2,864 research outputs found
Accumulation of blue-green algae in the surface water of the northern Baltic, 6 August 1975, generated from the CCT-tape MSS 5 (ID 2196-0917200) by a Hertz ink-jet plotter connected to a APDP 11/40 computer at FOA 3
There are no author-identified significant results in this report
The Baltic Sea
There are no author-identified significant results in this report
Dynamics and energy flows in the Baltic ecosystems: Remote sensing
There are no author-identified significant results in this report
Electronic structure and chemical bonding in Ti2AlC investigated by soft x-ray emission spectroscopy
The electronic structure of the nanolaminated transition metal carbide Ti2AlC
has been investigated by bulk-sensitive soft x-ray emission spectroscopy. The
measured Ti L, C K and Al L emission spectra are compared with calculated
spectra using ab initio density-functional theory including dipole matrix
elements. The detailed investigation of the electronic structure and chemical
bonding provides increased understanding of the physical properties of this
type of nanolaminates. Three different types of bond regions are identified;
the relatively weak Ti 3d - Al 3p hybridization 1 eV below the Fermi level, and
the Ti 3d - C 2p and Ti 3d - C 2s hybridizations which are stronger and deeper
in energy are observed around 2.5 eV and 10 eV below the Fermi level,
respectively. A strongly modified spectral shape of the 3s final states in
comparison to pure Al is detected for the buried Al monolayers indirectly
reflecting the Ti 3d - Al 3p hybridization. The differences between the
electronic and crystal structures of Ti2AlC, Ti3AlC2 and TiC are discussed in
relation to the number of Al layers per Ti layer in the two former systems and
the corresponding change of the unusual materials properties.Comment: 14 pages, 7 figures; PACS:78.70.En, 71.15.Mb, 71.20.-
Deconvolving Instrumental and Intrinsic Broadening in Excited State X-ray Spectroscopies
Intrinsic and experimental mechanisms frequently lead to broadening of
spectral features in excited-state spectroscopies. For example, intrinsic
broadening occurs in x-ray absorption spectroscopy (XAS) measurements of heavy
elements where the core-hole lifetime is very short. On the other hand,
nonresonant x-ray Raman scattering (XRS) and other energy loss measurements are
more limited by instrumental resolution. Here, we demonstrate that the
Richardson-Lucy (RL) iterative algorithm provides a robust method for
deconvolving instrumental and intrinsic resolutions from typical XAS and XRS
data. For the K-edge XAS of Ag, we find nearly complete removal of ~9.3 eV FWHM
broadening from the combined effects of the short core-hole lifetime and
instrumental resolution. We are also able to remove nearly all instrumental
broadening in an XRS measurement of diamond, with the resulting improved
spectrum comparing favorably with prior soft x-ray XAS measurements. We present
a practical methodology for implementing the RL algorithm to these problems,
emphasizing the importance of testing for stability of the deconvolution
process against noise amplification, perturbations in the initial spectra, and
uncertainties in the core-hole lifetime.Comment: 35 pages, 13 figure
Factors increase social welfare of the population in the knowledge economy
At present, the knowledge economy plays a very important role. It is the key to competitiveness in the market and is the driving force of enhanced social life of mankind. Improving the welfare conditions of the knowledge economy is a very urgent problem that most countries are particularly interested. This problem mainly be promoted based on the development of cognitive capital
Electronic structure and chemical bonding in Ti4SiC3 investigated by soft x-ray emission spectroscopy and first principle theory
The electronic structure in the new transition metal carbide Ti4SiC3 has been
investigated by bulk-sensitive soft x-ray emission spectroscopy and compared to
the well-studied Ti3SiC2 and TiC systems. The measured high-resolution Ti L, C
K and Si L x-ray emission spectra are discussed with ab initio calculations
based on density-functional theory including core-to-valence dipole matrix
elements. The detailed investigations of the Ti-C and Ti-Si chemical bonds
provide increased understanding of the physical properties of these
nanolaminates. A strongly modified spectral shape is detected for the buried Si
monolayers due to Si 3p hybridization with the Ti 3d orbitals. As a result of
relaxation of the crystal structure and the charge-transfer from Ti (and Si) to
C, the strength of the Ti-C covalent bond is increased. The differences between
the electronic and crystal structures of Ti4SiC3 and Ti3SiC2 are discussed in
relation to the number of Si layers per Ti layer in the two systems and the
corresponding change of materials properties.Comment: 12 pages, 7 figures, 1 tabl
Detection of viable Mycobacterium ulcerans in clinical samples by a novel combined 16S rRNA reverse transcriptase/IS2404 real-time qPCR assay.
Detection of Viable <em>Mycobacterium ulcerans</em> in Clinical Samples by a Novel Combined 16S rRNA Reverse Transcriptase/IS<em>2404</em> Real-Time qPCR Assa
Computational Modeling of Dynamical Systems
In this short note, we discuss the basic approach to computational modeling
of dynamical systems. If a dynamical system contains multiple time scales,
ranging from very fast to slow, computational solution of the dynamical system
can be very costly. By resolving the fast time scales in a short time
simulation, a model for the effect of the small time scale variation on large
time scales can be determined, making solution possible on a long time
interval. This process of computational modeling can be completely automated.
Two examples are presented, including a simple model problem oscillating at a
time scale of 1e-9 computed over the time interval [0,100], and a lattice
consisting of large and small point masses
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