Order Recall in Verbal Short-Term Memory is Influenced by Semantic Activation

It has recently been suggested that order recall in short-term memory tasks is influenced by the level of activation of items in the lexico-semantic network. According to the Activated Network view, increasing the level of activation of an item would increase the probability of observing a migration of the item toward the beginning of the list (Poirier et al., 2015). We tested this prediction by manipulating the orthographic neighbourhood of to-be-recalled items. In Experiment 1, the first three items of a 7-item list were orthographic neighbours of the target item in Position 5. As predicted, at recall, the target item migrated more toward the beginning of the list than control items. In Experiment 2, all list items were orthographic neighbours of the target item located on Position 4, 5, or 6. Compared to control items, the target item migrated more toward the beginning than the end of the list

Near-Infrared Kinetic Spectroscopy of the HO_2 and C_2H_5O_2 Self-Reactions and Cross Reactions

The self-reactions and cross reactions of the peroxy radicals HO_2 and C_2H_5O_2 and HO_2 were monitored using simultaneous independent spectroscopic probes to observe each radical species. Wavelength modulation (WM) near-infrared (NIR) spectroscopy was used to detect HO_2, and UV absorption monitored HO_2 and C_2H_5O_2. The temperature dependences of these reactions were investigated over a range of interest to tropospheric chemistry, 221−296 K. The Arrhenius expression determined for the cross reaction, k_2(T) = (6.01^(+1.95)_(−1.47)) × 10^(−13) exp((638 ± 73)/T) cm^3 molecules^(−1) s^(−1) is in agreement with other work from the literature. The measurements of the HO_2 self-reaction agreed with previous work from this lab and were not further refined.(1) The C_2H_5O_2 self-reaction is complicated by secondary production of HO_2. This experiment performed the first direct measurement of the self-reaction rate constant, as well as the branching fraction to the radical channel, in part by measurement of the secondary HO_2. The Arrhenius expression for the self-reaction rate constant is k_3(T) = (1.29^(+0.34)_(−0.27)) × 10^(−13)exp((−23 ± 61)/T) cm^3 molecules^(−1) s^(−1), and the branching fraction value is α = 0.28 ± 0.06, independent of temperature. These values are in disagreement with previous measurements based on end product studies of the branching fraction. The results suggest that better characterization of the products from RO_2 self-reactions are required

Experimental Line Parameters of the b^(1)Σ^(+)_g ← X^(3)Σ^(-)_g Band of Oxygen Isotopologues at 760 nm Using Frequency-Stabilized Cavity Ring-Down Spectroscopy

Positions, intensities, self-broadened widths, and collisional narrowing coefficients of the oxygen isotopologues ^(16)O^(18)O, ^(16)O^(17)O, ^(17)O^(18)O, and ^(18)O^(18)O have been measured for the b^(1)Σg + ← X^(3)Σg − (0,0) band using frequency-stabilized cavity ring-down spectroscopy. Line positions of 156 P-branch transitions were referenced against the hyperfine components of the ^(39)K D_1 (4s ^(2)S_(1/2) → 4p ^(2)P_(1/2)) and D_2 (4s ^(2)S_(1/2) → 4p ^(2)P_(3/2)) transitions, yielding precisions of ~0.00005 cm^(−1) and absolute accuracies of 0.00030 cm^(−1) or better. New excited b^(1)Σg + state molecular constants are reported for all four isotopologues. The measured line intensities of the ^(16)O^(18)O isotopologue are within 2% of the values currently assumed in molecular databases. However, the line intensities of the ^(16)O^(17)O isotopologue show a systematic, J-dependent offset between our results and the databases. Self-broadening half-widths for the various isotopologues are internally consistent to within 2%. This is the first comprehensive study of the line intensities and shapes for the ^(17)O^(18)O or ^(18)O_2 isotopologues of the b^(1)Σg + ← X^(3)Σg − (0,0) band of O_2. The ^(16)O_2, ^(16)O^(18)O, and ^(16)O^(17)O line parameters for the oxygen A-band have been extensively revised in the HITRAN 2008 database using results from the present study

Direct Detection of Products from the Pyrolysis of 2-Phenethyl Phenyl Ether

The pyrolysis of 2-phenethyl phenyl ether (PPE, C_6H_5C_2H_4OC_6H_5) in a hyperthermal nozzle (300-1350 °C) was studied to determine the importance of concerted and homolytic unimolecular decomposition pathways. Short residence times (<100 μs) and low concentrations in this reactor allowed the direct detection of the initial reaction products from thermolysis. Reactants, radicals, and most products were detected with photoionization (10.5 eV) time-of-flight mass spectrometry (PIMS). Detection of phenoxy radical, cyclopentadienyl radical, benzyl radical, and benzene suggest the formation of product by the homolytic scission of the C_6H_5C_2H_4-OC_6H_5 and C_6H_5CH_2-CH_2OC_6H_5 bonds. The detection of phenol and styrene suggests decomposition by a concerted reaction mechanism. Phenyl ethyl ether (PEE, C_6H_5OC_2H_5) pyrolysis was also studied using PIMS and using cryogenic matrix-isolated infrared spectroscopy (matrix-IR). The results for PEE also indicate the presence of both homolytic bond breaking and concerted decomposition reactions. Quantum mechanical calculations using CBS-QB3 were conducted, and the results were used with transition state theory (TST) to estimate the rate constants for the different reaction pathways. The results are consistent with the experimental measurements and suggest that the concerted retro-ene and Maccoll reactions are dominant at low temperatures (below 1000 °C), whereas the contribution of the C_6H_5C_2H_4-OC_6H_5 homolytic bond scission reaction increases at higher temperatures (above 1000 °C)

Union économique et mobilité des facteurs; le cas de l'Union Économique et Monétaire Ouest Africain (UEMOA)

L'objet de ce papier est d'analyser les conséquences de la mise en place d'une Union économique entre les pays d'Afrique de l'Ouest (UEMOA), dans le cadre d'un modèle d'équilibre général calculable multi-pays avec mobilité des facteurs de production. On s'interroge sur les facteurs de convergence ou de divergence de développement, consécutifs à la réallocation des ressources et du commerce engendrés par la création de l'Union entre les pays membres qui, même s'ils ont des niveaux de revenus uniformément faibles, sont d'une configuration assez asymétrique. Tout d'abord, dans la mesure où l'Union économique signifie pour certains une forte ouverture internationale et pour d'autres un léger réarmement douanier, ses effets, de faible ampleur, sont contrastés. Par ailleurs, en dépit de l'asymétrie du choc, nos résultats sont conformes à ceux développés par Venables (1999): la Côte d'Ivoire qui possède le rapport des facteurs de production le moins éloigné du rapport mondial est le pays qui bénéficie le plus du processus d'intégration régionale. A l'inverse, le Burkina Faso voit sa situation se dégrader. La mobilité du travail et du capital industriel accentue le phénomène de divergence entre les pays de la zone. C'est ainsi que le Sénégal, et dans une moindre mesure le Togo, verraient à long terme leurs situations se dégrader par rapport au scénario de référence du fait de la fuite des capitaux industriels et donc leur écart de développement avec la Côte d'Ivoire croître. A contrario, la question migratoire, qui est parfois mise en exergue dans ce contexte, compte tenu des niveaux des flux et de l'ampleur somme toute modérée du choc macro-économique n'apparaît pas avec acuité. Enfin, on montre que la question de la transition fiscalo-douanière est centrale. En effet, selon le mode de financement des pertes fiscales choisi, l'impact des réformes douanières peut aller en sens opposé notamment sur la croissance des secteurs industriels dans des pays comme le Sénégal. Tant de problème du "creusement" du fossé entre la Côte d'Ivoire et ses partenaires régionaux et ses effets en terme de migration et de localisation du capital industriel dans la région, que le traitement du problème de la transition fiscalo-douanière doivent inciter la communauté internationale à envisager les politiques d'aide dans une stratégie régionale et non pas nationale comme cela l'est malheureusement encore.Intégration régionale, UEMOA, migration, FDI, MEGC

Achieving sustainable construction within Private Finance Initiative (PFI) road projects in the UK

The construction industry is facing the challenge of increasing demands of its sustainability performance. The construction and maintenance of the built environment has substantial impact on the sustainability of the environment. Whist, public sector clients are increasingly asking for a sustainable approach in their specification and procurement decisions, sustainability is still seen as a novel concept within the construction industry in many parts of the world without a settled definition. The premise of this study is that the interaction between road projects realized by the private finance initiative and their delivery in the UK improve sustainability. The paper, based on case study research, explains the sustainability implementation in a PFI road project and demonstrates that the PFI mechanism facilitates sustainable implementation to a far greater extent than is achievable using traditional procurement methods

The major brain cholesterol metabolite 24(s)-hydroxycholesterol is a potent allosteric modulator of N-methyl-d-aspartate receptors

N-methyl-d-aspartate receptors (NMDARs) are glutamate-gated ion channels that are critical to the regulation of excitatory synaptic function in the CNS. NMDARs govern experience-dependent synaptic plasticity and have been implicated in the pathophysiology of various neuropsychiatric disorders including the cognitive deficits of schizophrenia and certain forms of autism. Certain neurosteroids modulate NMDARs experimentally but their low potency, poor selectivity, and very low brain concentrations make them poor candidates as endogenous ligands or therapeutic agents. Here we show that the major brain-derived cholesterol metabolite 24(S)-hydroxycholesterol (24(S)-HC) is a very potent, direct, and selective positive allosteric modulator of NMDARs with a mechanism that does not overlap that of other allosteric modulators. At submicromolar concentrations 24(S)-HC potentiates NMDAR-mediated EPSCs in rat hippocampal neurons but fails to affect AMPAR or GABA(A) receptors (GABA(A)Rs)-mediated responses. Cholesterol itself and other naturally occurring oxysterols present in brain do not modulate NMDARs at concentrations ≤10 μm. In hippocampal slices, 24(S)-HC enhances the ability of subthreshold stimuli to induce long-term potentiation (LTP). 24(S)-HC also reverses hippocampal LTP deficits induced by the NMDAR channel blocker ketamine. Finally, we show that synthetic drug-like derivatives of 24(S)-HC, which potently enhance NMDAR-mediated EPSCs and LTP, restore behavioral and cognitive deficits in rodents treated with NMDAR channel blockers. Thus, 24(S)-HC may function as an endogenous modulator of NMDARs acting at a novel oxysterol modulatory site that also represents a target for therapeutic drug development

Alien Registration- Robichaud, Felix J. (Rumford, Oxford County)

https://digitalmaine.com/alien_docs/12398/thumbnail.jp