High-order harmonic generation at high laser intensities beyond the tunnel regime

We present studies of high-order harmonic generation (HHG) at laser intensities well above saturation. We use driving laser pulses which present a particular electron dynamics in the turn-on stage. Our results predict an increasing on the harmonic yield, after an initial dropping, when the laser intensity is increased. This fact contradicts the general belief of a progressive degradation of the harmonic emission at ultrahigh intensities. We have identified a particular set of trajectories which emerges in the turn-on stage of these singular laser pulses, responsible of the unexpected growth on the harmonic efficiency at this high intensity regime. Our study combines two complementary approaches: classical analysis and full quantum mechanical calculations resulting from the numerical integration of the 3-dimensional time-dependent Schr\"odinger equation complemented with the time-frequency analysis

High-order harmonic generation driven by chirped laser pulses induced by linear and non linear phenomena

We present a theoretical study of high-order harmonic generation (HHG) driven by ultrashort optical pulses with different kind of chirps. The goal of the present work is perform a detailed study to clarify the relevant parameters in the chirped pulses to achieve a noticeable cut-off extensions in HHG. These chirped pulses are generated using both linear and nonlinear dispersive media.The description of the origin of the physical mechanisms responsible of this extension is, however, not usually reported with enough detail in the literature. The study of the behaviour of the harmonic cut-off with these kind of pulses is carried out in the classical context, by the integration of the Newton-Lorentz equation complemented with the quantum approach, based on the integration of the time dependent Schr\"odinger equation in full dimensions (TDSE-3D), we are able to understand the underlying physics.Comment: 13 pages, 8 figure

Carrier-wave Rabi flopping signatures in high-order harmonic generation for alkali atoms

We present the first theoretical investigation of carrier-wave Rabi flopping in real atoms by employing numerical simulations of high-order harmonic generation (HHG) in alkali species. Given the short HHG cutoff, related to the low saturation intensity, we concentrate on the features of the third harmonic of sodium (Na) and potassium (K) atoms. For pulse areas of 2$\pi$ and Na atoms, a characteristic unique peak appears, which, after analyzing the ground state population, we correlate with the conventional Rabi flopping. On the other hand, for larger pulse areas, carrier-wave Rabi flopping occurs, and is associated with a more complex structure in the third harmonic. These new characteristics observed in K atoms indicate the breakdown of the area theorem, as was already demonstrated under similar circumstances in narrow band gap semiconductors

A catalog of planetary nebula candidates in the Sculptor spiral galaxy NGC 300

[OIII]5007 on-band off-band images, obtained with the VLT and FORS2 spectrograph in two zones (center and outskirts) of the spiral galaxy NGC300, are analyzed searching for emission line objects. In particular we search for planetary nebula (PN) candidates to analyze their distribution and luminosity properties, to perform follow-up spectroscopy, and to study the planetary nebula luminosity function, PNLF. In the continuum-subtracted images, a large number of emission line objects were detected. From this sample we selected as PN candidates those objects with stellar appearance and no detectable central star. [OIII]5007 instrumental magnitudes were measured and calibrated by using spectrophotometric data from the follow-up spectroscopy. We identified more than a hundred PN candidates and a number of compact HII regions. The PN sample is the largest one reported for this galaxy so far. For all the objects we present coordinates, instrumental [OIII]5007 magnitudes and apparent nebular [OIII]5007 fluxes and magnitudes. The [OIII]5007 observed luminosity function for PNe (PNLF) was calculated for the whole sample and for the central and outskirts samples. The three PNLF are similar within uncertainties. We fit the empirical PNLF to the observed PNLF for all the samples. From our best fit for the whole sample we derived a maximum value for the apparent magnitudes of m*(5007)=22.019\pm0.022 and we obtained a tentative estimate of the distance modulus m(5007)-M(5007)= 26.29 {+0.12} {-0.22} mag, which agrees well with the recent value derived from Cepheid stars.Comment: 8 pages, 3 figures, one long table. Accepted by A&

Optimization of pulsed thermoelectric materials using simulated annealing and non-linear finite elements

[EN] The objective of this work is to determine the optimal shape, gains and duration of an electric pulse applied to a Peltier cell, together with the length of the thermoelectric to maximize cooling while min- imizing electric consumption. For this purpose, a fully coupled, multiphysics, dynamic finite-element model, which solves for the thermal, electric and mechanical fields is used. Because of the demanding computing requirements of the optimization process, a special mesh is designed and a convergence anal- ysis is carried out before using the multiphysics model. The highly non-linear optimization is done by simulated annealing, a heuristic algorithm in the Markov chain Monte-Carlo family. A preliminary para- metric investigation is presented, analyzing the impact of some of the parameters. The results of this pre- liminary analysis help to understand the effect of the different shapes in the evolution of the cold face temperature. Some of these results are expected and have already been discussed elsewhere, but others can only be explained after further analysis and a full system modeling. Pulse optimization is multiobjec- tive and multiparametric, i.e., it can consider several targets such as maximizing the cooling temperature, the cooling duration or others. The trade-offs between the different targets are studied. In all cases, stres- ses inside the thermoelement are examined at all points, and the pulses must meet the restriction that an equivalent stress is not above the allowable value.This research was partially supported by the grants, Haut-de-France Region (CR Picardie, 120-2015-RDISTRUCT-000010), EU funding (FEDER, RDISTRUCT-000010) for Chaire-de-Mecanique, and Spanish Ministry of Economy and Competitiveness grant CGL2014-59841-P. These supports are gratefully acknowledgedMoreno-Navarro, P.; Pérez-Aparicio, JL.; Gómez-Hernández, JJ. (2017). Optimization of pulsed thermoelectric materials using simulated annealing and non-linear finite elements. Applied Thermal Engineering. 120:603-613. https://doi.org/10.1016/j.applthermaleng.2017.04.036S60361312

Analytical and multicoupled methods for optimal steady-state thermoelectric solutions

[EN] Peltier cells have low efficiency, but they are becoming attractive alternatives for affordable and environmentally clean cooling. In this line, the current article develops closed-form and semianalytical solutions to improve the temperature distribution of Bi2Te3 thermoelements. From the distribution, the main objective of the current work-the optimal electric intensity to maximize cooling-is inferred. The general one-dimensional differential coupled equation is integrated for linear and quadratic geometry of thermoelements, under temperature constant properties. For a general shape, a piece-wise solution based on heat flux continuity among virtual layers gives accurate analytical solutions. For variable properties, another piece-wise solution is developed but solved iteratively. Taking advantage of the formulae, the optimal intensity is directly derived with a minimal computational cost; its value will be of utility for more advanced designs. Finally, a parametric study including straight, two linear, barrel, hourglass and vase geometries is presented, drawing conclusions on how the shape of the thermoelement affects the coupled phenomena. A specially developed coupled and non-linear finite element research code is run taking into account all the materials of the cell and using symmetries and repetitions. These accurate results are used to validate the analytical ones.This work was supported by the Generalitat Valenciana research programmes PROMETEO/2020/016: Applications de Topologic Isolators in Spintronics and Thermoelectricity (TOP-TERM) and BEST/2021/079. The support is gratefully acknowledged.Moreno-Navarro, P.; Pérez-Aparicio, JL.; Gómez-Hernández, JJ. (2022). Analytical and multicoupled methods for optimal steady-state thermoelectric solutions. Coupled Systems Mechanics, an international journal. 11(2):151-166. https://doi.org/10.12989/csm.2022.11.2.15115116611

Effluents from the copper electrorefining as a secondary source of antimony: Role of mass transfer on the recovery by electrodeposition

The limited availability of antimony has increased the need for exploiting alternative sources to its direct extraction from stibnite deposits. Furthermore, introducing recovery techniques in industries where antimony is released in wastewaters leads to more responsible production routes. In this work, electrodeposition is employed to recover the antimony present in a secondary waste effluent of the copper electrorefining that is highly concentrated in hydrochloric acid. The electrochemical characterization of the system was conducted by voltammetry to identify a range of suitable operating conditions for the potentiostatic and galvanostatic electro-recovery of antimony. In potentiostatic mode, the progress of the secondary electrode reactions of hydrogen and chlorine evolution at potentials more cathodic than −0.38 V vs. Ag/AgCl causes the detachment and redissolution of the deposited antimony. Operating under galvanostatic control, similar effects were observed when the limiting current density is exceeded. Current efficiency and specific energy consumption values above 50 % and below 65 kW·h·kg−1, were achieved below the limiting current density (1.265 mA·cm−2). The operational range where electrodeposition of antimony is accelerated at increasing current densities can be broadened at intensified hydrodynamic conditions and higher concentrations of antimony. The detrimental effect of the hydrogen evolution reaction on the recovery of antimony decreases at high HCl concentrations