239 research outputs found
Initial static susceptibilities of nonuniform and random Ising chains
Within the conventional framework of standard linear response theory we have
derived exact results for the initial static susceptibilities of nonuniform
spin-1/2 Ising chains. The results obtained permit one to study regularly
alternating-bond and random-bond Ising chains. The influence of several types
of nonuniformity and disorder on the temperature dependence of the initial
longitudinal and transverse static susceptibilities is discussed.Comment: LaTeX, 7 figure
Molecular Mechanism for the Hofmeister Effect Derived from NMR and DSC Measurements on Barnase
The effects of sodium thiocyanate, sodium chloride, and sodium sulfate on the ribonuclease barnase were studied using differential scanning calorimetry (DSC) and NMR. Both measurements reveal specific and saturable binding at low anion concentrations (up to 250 mM), which produces localized conformational and energetic effects that are unrelated to the Hofmeister series. The binding of sulfate slows intramolecular motions, as revealed by peak broadening in 13 C heteronuclear single quantum coherence spectroscopy. None of the anions shows significant binding to hydrophobic groups. Above 250 mM, the DSC results are consistent with the expected Hofmeister effects in that the chaotropic anion thiocyanate destabilizes barnase. In this higher concentration range, the anions have approximately linear effects on protein NMR chemical shifts, with no evidence for direct interaction of the anions with the protein surface. We conclude that the effects of the anions on barnase are mediated by solvent interactions. The results are not consistent with the predictions of the preferential interaction, preferential hydration, and excluded volume models commonly used to describe Hofmeister effects. Instead, they suggest that the Hofmeister anion effects on both stability and solubility of barnase are due to the way in which the protein interacts with water molecules, and in particular with water dipoles, which are more ordered around sulfate anions and less ordered around thiocyanate anions
Dilogarithm Identities in Conformal Field Theory and Group Homology
Recently, Rogers' dilogarithm identities have attracted much attention in the
setting of conformal field theory as well as lattice model calculations. One of
the connecting threads is an identity of Richmond-Szekeres that appeared in the
computation of central charges in conformal field theory. We show that the
Richmond-Szekeres identity and its extension by Kirillov-Reshetikhin can be
interpreted as a lift of a generator of the third integral homology of a finite
cyclic subgroup sitting inside the projective special linear group of all real matrices viewed as a {\it discrete} group. This connection
allows us to clarify a few of the assertions and conjectures stated in the work
of Nahm-Recknagel-Terhoven concerning the role of algebraic -theory and
Thurston's program on hyperbolic 3-manifolds. Specifically, it is not related
to hyperbolic 3-manifolds as suggested but is more appropriately related to the
group manifold of the universal covering group of the projective special linear
group of all real matrices viewed as a topological group. This
also resolves the weaker version of the conjecture as formulated by Kirillov.
We end with the summary of a number of open conjectures on the mathematical
side.Comment: 20 pages, 2 figures not include
Adsorption of Reactive Particles on a Random Catalytic Chain: An Exact Solution
We study equilibrium properties of a catalytically-activated annihilation reaction taking place on a one-dimensional chain of length () in which some segments (placed at random, with mean concentration
) possess special, catalytic properties. Annihilation reaction takes place,
as soon as any two particles land onto two vacant sites at the extremities
of the catalytic segment, or when any particle lands onto a vacant site on
a catalytic segment while the site at the other extremity of this segment is
already occupied by another particle. Non-catalytic segments are inert with
respect to reaction and here two adsorbed particles harmlessly coexist. For
both "annealed" and "quenched" disorder in placement of the catalytic segments,
we calculate exactly the disorder-average pressure per site. Explicit
asymptotic formulae for the particle mean density and the compressibility are
also presented.Comment: AMSTeX, 27 pages + 4 figure
Thermodynamical Bethe Ansatz and Condensed Matter
The basics of the thermodynamic Bethe ansatz equation are given. The simplest
case is repulsive delta function bosons, the thermodynamic equation contains
only one unknown function. We also treat the XXX model with spin 1/2 and the
XXZ model and the XYZ model. This method is very useful for the investigation
of the low temperature thermodynamics of solvable systems.Comment: 52 pages, 6 figures, latex, lamuphys.st
Dynamics of Phase Transitions by Hysteresis Methods I
In studies of the QCD deconfining phase transition or crossover by means of
heavy ion experiments, one ought to be concerned about non-equilibrium effects
due to heating and cooling of the system. Motivated by this, we look at
hysteresis methods to study the dynamics of phase transitions. Our systems are
temperature driven through the phase transition using updating procedures in
the Glauber universality class. Hysteresis calculations are presented for a
number of observables, including the (internal) energy, properties of
Fortuin-Kasteleyn clusters and structure functions. We test the methods for 2d
Potts models, which provide a rich collection of phase transitions with a
number of rigorously known properties. Comparing with equilibrium
configurations we find a scenario where the dynamics of the transition leads to
a spinodal decomposition which dominates the statistical properties of the
configurations. One may expect an enhancement of low energy gluon production
due to spinodal decomposition of the Polyakov loops, if such a scenario is
realized by nature.Comment: 12 pages, revised after referee report, to appear in Phys. Rev.
Adjustment to colostomy: stoma acceptance, stoma care self-efficacy and interpersonal relationships
‘The definitive version is available at www.blackwell-synergy.com.’ Copyright Blackwell Publishing. DOI: 10.1111/j.1365-2648.2007.04446.xThis paper is a report of a study to examine adjustment and its relationship with stoma acceptance and social interaction, and the link between stoma care self-efficacy and adjustment in the presence of acceptance and social interactions.Peer reviewe
Calibrating and adjusting expectations in life: A grounded theory on how elderly persons with somatic health problems maintain control and balance in life and optimize well-being
Aim: This study aims at exploring the main concern for elderly individuals with somatic health problems and what they do to manage this. Method: In total, 14 individuals (mean = 74.2 years; range = 68–86 years) of both gender including hospitalized and outpatient persons participated in the study. Open interviews were conducted and analyzed according to grounded theory, an inductive theory-generating method. Results: The main concern for the elderly individuals with somatic health problems was identified as their striving to maintain control and balance in life. The analysis ended up in a substantive theory explaining how elderly individuals with somatic disease were calibrating and adjusting their expectations in life in order to adapt to their reduced energy level, health problems, and aging. By adjusting the expectations to their actual abilities, the elderly can maintain a sense of that they still have the control over their lives and create stability. The ongoing adjustment process is facilitated by different strategies and result despite lower expectations in subjective well-being. The facilitating strategies are utilizing the network of important others, enjoying cultural heritage, being occupied with interests, having a mission to fulfill, improving the situation by limiting boundaries and, finally, creating meaning in everyday life. Conclusion: The main concern of the elderly with somatic health problems was to maintain control and balance in life. The emerging theory explains how elderly people with somatic health problems calibrate their expectations of life in order to adjust to reduced energy, health problems, and aging. This process is facilitated by different strategies and result despite lower expectation in subjective well-being
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