linked to precipitation. Therefore, our results strongly favor a cold early Mars with episodic snowmelt as a source for runoff. Our approach is challenged by mostly unconstrained parameters, e.g. greenhouse gas abundance, global meteorology (for example, clouds) and planetary parameters such as obliquity- which affect the atmospheric result - as as well as by inherent problems in estimating discharge and runoff on ancient Mars, such as a lack of knowledge on infiltration and evaporation rates and on flooding timescales, which affect the geomorphological data. Nevertheless, our work represents a first step in combining and interpreting quantitative tools applied in early Mars atmospheric and geomorphological studies.Comment: accepted in Planetary and Space Science, 37 pages, 14 figures, 2 table

Mid-infrared emissivity of partially dehydrated asteroid (162173) Ryugu shows strong signs of aqueous alteration

The near-Earth asteroid (162173) Ryugu, the target of Hayabusa2 space mission, was observed via both orbiter and the lander instruments. The infrared radiometer on the MASCOT lander (MARA) is the only instrument providing spectrally resolved mid-infrared (MIR) data, which is crucial for establishing a link between the asteroid material and meteorites found on Earth. Earlier studies revealed that the single boulder investigated by the lander belongs to the most common type found on Ryugu. Here we show the spectral variation of Ryugu’s emissivity using the complete set of in-situ MIR data and compare it to those of various carbonaceous chondritic meteorites, revealing similarities to the most aqueously altered ones, as well as to asteroid (101955) Bennu. The results show that Ryugu experienced strong aqueous alteration prior to any dehydration

The PanCam instrument on the 2018 Exomars rover: Scientific objectives

Geophysical Research Abstract

The formation and evolution of bright spots on Ceres

The otherwise homogeneous surface of Ceres is dotted with hundreds of anomalously bright, predominantly carbonate-bearing areas, termed "faculae," with Bond albedos ranging from ∼0.02 to >0.5. Here, we classify and map faculae globally to characterize their geological setting, assess potential mechanisms for their formation and destruction, and gain insight into the processes affecting the Ceres surface and near-surface. Faculae were found to occur in four distinct geological settings, associated predominantly with impact craters: (1) crater pits, peaks, or floor fractures (floor faculae), (2) crater rims or walls (rim/wall faculae), (3) bright ejecta blankets, and (4) the mountain Ahuna Mons. Floor faculae were identified in eight large, deep, and geologically young (asteroid-derived model (ADM) ages of <420 ± 60 Ma) craters: Occator, Haulani, Dantu, Ikapati, Urvara, Gaue, Ernutet, and Azacca. The geometry and geomorphic features of the eight craters with floor faculae are consistent with facula formation via impact-induced heating and upwelling of volatile-rich materials, upwelling/excavation of heterogeneously distributed subsurface brines or their precipitation products, or a combination of both processes. Rim/wall faculae and bright ejecta occur in and around hundreds of relatively young craters of all sizes, and the geometry of exposures is consistent with facula formation via the excavation of subsurface bright material, possibly from floor faculae that were previously emplaced and buried. A negative correlation between rim/wall facula albedo and crater age indicates that faculae darken over time. Models using the Ceres crater production function suggest initial production or exposure of faculae by large impacts, subsequent dissemination of facula materials to form additional small faculae, and then burial by impact-induced lateral mixing, which destroys faculae over timescales of less than 1.25 Gyr. Cumulatively, these models and the observation of faculae limited to geologically young craters indicate relatively modern formation or exposure of faculae, indicating that Ceres' surface remains active and that the near surface may support brines in the present day

Binding energy referencing for XPS in Alkali metal-based battery materials research (II): Application to complex composite electrodes

X-ray photoelectron spectroscopy (XPS) is a key method for studying (electro-)chemical changes in metal-ion battery electrode materials. In a recent publication, we pointed out a conflict in binding energy (BE) scale referencing at alkali metal samples, which is manifested in systematic deviations of the BEs up to several eV due to a specific interaction between the highly reactive alkali metal in contact with non-conducting surrounding species. The consequences of this phenomenon for XPS data interpretation are discussed in the present manuscript. Investigations of phenomena at surface-electrolyte interphase regions for a wide range of materials for both lithium and sodium-based applications are explained, ranging from oxide-based cathode materials via alloys and carbon-based anodes including appropriate reference chemicals. Depending on material class and alkaline content, specific solutions are proposed for choosing the correct reference BE to accurately define the BE scale. In conclusion, the different approaches for the use of reference elements, such as aliphatic carbon, implanted noble gas or surface metals, partially lack practicability and can lead to misinterpretation for application in battery materials. Thus, this manuscript provides exemplary alternative solutions