Detrital zircon from a late Paleozoic accretionary complex of SW Iberia (Variscan Belt): History of crustal growth and recycling at the Rheic convergent margin

In this study we present new U-Pb ages of detrital zircons from greywackes and quartzites of the Pulo do Lobo Anticline (PLA) that have been interpreted to represent a Late Paleozoic accretionary complex in SW Iberia. The PLA separates the Ossa Morena Zone, which has a North- Gondwana affinity throughout Late Ediacaran and Early Paleozoic times, from the South Portuguese Zone, which is considered to be underlain by Laurussia basement. The PLA stratigraphy most likely represents a synorogenic basin that records the closure of the Late Paleozoic Rheic Ocean and the amalgamation of Pangaea. The youngest formations of the PLA contain upper Devonian microfossils.The results obtained indicate that the detrital zircons from the PLA represent a wide range of Precambrian and Paleozoic crystallization ages. Recycling of older sedimentary units of the Late Ediacaran active margin (Cadomian/Pan-African orogenies) as well as of the Early Paleozoic rifting and passive margin (Rheic Ocean) stages, accounts for the older populations with North-Gondwana affinity (Cambrian, Neoproterozoic, Paleoproterozoic and Archean, with a gap of Mesoproterozoic-age). However, the Mesoproterozoic detrital zircon ages found in the greywackes of the Pulo do Lobo Formation (< 7%) that do not correspond to any substantial source within North-Gondwana, could come from recycled sedimentary deposits or from denudation of Grenville-age basement (Laurussia?). The more recent formations present in the northern limb (Ferreira-Ficalho Group) of the PLA show a significant age cluster in the upper Devonian (c. 378 Ma), whereas on the southern limb (Chança Group), samples have from base to top of the stratigraphic sequence: a minor age cluster in the middle Devonian (c. 390 Ma), a significant age cluster in upper Devonian (c. 380 Ma) and very significant age cluster in the upper Devonian (c. 372 Ma). The presence of middle-upper Devonian detrital zircons in combination with very low abundances of Mesoproterozoic detrital zircon suggests that the PLA sedimentary rocks were not derived from exotic sources but rather have a North-Gondwanan origin. The zircon population in the interval c. 390-380 Ma has no identified corresponding magmatic or stratigraphic source in SW Iberia. Considering that, during the development of the upper Devonian basins of SW Iberia, Laurussia basement was not exposed and that there was no magmatic arc on the North-Gondwana margin, we suggest that the c. 390- 380 Ma detrital zircons are most probably derived from denudation of a (intra-oceanic) magmatic arc related to the closure of the Rheic Ocean

Population expansion in the North African Late Pleistocene signalled by mitochondrial DNA haplogroup U6

Background &lt;br/&gt; The archaeology of North Africa remains enigmatic, with questions of population continuity versus discontinuity taking centre-stage. Debates have focused on population transitions between the bearers of the Middle Palaeolithic Aterian industry and the later Upper Palaeolithic populations of the Maghreb, as well as between the late Pleistocene and Holocene. &lt;br/&gt; Results Improved resolution of the mitochondrial DNA (mtDNA) haplogroup U6 phylogeny, by the screening of 39 new complete sequences, has enabled us to infer a signal of moderate population expansion using Bayesian coalescent methods. To ascertain the time for this expansion, we applied both a mutation rate accounting for purifying selection and one with an internal calibration based on four approximate archaeological dates: the settlement of the Canary Islands, the settlement of Sardinia and its internal population re-expansion, and the split between haplogroups U5 and U6 around the time of the first modern human settlement of the Near East. &lt;br/&gt; Conclusions &lt;br/&gt; A Bayesian skyline plot placed the main expansion in the time frame of the Late Pleistocene, around 20 ka, and spatial smoothing techniques suggested that the most probable geographic region for this demographic event was to the west of North Africa. A comparison with U6's European sister clade, U5, revealed a stronger population expansion at around this time in Europe. Also in contrast with U5, a weak signal of a recent population expansion in the last 5,000 years was observed in North Africa, pointing to a moderate impact of the late Neolithic on the local population size of the southern Mediterranean coast

U-Pb geochronology of the El Jadida rhyolite and relation to possible Lower Cambrian recycling (Coastal block, Moroccan Meseta).

The El Jadida (Mazagan) dome, whose existence was reported as early as 1934 by Yovanovitch and Freys, constitutes one of the first outcrops of the Moroccan Meseta where the Precambrian (PIII?)-Paleozoic (Lower Cambrian?) boundary was established (Gigout, 1951; Cornée et al., 1984). Since then, it is listed as one of the few locations where the basement of the Moroccan Variscan belt can be observed (Hoepffner et al.. 2005; Michard et al., 2010).Despite, the absence of geochronological and biostratigraphic precise data to constrain the time interval recorded here, there are stratigraphic similarities that allow a correlation with the Ediacaran-Cambrian geological record of Anti-Atlas belt (Cornée et al., 1984). In this study, we developed a petrographic, geochemical and U-Pb geochronological study using zircon extracted from: (i) the El Jadida rhyolite with the aim of characterizing the magma source and estimate the age of crystallization; (ii) a microbreccia sampled at the base of the El Jadida Dolomitic Formation for determining provenance

Sedimentary provenance of siliciclastic rocks from the Lalla Mouchaa Calcschists Formation (Coastal Block, Western Rehamna): Evidence of denudation of ca. 2 Ga basement in the Moroccan Meseta.

Paleoproterozoic basement rocks (ca. 2Ga) are scarce along the European and North African Paleozoic mountain chains (Fig.1a). In Morocco, ca. 2.2-2Ga granitic rocks (Gasquet et al., 2008; Kouyaté et al., 2013) have been exclusively reported in the Western Anti-Atlas at southwest of the Anti-Atlas Major Fault, (Choubert, 1963). In Eastern and Central Anti-Atlas and in the Moroccan Meseta, the existence of a Paleoproterozoic basement has only been recognized through indirect evidence (Gasquet et al., 2008; Michard et al., 2010). In the Anti- Atlas belt, ca. 2Ga detrital zircon grains are found in the Ediacaran siliciclastic rocks of the Bou Salda, Saghro and Taghdout groups (Abati et al., 2010). In the Moroccan Meseta, Paleoproterozoic (ca. 2Ga) zircon grains were extracted from gneiss and granitic xenoliths found in Triassic lamprophyre dykes, and from Carboniferous granophyric microgranite intrusions of central Jebilet (Dostal et al., 2005, Essaifi et al., 2003). Recently, a porphyritic rhyolite from the Rehamna Massif was dated at ca. 2.05Ga (Pereira et al., 2015), demonstrating for the first time, the exposure of the Eburnian basement in the Western Meseta. These Eburnian arc-related magmatic rocks, which are exposed to the south of the Permian Sebt Brikiyine granite in the core of anticlines from the Lalla Mouchaa Anticlinorium, are allegedly unconformably overlained by transgressive siliciclastic and carbonate beds (Corsini, 1988; Pereira et al., 2015). At north of the Sebt Brikiyine granite the probable Lower Cambrian sequence (Lalla Mouchaa Calcschists Formation; Guezou & Michard, 1976; Corsini, 1988) comprises a basal unit of microbreccias, arkosic sandstones and siltstones (lower member) that pass towards the top to centimeter-thick beds of calcschists interbedded with limestones and dolomites (upper member) that are conformably overlain by the “Paradoxides Shale Formation” composed of siltstone, greywacke and sandstone with Middle Cambrian fauna. In order to study the potential sources of the Lalla Mouchaa Calcschists Formation (probable Lower Cambrian), we have sampled a microbreccia at the Koudiat El Hamra region, for U-Pb geochronology on detrital zircon. This foliated microbreccia is composed of elongated Kfeldspar and quartz phenocrysts surrounded by a fine-grained matrix. Detrital zircon grains gave 206Pb/238Ub ages that in the Probability density plot curve are distributed by two main age peaks at ca. 2.05Ga and ca. 2.03Ga (Fig.1b), yielding a 206Pb/238U age-weighted mean of ca. 2.04Ga (El Houicha et al., 2018). The obtained U-Pb results point to a provenance from a Paleoproterozoic source, suggesting a possible contribution from rocks of the same age of the 2Ga porphyritic rhyolite exposed at south of the Sebt Brikiyine granite. Thus, there is a possibility that the Paleoproterozoic basement extends bellow the Paleozoic and Neoproterozoic sequences of the Rehamna massif

Time-space distribution of silicic plutonism in a gneiss dome of the Iberian Variscan Belt: The Évora Massif (Ossa-Morena Zone, Portugal)

In the Iberian Variscan Belt, polyphasic deformation has been recognized as comprising an early phase of crustal thickening, followed by an intermediate phase of crustal extension and doming, and a later phase of shortening. The Évora Massif is a gneiss dome of the westernmost domains of the Ossa-Morena Zone (SW Iberia), which provides a remarkable insight into the late Paleozoic deep crustal structure of the Variscan continental crust of northern Gondwana. In this study, we bring new structural and geochronological U-Pb data for the northern hanging-wall of the Évora Massif. We describe the existence of low-dipping D2 extensional shear zones associated with Buchan-type metamorphism (M2); this enables three tectono-metamorphic units to be distinguished: the Lower Gneiss Unit, the Intermediate Schist Unit, and the Upper Slate Unit. D2-M2 structures experienced sub- horizontal shortening (D3) and were transposed by low-plunging folding, thrusting and strike-slip faulting. Zircon grains extracted from Pavia quartz-feldspathic gneiss of the Lower Gneiss Unit yielded a crystallization age of ca. 521 Ma (Cambrian Stage 2–3), which establishes a correlation with tectono-metamorphic units of the footwall and southern hanging-wall of the Évora Massif. U-Pb zircon dating of Divôr foliated quartz-diorite (339 ± 7 Ma), Malarranha weakly foliated biotite-rich granite (322 ± 3 Ma), and undeformed porphyritic granite of the Pavia pluton (314 ± 4 Ma) constrain the timing of emplacement of granitic magmas synchro- nously with doming. Carboniferous magmatism initiated with doming (ME1 - ca. 343–335 Ma), continued through D2-M2 (ME2 - ca. 328–319 Ma), and lasted until the waning stage of crustal extension (ME3 - ca. 317–313 Ma). The Évora Massif gneiss dome probably formed as result of the combined effect of gravitational collapse of the thickened crust and buoyancy-driven gravitational instability developed in the partially molten continental crust influenced by the transfer of heat from rising mantle-derived (i.e. dioritic-gabbroic) magmas rocks found in the footwall of the Évora Massif

Age of the basement beneath the Mesozoic Lusitanian Basin revealed by granitic xenoliths from the Papôa volcanic breccia (West Iberia)

The dyke of the Papôa volcanic breccia cross-cutting the Lower Jurassic sequence of the Lusitanian Basin (West Iberia) contains granitic xenoliths. In this study, for the first time, U-Th-Pb zircon analysis of two xenoliths yielded 298 ± 4 Ma for biotite granite and of 292 ± 2 Ma for two-mica granite, indicating that the pre-Mesozoic basement of the Lusitanian Basin includes Permian intrusions. These ages are close within the margin of error of the age of the Late Carboniferous granites of the Berlengas isle that with the Late Devonian high-grade metamorphic rocks of the Farilhões isles, located northwest of the study area, which form the pre-Mesozoic basement of the Lusitanian Basin. These new geochronological findings enable it to be established that Permo-Carboniferous magmatism lasted at least 13 Ma, in this region of the Appalachian-Variscan belt. Furthermore, a comparison with available data from Paleozoic tectonic units of the Appalachian-Variscan belt located both in the Iberian Massif and outside it enables the suggestion to be made that the Lusitanian Basin (Peniche) most probably rests on the South Portuguese Zone, which may also be correlated with the Rhenohercynian Zone present in southwest England, and the Meguma terrane of Nova Scotia

Age of the basement beneath the Mesozoic Lusitanian Basin revealed by granitic xenoliths from the Papôa volcanic breccia (West Iberia)

The dyke of the Papôa volcanic breccia cross-cutting the Lower Jurassic sequence of the Lusitanian Basin (West Iberia) contains granitic xenoliths. In this study, for the first time, U-Th-Pb zircon analysis of two xenoliths yielded 298±4Ma for biotite granite and of 292±2Ma for two-mica granite, indicating that the pre-Mesozoic basement of the Lusitanian Basin includes Permian intrusions. These ages are close within the margin of error of the age of the Late Carboniferous granites of the Berlengas isle that with the Late Devonian high-grade metamorphic rocks of the Farilhões isles, located northwest of the study area, which form the pre-Mesozoic basement of the Lusitanian Basin. These new geochronological findings enable it to be established that Permo-Carboniferous magmatism lasted at least 13Ma, in this region of the Appalachian-Variscan belt. Furthermore, a comparison with available data from Paleozoic tectonic units of the Appalachian-Variscan belt located both in the Iberian Massif and outside it enables the suggestion to be made that the Lusitanian Basin (Peniche) most probably rests on the South Portuguese Zone, which may also be correlated with the Rhenohercynian Zone present in southwest England, and the Meguma terrane of Nova Scotia

Simulation of the soil water balance of wheat using daily weather forecast messages to estimate the reference evapotranspiration

Abstract. Aiming at developing real time water balance modelling for irrigation scheduling, this study assesses the accuracy of using the reference evapotranspiration (ETo) estimated from daily weather forecast messages (ETo,WF) as model input. A previous study applied to eight locations in China (Cai et al., 2007) has shown the feasibility for estimating ETo,WF with the FAO Penman-Monteith equation using daily forecasts of maximum and minimum temperature, cloudiness and wind speed. In this study, the global radiation is estimated from the difference between the forecasted maximum and minimum temperatures, the actual vapour pressure is estimated from the forecasted minimum temperature and the wind speed is obtained from converting the common wind scales into wind speed. The present application refers to a location in the North China Plain, Daxing, for the wheat crop seasons of 2005–2006 and 2006–2007. Results comparing ETo,WF with ETo computed with observed data (ETo,obs) have shown favourable goodness of fitting indicators and a RMSE of 0.77mmd−1. ETo was underestimated in the first year and overestimated in the second. The water balance model ISAREG was calibrated with data from four treatments for the first season and validated with data of five treatments in the second season using observed weather data. The calibrated crop parameters were used in the simulations of the same treatments using ETo,WF as model input. Errors in predicting the soil water content are small, 0.010 and 0.012m3 m−3, respectively for the first and second year. Other indicators also confirm the goodness of model predictions. It could be concluded that using ETo computed from daily weather forecast messages provides for accurate model predictions and to use an irrigation scheduling model in real tim

Revisiting the Ediacaran-Cambrian boundary in the Ossa-Morena Zone (SW Iberia)

Some of the best outcrops of Iberia to study the Ediacaran-Cambrian boundary are located in the Ossa- Morena Zone. In the Crato-Campo Maior region (SW Iberia, Portugal), this stratigraphic boundary is marked by an angular unconformity (Gonçalves, 1971). The Ediacaran sedimentary rocks of the Série Negra Group (maximum depositional age of c. 545 Ma; Linnemann et al., 2008) are overlain by Early Cambrian strata. A folded foliation has been recognized in the Ediacaran metagreywackes, metapelites, black metachert, marbles and metabasic rocks (Pereira & Silva, 2002). This deformation event is previous to the intrusion of c. 526-525 Ma granitic rocks (Barquete and Barreiros plutons; Pereira et al., 2011; Sánchez-García et al., 2013), and is not represented in the unconformable overlying Early Cambrian strata including sandstone (maximum depositional age of c. 532 Ma; Pereira et al., 2011). At the base of the lower Cambrian stratigraphic section there is the Freixo-Segóvia volcanosedimentary complex consisting of felsic tuff interbedded with conglo-merate and rhyolitic-dacitic lava flow (Pereira et al., 2006). The conglomerate is composed of pebbles of volcanic rock (basalt, rhyolite, dacite and mafic and felsic tuff), granitic rocks, chert, quartzite, arkosic sandstone, greywacke and shale in a tuffaceous sandy matrix. This volcano-sedimentary complex is overlain by a sequence of sandstone and shale passing vertically to limestone beds which have been attributed to the lower Cambrian (Pereira et al., 2006) (see Fig. 12). An ongoing research project intends to date the volcanic rocks of the volcano-sedimentary complex using U-Pb zircon geochronology. The absolute dates determined from these volcanic rocks will provide the time framework for the calibration of the existing stratigraphic scheme based on regional correlation

Hybrid molecular dynamic Monte Carlo simulation and experimental production of a multi-component Cu-Fe-Ni-Mo-W alloy

ABSTRACT: High-entropy alloys are a class of materials intensely studied in the last years due to their innovative properties. Their unconventional compositions and chemical structures hold promise for achieving unprecedented combinations of mechanical properties. The Cu-Fe-Ni-Mo-W multicomponent alloy was studied using a combination of simulation and experimental production to test the possibility of formation of a simple solid solution. Therefore, Molecular Dynamics and hybrid Molecular Dynamic/Monte Carlo simulations from 10K up to the melting point of the alloy were analyzed together with the experimental production by arc furnace and powder milling. The Molecular Dynamics simulations starting with a bcc type-structure show the formation of a singlephase bcc solid solution type-structure, whereas using Monte Carlo one, generally produced a two-phase mixture. Moreover, the lowest potential energy was obtained when starting from a fcc type-structure and using Monte Carlo simulation giving rise to the formation of a bcc Fe-Mo-W phase and a Cu-Ni fcc type-structure. Dendritic and interdendritic phases were observed in the sample produced by arc furnace while the milled powder evidence an separation of two phases Cu-Fe-Ni phase and W-Mo type-structures. Samples produced by both methods show the formation of bcc and a fcc type-structures. Therefore, the Monte Carlo simulation seems to be closer with the experimental results, which points to a two-phase mixture formation for the Cu-Fe-Ni-Mo-W multicomponent system.info:eu-repo/semantics/publishedVersio