Electronic structure and chemical bonding of nc-TiC/a-C nanocomposites

The electronic structure of nanocrystalline (nc-) TiC/amorphous C nanocomposites has been investigated by soft x-ray absorption and emission spectroscopy. The measured spectra at the Ti 2p and C 1s thresholds of the nanocomposites are compared to those of Ti metal and amorphous C. The corresponding intensities of the electronic states for the valence and conduction bands in the nanocomposites are shown to strongly depend on the TiC carbide grain size. An increased charge-transfer between the Ti 3d-eg states and the C 2p states has been identified as the grain size decreases, causing an increased ionicity of the TiC nanocrystallites. It is suggested that the charge-transfer occurs at the interface between the nanocrystalline TiC and the amorphous C matrix and represents an interface bonding which may be essential for the understanding of the properties of nc-TiC/amorphous C and similar nanocomposites.Comment: 13 pages, 6 figures, 1 table; http://link.aps.org/doi/10.1103/PhysRevB.80.23510

Linking models for land use analysis: experiences from the SENSOR project

In order to quantify the effects of a comprehensive set of policies on land use, interaction between sectors needs to be accounted for, while maintaining a high level of detail for each sector. This calls for a combination of sector specific and sector wide models. This paper describes such a modelling system, with emphasis on the linking of the models to a coherent system. Five sectors of significant importance for land use are modelled individually: Forestry, agriculture, urban land use, transport infrastructure, and tourism. All models are connected as sub-modules to an economy-wide partial econometric model. In addition, a land cover model is used to disaggregate land use down to 1km grid resolution. The linking of such a diverse set of models in a consistent way poses conceptual as well as practical issues. The conceptual issues concern questions such as which items of the models to link, how to obtain a stable joint baseline scenario, and how to obtain a joint equilibrium solution for all models simultaneously in simulation. Practical issues concern the actual implementation of the conceptually sound linkages and provision of a workable technical solution. The linked system allows us to introduce a shock in either of the models, and the set of results will provide a joint solution for all sectors modelled in SENSOR. In this manner, the models take a complex policy scenario as argument and compute a comprehensive set of variables involving all five land use sectors on regional level, which in turn forms a basis for distilling out the impact on sustainability in the form of indicators. Without the extensive automation and technical linkages, it would not have been possible to obtain a joint equilibrium, or it would have required exorbitant amounts of working time.Model linking, sustainable land use, cross sector modelling, iterative recalibration, Land Economics/Use,

Solid State Switch Application for the LHC Extraction Kicker Pulse Generator

A semiconductor solid state switch has been constructed and tested in the prototype extraction kicker pulse generator of CERN's Large Hadron Collider (LHC) [1]. The switch is made of 10 modified 4.5 kV, 66 mm symmetric GTO's (also called FHCT-Fast High Current Thyristor), connected in series. It holds off a d.c. voltage of 30 kV and conducts a 5 µs half-sine wave current of 20 kA with an initial di/dt of 10 kA/µs. Major advantages of the switch are the extremely low self-firing hazard, no power consumption during the ready-to-go status, instantaneous availability, simple condition control, very low noise emission during soft turn-on switching and easy maintenance. However, the inherent soft, relatively slow turn-on time is a non negligible part of the required rise time and this involves adaptation of generator components. A dynamic current range of 16 is achieved with variations in rise time, which stay within acceptable limits. Important generator improvements have been made with the series diodes and freewheel diodes. A more efficient droop compensation circuit is being studied. It is directly connected in series with the freewheel diode stack and maintains an acceptable flattop variation of 5% of the magnet current during 90 µs. This paper presents the complete generator, in particular the solid state switch and discusses related electrical measurements

Kick Stability Analysis of the LHC Inflectors

Two sets of four LHC inflector magnet systems must produce a kick of 1.36 Tm each with a duration of 6.5 µs, a rise time of 750 ns, and an overall stability of ± 0.5%. The electrical circuit of the complete system, including all known stray quantities, has been simulated with PSpice. Many stray elements were determined from Opera2D simulations which included eddy-currents. 3D analyses have also been carried out for the kicker magnet using the electromagnetic analysis code Opera3D. Equivalent circuits which simulate the frequency dependence of inductance and resistance of the Pulse Forming Network (PFN) have been derived. The dimensions of the PFN coil have been selected to give the correct pulse response. The end cells of the PFN have also been optimised. The discharge stability of various PFN capacitors has been measured. This paper presents the results of both the analyses and measurements

Design of the injection kicker magnet system for CERN's 14 TeV proton collider LHC

Two counter-rotating proton beams will be injected into the LHC at an energy of 450 GeV by two kicker magnet systems, producing magnetic field pulses of approximately 750 ns rise time and 6.6 µs flat top duration. To avoid dilution of the beam emittance during injection, a stringent design requirement of the system is a flat top ripple of the magnetic field of less than ± 0.5%. Both injection systems are composed of 4 travelling wave kicker magnets of 2.17 m length each, powered by pulse forming networks (PFN's) and matched to their characteristic impedance. To achieve the high required kick strength of 1.2 Tm, for a compact and cost efficient design, a comparably low characteristic impedance of 5 has been chosen. The electrical circuit of the system is being designed with the help of PSpice computer modelling. Most known parasitic elements are included in the model to obtain a realistic pulse response prediction. The present paper reports on design and modeling results of the LHC injection kicker magnet system that has several novel and demanding design requirements

Pseudospark Switch Development for the LHC Extraction Kicker Pulse Generator

CERN, the European Laboratory for Particle Physics, has started construction of the Large Hadron Collider (LHC), a superconducting accelerator that will collide protons at a center of mass energy of 14 TeV from the year 2005 onwards. The kicker magnet pulse generators of the LHC beam extraction system require fast high power switches. One possible type is the pseudospark switch (PSS) which has several advantages for this application. A PSS fulfilling most of the requirements has been developed in the past years. Two outstanding problems, prefiring at high operating voltages and sudden current interruptions (quenching) at low voltage could be solved recently. Prefiring can be avoided for this special application by conditioning the switch at two times the nominal voltage after each power pulse. Quenching can be suppressed by choosing an appropriate electrode geometry and by mixing Krypton to the D2 gas atmosphere. One remaining problem, related to the required large dynamic voltage range (1.7 kV to 30 kV) is under active investigation: steps in forward voltage during conduction, occurring at low operation voltage at irregular time instants and causing a pulse to pulse jitter of the peak current. This paper presents results of electrical measurements concerning prefiring and quenching and explains how these problems have been solved. Furthermore the plans to cure the forward voltage step problem will be discussed

Underappreciated features of cultural evolution.

Cultural evolution theory has long been inspired by evolutionary biology. Conceptual analogies between biological and cultural evolution have led to the adoption of a range of formal theoretical approaches from population dynamics and genetics. However, this has resulted in a research programme with a strong focus on cultural transmission. Here, we contrast biological with cultural evolution, and highlight aspects of cultural evolution that have not received sufficient attention previously. We outline possible implications for evolutionary dynamics and argue that not taking them into account will limit our understanding of cultural systems. We propose 12 key questions for future research, among which are calls to improve our understanding of the combinatorial properties of cultural innovation, and the role of development and life history in cultural dynamics. Finally, we discuss how this vibrant research field can make progress by embracing its multidisciplinary nature. This article is part of the theme issue 'Foundations of cultural evolution'