Drone-based Integration of Hyperspectral Imaging and Magnetics for Mineral Exploration

The advent of unoccupied aerial systems (UAS) as disruptive technology has a lasting impact on remote sensing, geophysics and most geosciences. Small, lightweight, and low-cost UAS enable researchers and surveyors to acquire earth observation data in higher spatial and spectral resolution as compared to airborne and satellite data. UAS-based applications range from rapid topographic mapping using photogrammetric techniques to hyperspectral and geophysical measurements of surface and subsurface geology. UAS surveys contribute to identifying metal deposits, monitoring of mine sites and can reveal arising environmental issues associated with mining. Further, affordable UAS technology will boost exploration data availability and expertise in the global south. This thesis investigates the application of UAS-based multi-sensor data for mineral exploration, in particular the integration of hyperspectral imagers, magnetometers and digital cameras (covering the visible red, green, blue light spectrum). UAS-based research is maturing, however the aforementioned methods are not unified effectively. RGB-based photogrammetry is used to investigate topography and surface texture. Image spectrometers measure mineral-specific surface signatures. Magnetometers detect geomagnetic field changes caused by magnetic minerals at surface and depth. The integration of such UAS sensor-based methods in this thesis augments exploration potential with non-invasive, high-resolution, safe, rapid and practical survey methods. UAS-based surveying acquired, processed and integrated data from three distinct test sites. The sites are located in Finland (Fe-Ti-V at Otanmäki; apatite at Siilinjärvi) and Greenland (Ni-Cu-PGE at Qullissat, Disko Island) and were chosen as geologically diverse areas in subarctic to arctic environments. Restricted accessibility, unfavourable atmospheric conditions, dark rocks, debris and vegetation cover and low solar illumination were common features. While the topography in Finland was moderately flat, a steep landscape challenged the Greenland field work. These restraints meant that acquisitions varied from site to site and how data was integrated and interpreted is dependent on the commodity of interest. Iron-based spectral absorption and magnetic mineral response were detected using hyperspectral and magnetic surveying in Otanmäki. Multi-sensor-based image feature detection and classification combined with magnetic forward modelling enabled seamless geologic mapping in Siilinjärvi. Detailed magnetic inversion and multispectral photogrammetry led to the construction of a comprehensive 3D model of magmatic exploration targets in Greenland. Ground truth at different intensity was employed to verify UAS-based data interpretations during all case studies. Laboratory analysis was applied when deemed necessary to acquire geologic-mineralogic validation (e.g., X-ray diffraction and optical microscopy for mineral identification to establish lithologic domains, magnetic susceptibility measurements for subsurface modelling), for example for trace amounts of magnetite in carbonatite (Siilinjärvi) and native iron occurrence in basalt (Qullissat). Technical achievements were the integration of a multicopter-based prototype fluxgate-magnetometer data from different survey altitudes with ground truth, and a feasibility study with a high-speed multispectral image system for fixed-wing UAS. The employed case studies transfer the experiences made towards general recommendations for UAS application-based multi-sensor integration. This thesis highlights the feasibility of UAS-based surveying at target scale (1–50 km2) and solidifies versatile survey approaches for multi-sensor integration.Ziel dieser Arbeit war es, das Potenzial einer Drohnen-basierten Mineralexploration mit Multisensor-Datenintegration unter Verwendung optisch-spektroskopischer und magnetischer Methoden zu untersuchen, um u. a. übertragbare Arbeitsabläufe zu erstellen. Die untersuchte Literatur legt nahe, dass Drohnen-basierte Bildspektroskopie und magnetische Sensoren ein ausgereiftes technologisches Niveau erreichen und erhebliches Potenzial für die Anwendungsentwicklung bieten, aber es noch keine ausreichende Synergie von hyperspektralen und magnetischen Methoden gibt. Diese Arbeit umfasste drei Fallstudien, bei denen die Drohnengestützte Vermessung von geologischen Zielen in subarktischen bis arktischen Regionen angewendet wurde. Eine Kombination von Drohnen-Technologie mit RGB, Multi- und Hyperspektralkameras und Magnetometern ist vorteilhaft und schuf die Grundlage für eine integrierte Modellierung in den Fallstudien. Die Untersuchungen wurden in einem Gelände mit flacher und zerklüfteter Topografie, verdeckten Zielen und unter oft schlechten Lichtverhältnissen durchgeführt. Unter diesen Bedingungen war es das Ziel, die Anwendbarkeit von Drohnen-basierten Multisensordaten in verschiedenen Explorationsumgebungen zu bewerten. Hochauflösende Oberflächenbilder und Untergrundinformationen aus der Magnetik wurden fusioniert und gemeinsam interpretiert, dabei war eine selektive Gesteinsprobennahme und Analyse ein wesentlicher Bestandteil dieser Arbeit und für die Validierung notwendig. Für eine Eisenerzlagerstätte wurde eine einfache Ressourcenschätzung durchgeführt, indem Magnetik, bildspektroskopisch-basierte Indizes und 2D-Strukturinterpretation integriert wurden. Fotogrammetrische 3D-Modellierung, magnetisches forward-modelling und hyperspektrale Klassifizierungen wurden für eine Karbonatit-Intrusion angewendet, um einen kompletten Explorationsabschnitt zu erfassen. Eine Vektorinversion von magnetischen Daten von Disko Island, Grönland, wurden genutzt, um großräumige 3D-Modelle von undifferenzierten Erdrutschblöcken zu erstellen, sowie diese zu identifizieren und zu vermessen. Die integrierte spektrale und magnetische Kartierung in komplexen Gebieten verbesserte die Erkennungsrate und räumliche Auflösung von Erkundungszielen und reduzierte Zeit, Aufwand und benötigtes Probenmaterial für eine komplexe Interpretation. Der Prototyp einer Multispektralkamera, gebaut für eine Starrflügler-Drohne für die schnelle Vermessung, wurde entwickelt, erfolgreich getestet und zum Teil ausgewertet. Die vorgelegte Arbeit zeigt die Vorteile und Potenziale von Multisensor-Drohnen als praktisches, leichtes, sicheres, schnelles und komfortabel einsetzbares geowissenschaftliches Werkzeug, um digitale Modelle für präzise Rohstofferkundung und geologische Kartierung zu erstellen

Exemestane in early breast cancer: a review

The adjuvant treatment of women with endocrine-sensitive early breast cancer has been dominated for the last 40 years by tamoxifen. However, the side-effects associated with this therapy have prompted a search for safer and biochemically more selective endocrine agents and led to the development of the third-generation aromatase inhibitors (AIs) anastrozole, letrozole and exemestane. Promising results in advanced disease have paved the way for treating early breast cancer, and AIs are increasingly replacing tamoxifen in the adjuvant setting. Several large, randomized trials with AIs have been completed or are ongoing in women with early-stage breast cancer, documenting the significant impact that these drugs are making on the risk for recurrence of breast cancer. As a result, there is increasing and widespread use of AI therapy for the treatment of early-stage endocrine-responsive breast cancer. This review summarizes the data for exemestane in the adjuvant setting, showing that a switch to exemestane after 2 to 3 years of tamoxifen therapy is associated with a statistically significant survival benefit and is regarded as being sensitive by international and national experts

2,2′,6,6′-Tetra­methyl-4,4′-bipyridine

In the title compound, C14H16N2, which has no crystallographic molecular symmetry, the dihedral angle between the least-squares planes of the two pyridine rings is 19.48 (2)°. No classical hydrogen bonds nor π–π inter­actions were found

Form and function in hillslope hydrology : in situ imaging and characterization of flow-relevant structures

Thanks to Elly Karle and the Engler-BunteInstitute, KIT, for the IC measurements of bromide. We are grateful to Selina Baldauf, Marcel Delock, Razije Fiden, Barbara Herbstritt, Lisei Köhn, Jonas Lanz, Francois Nyobeu, Marvin Reich and Begona Lorente Sistiaga for their support in the lab and during fieldwork, as well as Markus Morgner and Jean Francois Iffly for technical support and Britta Kattenstroth for hydrometeorological data acquisition. Laurent Pfister and Jean-Francois Iffly from the Luxembourg Institute of Science and Technology (LIST) are acknowledged for organizing the permissions for the experiments. Moreover, we thank Markus Weiler (University of Freiburg) for his strong support during the planning of the hillslope experiment and the preparation of the manuscript. This study is part of the DFG-funded CAOS project “From Catchments as Organised Systems to Models based on Dynamic Functional Units” (FOR 1598). The manuscript was substantially improved based on the critical and constructive comments of the anonymous reviewers, Christian Stamm and Alexander Zimmermann, and the editor Ross Woods during the open review process, which is highly appreciated.Peer reviewedPublisher PD

Form and function in hillslope hydrology : Characterization of subsurface ow based on response observations

Acknowledgements. We are grateful to Marcel Delock, Lisei Köhn, and Marvin Reich for their support during fieldwork, as well as Markus Morgner and Jean Francois Iffly for technical support, Britta Kattenstroth for hydrometeorological data acquisition and isotope sampling, and Barbara Herbstritt and Begoña Lorente Sistiaga for laboratory work. Laurent Pfister and Jean-Francois Iffly from the Luxembourg Institute of Science and Technology (LIST) are acknowledged for organizing the permissions for the experiments and providing discharge data for Weierbach 1 and Colpach. We also want to thank Frauke K. Barthold and the two anonymous reviewers, whose thorough remarks greatly helped to improve the manuscript. This study is part of DFG-funded CAOS project “From Catchments as Organised Systems to Models based on Dynamic Functional Units” (FOR 1598). The article processing charges for this open-access publication were covered by a Research Centre of the Helmholtz Association.Peer reviewedPublisher PD

Linking structure and functioning of hydrological systems - How to achieve necessary experimental and model complexity with adequate effort

This thesis quests after minimum adequacy of model complexity, geophysical exploration and functional unit identification through examples from the Attert experimental basin. With emphasis on a joined examination of theoretical concepts, experimental methodology and modelling approaches the study addresses landscape and process analysis, targeted experiments at the plot- and hillslope-scale and the development of a novel Lagrangian model framework for diffusive and advective soil water dynamics

Personagens imaginários : uma contribuição sobre a sua influência na comunicação dirigida à criança através da análise de embalagens

Com o objetivo de analisar a influência exercida sobre a criança, este estudo versa sobre o personagem imaginário, sua função na comunicação e seu relacionamento com o público infantil. Para tanto, são abordados temas como a persuasão, a função persuasiva da imagem e sua relação com a criança, bem como aportes teóricos relacionados à comunicação da marca dirigida ao público infantil. Como forma de ponderar sobre essa utilização do personagem imaginário, o trabalho apresenta também uma breve análise sobre duas embalagens retiradas do mercado brasileiro pertencentes a produtos destinados diretamente a esses indivíduos