Ion exchange removal of Cu(II), Fe(II), Pb(II) and Zn(II) from acid extracted sewage sludge – Resin screening in weak acid media

A shortage of phosphate rock resources has led to a focus on the use of sewage sludge as a fertiliser. One factor preventing the unlimited application of sewage sludge in agriculture is the heavy metal content. This work looks at a process where weak acid leaching of sewage sludge would be coupled to ion exchange (IX) for heavy metal ion removal. IX offers an effective method for the recovery of these metals from a leachate. This study presents the pH performance of six selected IX resins in extracting Cu2+, Fe2+, Pb2+ and Zn2+ from acetic, lactic and citric acid media simulated weak acid leachate. Acetic acid media displayed limited suppression of metal extraction, whilst lactic and citric acid media rendered MTS9100 ineffective. Lactic acid media when combined with C107E resin allows for the targeted extraction of lead. Both MTS9570 and MTS9501 display high ferrous extraction in all media at all pH values, although citric acid hinders extraction by both resins at higher pH values. TP214 is selective for copper over all other metal ions in all weak acid media. MTS9301 is the most effective at extracting all metals from all media solutions, with separation of copper becoming more apparent when transitioning to citric acid

The management of tree genetic resources and the livelihoods of rural communities in the tropics: non-timber forest products, smallholder agroforestry practices and tree commodity crops

Products and services provided by trees in forests and farmland support the needs and promote the wellbeing of hundreds of millions of people in the tropics. Value depends on managing both the diversity of tree species present in landscapes and the genetic variation within these species. The benefits from trees and their genetic resources are, however, often not well quantified because trade is frequently outside formal markets, there is a multiplicity of species and ways in which trees are used and managed, and genetic diversity within species is frequently not given proper consideration. We review here what is known about the value of trees to rural communities through considering three production categories: non-timber products harvested from trees in natural and managed forests and woodlands; the various products and services obtained from a wide range of trees planted and/or retained in smallholders’ agroforestry systems; and the commercial products harvested from cultivated tree commodity crops. Where possible, we focus on the role of intra-specific genetic variation in providing support to livelihoods, and for each of the three production categories we also consider wider conservation and sustainability issues, including the linkages between categories in terms of management. Challenges to ‘conventional wisdom’ on tree resource use, value and management – such as in the posited links between commercialisation, cultivation and conservation – are highlighted, and constraints and opportunities to maintain and enhance value are described

Single metal isotherm study of the ion exchange removal of Cu(II), Fe(II), Pb(II) and Zn(II) from synthetic acetic acid leachate

A large predicted increase in population growth and dwindling phosphate resources has led to sewage sludge being an attractive alternative to commercial fertilisers. Among other contaminants, heavy metals are a barrier to unrestricted use of sewage sludge or sewage sludge ash as a phosphate source. This study will focus on the equilibrium isotherm behaviours of Cu2+, Fe2+, Pb2+ and Zn2+ towards C107E, MTS9301 and TP214 resins within acetic acid media, fit to the two parameter Freundlich, Langmuir, Temkin and Dubinin-Radushkevich (D-R) isotherm models. C107E and MTS9301 were both found to have comparable monolayer capacities for Cu2+ and Fe2+ (5±1 vs 4.3±0.7mmol · g−1 and 2.1±0.8 vs 2.3±0.8mmol · g−1 for Cu2+ and Fe2+, respectively). The Freundlich model implied heterogeneous binding for Pb2+ and Zn2+ adsorption to C107E and MTS9301. The monolayer capacities of MTS9301 for lead and zinc were calculated as 2.1±0.2mmol · g−1 and 3±1mmol · g−1, respectively. MTS9301 returned larger D-R free energy values than C107E, with the largest difference being Zn2+, displaying energies of 14.0 and 5.5kJ · mol−1, respectively. TP214 displayed the lowest capacity for metals with Fe2+, Pb2+ and Zn2+ returning D-R energy values closer to physisorption mechanisms (6.0±0.5, 7.1±0.4 and 7.8±0.5kJ · mol−1, respectively), with copper returning a D-R energy relating to chemisorption (17±1kJ · mol−1). Overall, it was observed that the similarity of the C107E functionality to the free acetate anion led to the highest level of hindrance, seconded by the interaction between Fe2+, Pb2+ and Zn2+ to TP214, while copper displayed strong interaction with TP214 and MTS9301 displayed little or no hindrance by the acetate complexes in solution, with solution phase complexes affecting the homogeneity of binding within any ion exchange reaction

Adsorption studies of a multi-metal system within acetate media, with a view to sustainable phosphate recovery from sewage sludge

Phosphate shortages and the ensuing pressures on food security have led to an interest in processed sewage sludge as a substitute for commercial fertilisers. The presence of heavy metals in this nutrient source causes concerns around environmental release and pollution. This work builds towards a resin-in-pulp sludge detoxification process. It showcases the kinetic and thermodynamic adsorption capabilities of the ion-exchange resins C107E (carboxylic acid functionality), MTS9301 (iminodiacetic acid) and TP214 (thiourea), with respect to Cu(II), Fe(II), Pb(II) and Zn(II), within a simulated sewage sludge weak acid (acetate) leachate. The isotherms produced in this complex system were quite different to those generated when single metals were investigated in isolation, with desorption of lower affinity species clearly observed at higher equilibrium concentration values. Mixed-metal isotherm data were fitted to common two-parameter isotherm models and also a novel modified Langmuir model, which better accounted for the effects of desorption and competition. Kinetic data were also fit to common two-parameter models; results suggesting the system was likely film diffusion-controlled and followed pseudo-2nd-order kinetics. C107E displayed rapid adsorption of lead (t1/2 = 26 ± 3min), and significant uptake of all metals. MTS9301 showed high affinity for copper ions, with concurrent desorption of all the other metals, and also displayed the fastest kinetics (t1/2 = 14.1 ± 0.9, 130 ± 20, 25 ± 5 and 49 ± 6 min for copper, iron(II), lead and zinc, respectively). C107E and MTS9301 showed far slower adsorption for iron(II) than the other three metals, which invited the possibility of kinetic separations. TP214 had reasonable effectiveness in removal of copper, but poor affinity for all other metals. The greatest difficulty in modelling the multi-metal system was the two-stage trends observed in equilibrium experiments, as metal-proton exchanges become metal-metal exchanges. While not having the highest capacity, MTS9301 was recommended as the most appropriate resin for rapid and efficient removal of Cu, Pb and Zn from the acetate medium

A microscopic estimate of the nuclear matter compressibility and symmetry energy in relativistic mean-field models

The relativistic mean-field plus RPA calculations, based on effective Lagrangians with density-dependent meson-nucleon vertex functions, are employed in a microscopic analysis of the nuclear matter compressibility and symmetry energy. We compute the isoscalar monopole and the isovector dipole response of $^{208}$Pb, as well as the differences between the neutron and proton radii for $^{208}$Pb and several Sn isotopes. The comparison of the calculated excitation energies with the experimental data on the giant monopole resonance in $^{208}$Pb, restricts the nuclear matter compression modulus of structure models based on the relativistic mean-field approximation to $K_{\rm nm}\approx 250 - 270$ MeV. The isovector giant dipole resonance in $^{208}$Pb, and the available data on differences between neutron and proton radii, limit the range of the nuclear matter symmetry energy at saturation (volume asymmetry) to 32 MeV $\leq a_4 \leq$ 36 MeV.Comment: 16 pages, 6 figure

Spatio-temporal processes drive fine-scale genetic structure in an otherwise panmictic seabird population

When and where animals breed can shape the genetic structure and diversity of animal populations. The importance of drivers of genetic diversity is amplified in island populations that tend to have more delineated gene pools compared to continental populations. Studies of relatedness as a function of the spatial distribution of individuals have demonstrated the importance of spatial organisation for individual fitness with outcomes that are conditional on the overall genetic diversity of the population. However, few studies have investigated the impact of breeding timing on genetic structure. We characterise the fine-scale genetic structure of a geographically-isolated population of seabirds. Microsatellite markers provide evidence for largely transient within-breeding season temporal processes and limited spatial processes, affecting genetic structure in an otherwise panmictic population of sooty terns Onychoprion fuscatus. Earliest breeders had significantly different genetic structure from the latest breeders. Limited evidence was found for localised spatial structure, with a small number of individuals being more related to their nearest neighbours than the rest of the population. Therefore, population genetic structure is shaped by heterogeneities in collective movement in time and to a lesser extent space, that result in low levels of spatio-temporal genetic structure and the maintenance of genetic diversity

Relativistic Random-Phase Approximation with density-dependent meson-nucleon couplings

The matrix equations of the relativistic random-phase approximation (RRPA) are derived for an effective Lagrangian characterized by density-dependent meson-nucleon vertex functions. The explicit density dependence of the meson-nucleon couplings introduces rearrangement terms in the residual two-body interaction, that are essential for a quantitative description of excited states. Illustrative calculations of the isoscalar monopole, isovector dipole and isoscalar quadrupole response of $^{208}$Pb, are performed in the fully self-consistent RRPA framework, based on effective interactions with a phenomenological density dependence adjusted to nuclear matter and ground-state properties of spherical nuclei. The comparison of the RRPA results on multipole giant resonances with experimental data constrains the parameters that characterize the isoscalar and isovector channel of the density-dependent effective interactions.Comment: RevTeX, 8 eps figures, submitted to Phys. Rev.

An horizon scan of biogeography

The opportunity to reflect broadly on the accomplishments, prospects, and reach of a field may present itself relatively infrequently. Each biennial meeting of the International Biogeography Society showcases ideas solicited and developed largely during the preceding year, by individuals or teams from across the breadth of the discipline. Here, we highlight challenges, developments, and opportunities in biogeography from that biennial synthesis. We note the realized and potential impact of rapid data accumulation in several fields, a renaissance for inter-disciplinary research, the importance of recognizing the evolution-ecology continuum across spatial and temporal scales and at different taxonomic, phylogenetic and functional levels, and re-exploration of classical assumptions and hypotheses using new tools. However, advances are taxonomically and geographically biased, and key theoretical frameworks await tools to handle, or strategies to simplify, the biological complexity seen in empirical systems. Current threats to biodiversity require unprecedented integration of knowledge and development of predictive capacity that may enable biogeography to unite its descriptive and hypothetico-deductive branches and establish a greater role within and outside academia

Footprints of the Beyond in flavor physics: Possible role of the Top Two Higgs Doublet Model

The B-factories results provide an impressive confirmation of the Standard Model (SM) description of flavor and CP violation. Nevertheless, as more data were accumulated, deviations in the 2.5-3.5 sigma range have emerged pointing to the exciting possibility of new CP-odd phase(s) and flavor violating parameters in B-decays. Primarily this seems to be the case in the time dependent CP asymmetries in penguin dominated modes (e.g. B -> phi (eta') Ks). We discuss these and other deviations from the SM and, as an illustration of possible new physics scenarios, we examine the role of the Top Two Higgs Doublet Model. This is a simple extension of the SM obtained by adding second Higgs doublet in which the Yukawa interactions of the two Higgs doublets are assigned in order to naturally account for the large top-quark mass. Of course, many other extensions of the Standard Model could also account for these experimental deviations. Clearly if one takes these deviations seriously then some new particles in the 300 GeV to few TeV with associated new CP-odd phase(s) are needed.Comment: 40 pages, 17 figures (png format), uses pdflate

Dynamical Systems approach to Saffman-Taylor fingering. A Dynamical Solvability Scenario

A dynamical systems approach to competition of Saffman-Taylor fingers in a channel is developed. This is based on the global study of the phase space structure of the low-dimensional ODE's defined by the classes of exact solutions of the problem without surface tension. Some simple examples are studied in detail, and general proofs concerning properties of fixed points and existence of finite-time singularities for broad classes of solutions are given. The existence of a continuum of multifinger fixed points and its dynamical implications are discussed. The main conclusion is that exact zero-surface tension solutions taken in a global sense as families of trajectories in phase space spanning a sufficiently large set of initial conditions, are unphysical because the multifinger fixed points are nonhyperbolic, and an unfolding of them does not exist within the same class of solutions. Hyperbolicity (saddle-point structure) of the multifinger fixed points is argued to be essential to the physically correct qualitative description of finger competition. The restoring of hyperbolicity by surface tension is discussed as the key point for a generic Dynamical Solvability Scenario which is proposed for a general context of interfacial pattern selection.Comment: 3 figures added, major rewriting of some sections, submitted to Phys. Rev.