Portable LED fluorescence instrumentation for the rapid assessment of potable water quality

Characterising the organic and microbial matrix of water are key issues in ensuring a safe potable water supply. Current techniques only confirm water quality retrospectively via laboratory analysis of discrete samples. Whilst such analysis is required for regulatory purposes, it would be highly beneficial to monitor water quality in-situ in real time, enabling rapid water quality assessment and facilitating proactive management of water supply systems. A novel LED-based instrument, detecting fluorescence peaks C and T (surrogates for organic and microbial matter, respectively), was constructed and performance assessed. Results from over 200 samples taken from source waters through to customer tap from three UK water companies are presented. Excellent correlation was observed between the new device and a research grade spectrophotometer (r 2 = 0.98 and 0.77 for peak C and peak T respectively), demonstrating the potential of providing a low cost, portable alternative fluorimeter. The peak C/TOC correlation was very good (r 2 = 0.75) at low TOC levels found in drinking water. However, correlations between peak T and regulatory measures of microbial matter (2 day/3 day heterotrophic plate counts (HPC), E. coli, and total coliforms) were poor, due to the specific nature of these regulatory measures and the general measure of peak T. A more promising correlation was obtained between peak T and total bacteria using flow cytometry. Assessment of the fluorescence of four individual bacteria isolated from drinking water was also considered and excellent correlations found with peak T (Sphingobium sp. (r 2 = 0.83); Methylobacterium sp. (r 2 = 1.0); Rhodococcus sp. (r 2 = 0.86); Xenophilus sp. (r 2 = 0.96)). It is notable that each of the bacteria studied exhibited different levels of fluorescence as a function of their number. The scope for LED based instrumentation for insitu, real time assessment of the organic and microbial matrix of potable water is clearly demonstrated

Tricritical scaling at the N_t=6 chiral phase transition for 2 flavour lattice QCD with staggered quarks

We have simulated lattice QCD directly in the chiral limit of zero quark mass by adding an additional, irrelevant 4-fermion interaction to the standard action. Using lattices having temporal extent of six and spatial extents of twelve and eighteen, we find that the theory with 2 massless staggered quark flavors has a second order finite temperature phase transition. The critical exponents $\beta_{mag}$, $\delta$ and $\nu$ are measured and favour tricritical behaviour over that expected by universality arguments. The pion screening mass is consistent with zero below the transition, but is degenerate with the nonzero $\sigma(f_0)$ mass above the transition, indicating the restoration of chiral symmetry.Comment: 12 pages, 3 postscript figures Letter has been rewritten to reflect a reinterpretation of our results as indicating tricritical critical indices rather than those predicted by standard universality arguments. Some additional analysis which supports this interpretation is included. The comparison of our methods with those of others has been expande

Finishing of precision generated metal optical components

Diamond turning and precision generation of aspheric metal surfaces has promoted a change in lapping techniques due to the extremely close figure tolerances and surface finishes that have been achieved. Special tooling, diamond abrasive, silicon oil and special techniques used to polish the unusual aspheric figures are described. The studies include small flat diamond turned samples of copper, electroplated copper, electroplated silver, electroplated nickel and silver as well as large aspheres such as an f/0.75, 35 cm dia copper ellipse. Results from cleaning studies on flat samples using ultrasonics and vapor degreasers are also summarized. Interferograms of wavefront distortion and analysis of focal volume are included as well as 10.6 $mu$m reflectivity and a summary of laser damage experiments. (TFD

Universal features of the order-parameter fluctuations : reversible and irreversible aggregation

We discuss the universal scaling laws of order parameter fluctuations in any system in which the second-order critical behaviour can be identified. These scaling laws can be derived rigorously for equilibrium systems when combined with the finite-size scaling analysis. The relation between order parameter, criticality and scaling law of fluctuations has been established and the connexion between the scaling function and the critical exponents has been found. We give examples in out-of-equilibrium aggregation models such as the Smoluchowski kinetic equations, or of at-equilibrium Ising and percolation models.Comment: 19 pages, 10 figure

Cloud microphysical effects of turbulent mixing and entrainment

Turbulent mixing and entrainment at the boundary of a cloud is studied by means of direct numerical simulations that couple the Eulerian description of the turbulent velocity and water vapor fields with a Lagrangian ensemble of cloud water droplets that can grow and shrink by condensation and evaporation, respectively. The focus is on detailed analysis of the relaxation process of the droplet ensemble during the entrainment of subsaturated air, in particular the dependence on turbulence time scales, droplet number density, initial droplet radius and particle inertia. We find that the droplet evolution during the entrainment process is captured best by a phase relaxation time that is based on the droplet number density with respect to the entire simulation domain and the initial droplet radius. Even under conditions favoring homogeneous mixing, the probability density function of supersaturation at droplet locations exhibits initially strong negative skewness, consistent with droplets near the cloud boundary being suddenly mixed into clear air, but rapidly approaches a narrower, symmetric shape. The droplet size distribution, which is initialized as perfectly monodisperse, broadens and also becomes somewhat negatively skewed. Particle inertia and gravitational settling lead to a more rapid initial evaporation, but ultimately only to slight depletion of both tails of the droplet size distribution. The Reynolds number dependence of the mixing process remained weak over the parameter range studied, most probably due to the fact that the inhomogeneous mixing regime could not be fully accessed when phase relaxation times based on global number density are considered.Comment: 17 pages, 10 Postscript figures (figures 3,4,6,7,8 and 10 are in reduced quality), to appear in Theoretical Computational Fluid Dynamic

Weak convergence of finite element approximations of linear stochastic evolution equations with additive noise II. Fully discrete schemes

We present an abstract framework for analyzing the weak error of fully discrete approximation schemes for linear evolution equations driven by additive Gaussian noise. First, an abstract representation formula is derived for sufficiently smooth test functions. The formula is then applied to the wave equation, where the spatial approximation is done via the standard continuous finite element method and the time discretization via an I-stable rational approximation to the exponential function. It is found that the rate of weak convergence is twice that of strong convergence. Furthermore, in contrast to the parabolic case, higher order schemes in time, such as the Crank-Nicolson scheme, are worthwhile to use if the solution is not very regular. Finally we apply the theory to parabolic equations and detail a weak error estimate for the linearized Cahn-Hilliard-Cook equation as well as comment on the stochastic heat equation

On the nature of the finite-temperature transition in QCD

We discuss the nature of the finite-temperature transition in QCD with N_f massless flavors. Universality arguments show that a continuous (second-order) transition must be related to a 3-D universality class characterized by a complex N_f X N_f matrix order parameter and by the symmetry-breaking pattern [SU(N_f)_L X SU(N_f)_R]/Z(N_f)_V -> SU(N_f)_V/Z(N_f)_V, or [U(N_f)_L X U(N_f)_R]/U(1)_V -> U(N_f)_V/U(1)_V if the U(1)_A symmetry is effectively restored at T_c. The existence of any of these universality classes requires the presence of a stable fixed point in the corresponding 3-D Phi^4 theory with the expected symmetry-breaking pattern. Otherwise, the transition is of first order. In order to search for stable fixed points in these Phi^4 theories, we exploit a 3-D perturbative approach in which physical quantities are expanded in powers of appropriate renormalized quartic couplings. We compute the corresponding Callan-Symanzik beta-functions to six loops. We also determine the large-order behavior to further constrain the analysis. No stable fixed point is found, except for N_f=2, corresponding to the symmetry-breaking pattern [SU(2)_L X SU(2)_R]/Z(2)_V -> SU(2)_V/Z(2)_V equivalent to O(4) -> O(3). Our results confirm and put on a firmer ground earlier analyses performed close to four dimensions, based on first-order calculations in the framework of the epsilon=4-d expansion. These results indicate that the finite-temperature phase transition in QCD is of first order for N_f>2. A continuous transition is allowed only for N_f=2. But, since the theory with symmetry-breaking pattern [U(2)_L X U(2)_R]/U(1)_V -> U(2)_V/U(1)_V does not have stable fixed points, the transition can be continuous only if the effective breaking of the U(1)_A symmetry is sufficiently large.Comment: 30 pages, 3 figs, minor correction

Integrating Maternal Depression Screening Into an Early Intervention Program: An Implementation Evaluation

Background: In all 50 states, early intervention (EI) services to improve long-term child cognitive and academic outcomes are provided to infants and toddlers with suspected or diagnosed developmental delays. When mothers of EI-enrolled children experience depressive symptoms, uptake of EI services can be compromised. Aims: The purpose of the article is to present a depressive symptom screening intervention for mothers consisting of toolkit development for EI staff and families, symptom screening for mothers and follow-up protocol. To formally evaluate the implementation of the intervention, our research team followed the consolidated framework for implementation research (CFIR). Methods: Participants were 12 EI service coordinators across two offices. Focus groups and individual interviews were used to develop the toolkit and education module. Through the five CFIR domains, we evaluated the implemented intervention in order to allow other teams to learn from our experiences. Results: Our team successfully partnered with SCs to develop the intended deliverables. Still, the SCs found it challenging to conduct the screenings and reported mixed success. Conclusions: Preparation of EI SCs to integrate mental health screenings into their existing skillsets requires a high level of support from the research team, resulting in a rich understanding of the barriers-and potential rewards-for staff and families

Striking divergences in Earth Observation products may limit their use for REDD+

Countries are required to generate baselines of carbon emissions, or Forest Reference Emission Levels, for implementing REDD+ under the United Nations Framework Convention on Climate Change and to access results-based payments. Developing these baselines requires accurate maps of carbon stocks and historical deforestation. Global remote sensing products provide low-cost solutions for this information, but there has been little validation of these products at national scales. This study compares the ability of currently available products obtained from remote sensing data to deliver estimates of deforestation and associated carbon emissions in Guinea-Bissau, a West African country encompassing the climate and vegetation gradients that are typical of sub-Saharan Africa. We show that disagreements in estimates of deforestation are striking, and this variation leads to high uncertainty in derived emissions. For Guinea-Bissau, we suggest that higher temporal resolution of remote sensing products is required to reduce this uncertainty by overcoming current limitations in differentiating deforestation from seasonality. In contrast, existing datasets of carbon stocks show better agreement, and contribute much less to the variation in estimated emissions. We conclude that using global datasets based on Earth Observation data is a cost-effective solution to make REDD+ operational, but deforestation maps in particular should be derived carefully and their uncertainty assessed

The 3-D O(4) universality class and the phase transition in two-flavor QCD

We determine the critical equation of state of the three-dimensional O(4) universality class. We first consider the small-field expansion of the effective potential (Helmholtz free energy). Then, we apply a systematic approximation scheme based on polynomial parametric representations that are valid in the whole critical regime, satisfy the correct analytic properties (Griffiths' analyticity), take into account the Goldstone singularities at the coexistence curve, and match the small-field expansion of the effective potential. From the approximate representations of the equation of state, we obtain estimates of several universal amplitude ratios. The three-dimensional O(4) universality class is expected to describe the finite-temperature chiral transition of quantum chromodynamics with two light flavors. Within this picture, the O(4) critical equation of state relates the reduced temperature, the quark masses, and the condensates around T_c in the limit of vanishing quark masses.Comment: 19 pages, 5 fig