116 research outputs found
A Soluble Phase Field Model
The kinetics of an initially undercooled solid-liquid melt is studied by
means of a generalized Phase Field model, which describes the dynamics of an
ordering non-conserved field phi (e.g. solid-liquid order parameter) coupled to
a conserved field (e.g. thermal field). After obtaining the rules governing the
evolution process, by means of analytical arguments, we present a discussion of
the asymptotic time-dependent solutions. The full solutions of the exact
self-consistent equations for the model are also obtained and compared with
computer simulation results. In addition, in order to check the validity of the
present model we confronted its predictions against those of the standard Phase
field model and found reasonable agreement. Interestingly, we find that the
system relaxes towards a mixed phase, depending on the average value of the
conserved field, i.e. on the initial condition. Such a phase is characterized
by large fluctuations of the phi field.Comment: 13 pages, 8 figures, RevTeX 3.1, submitted to Physical Review
Unconventional MBE Strategies from Computer Simulations for Optimized Growth Conditions
We investigate the influence of step edge diffusion (SED) and desorption on
Molecular Beam Epitaxy (MBE) using kinetic Monte-Carlo simulations of the
solid-on-solid (SOS) model. Based on these investigations we propose two
strategies to optimize MBE growth. The strategies are applicable in different
growth regimes: During layer-by-layer growth one can exploit the presence of
desorption in order to achieve smooth surfaces. By additional short high flux
pulses of particles one can increase the growth rate and assist layer-by-layer
growth. If, however, mounds are formed (non-layer-by-layer growth) the SED can
be used to control size and shape of the three-dimensional structures. By
controlled reduction of the flux with time we achieve a fast coarsening
together with smooth step edges.Comment: 19 pages, 7 figures, submitted to Phys. Rev.
A Dissipative-Particle-Dynamics Model for Simulating Dynamics of Charged Colloid
A mesoscopic colloid model is developed in which a spherical colloid is
represented by many interacting sites on its surface. The hydrodynamic
interactions with thermal fluctuations are taken accounts in full using
Dissipative Particle Dynamics, and the electrostatic interactions are simulated
using Particle-Particle-Particle Mesh method. This new model is applied to
investigate the electrophoretic mobility of a charged colloid under an external
electric field, and the influence of salt concentration and colloid charge are
systematically studied. The simulation results show good agreement with
predictions from the electrokinetic theory.Comment: 17 pages, 8 figures, submitted to the proceedings of High Performance
Computing in Science & Engineering '1
The liquid-vapor interface of an ionic fluid
We investigate the liquid-vapor interface of the restricted primitive model
(RPM) for an ionic fluid using a density-functional approximation based on
correlation functions of the homogeneous fluid as obtained from the
mean-spherical approximation (MSA). In the limit of a homogeneous fluid our
approach yields the well-known MSA (energy) equation of state. The ionic
interfacial density profiles, which for the RPM are identical for both species,
have a shape similar to those of simple atomic fluids in that the decay towards
the bulk values is more rapid on the vapor side than on the liquid side. This
is the opposite asymmetry of the decay to that found in earlier calculations
for the RPM based on a square-gradient theory. The width of the interface is,
for a wide range of temperatures, approximately four times the second moment
correlation length of the liquid phase. We discuss the magnitude and
temperature dependence of the surface tension, and argue that for temperatures
near the triple point the ratio of the dimensionless surface tension and
critical temperature is much smaller for the RPM than for simple atomic fluids.Comment: 6 postscript figures, submitted to Phys. Rev.
Monte Carlo Methods for Estimating Interfacial Free Energies and Line Tensions
Excess contributions to the free energy due to interfaces occur for many
problems encountered in the statistical physics of condensed matter when
coexistence between different phases is possible (e.g. wetting phenomena,
nucleation, crystal growth, etc.). This article reviews two methods to estimate
both interfacial free energies and line tensions by Monte Carlo simulations of
simple models, (e.g. the Ising model, a symmetrical binary Lennard-Jones fluid
exhibiting a miscibility gap, and a simple Lennard-Jones fluid). One method is
based on thermodynamic integration. This method is useful to study flat and
inclined interfaces for Ising lattices, allowing also the estimation of line
tensions of three-phase contact lines, when the interfaces meet walls (where
"surface fields" may act). A generalization to off-lattice systems is described
as well.
The second method is based on the sampling of the order parameter
distribution of the system throughout the two-phase coexistence region of the
model. Both the interface free energies of flat interfaces and of (spherical or
cylindrical) droplets (or bubbles) can be estimated, including also systems
with walls, where sphere-cap shaped wall-attached droplets occur. The
curvature-dependence of the interfacial free energy is discussed, and estimates
for the line tensions are compared to results from the thermodynamic
integration method. Basic limitations of all these methods are critically
discussed, and an outlook on other approaches is given
The impact of ‘exile’ on thought: Plotinus, Derrida and Gnosticism
This article examines the impact of ‘exile’ – as an individual or collective experience – on how human experience is theorized. The relationship between ‘exile’ and thought is initially approached historically by looking at the period that Eric Dodds famously called the ‘age of anxiety’ in late antiquity, i.e. the period between the emperors Aurelius and Constantine. A particular interest is in the dynamics of ‘empire’ and the concomitant religious ferment as a context in which ‘exile’, both experientially and symbolically, appears to assume an overbearing significance. Plotinus’ narrative of emanation and epistrophe as well as a group of narratives often classified as ‘Gnosticism’ are juxtaposed as two radical examples of a wider spiritual trend at the time according to which ‘exile’ could be considered constitutive of human experience. By way of an historical analogy, the insights gained from this study of late antiquity are then used to guide an analysis of the current, ‘restless’ epoch, in which experiences of displacement and exile on a mass scale undermine traditional notions of belonging, thus reviving the gnostic vision of cosmic reality as an alien, exilic environment. The article concludes with a discussion of Jacques Derrida’s work as an example of contemporary gnosticism, in which a ‘metaphysics of exile’ is presented in the disguise of an ‘exile from metaphysics’
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