Charge trapping in polymer transistors probed by terahertz spectroscopy and scanning probe potentiometry

Terahertz time-domain spectroscopy and scanning probe potentiometry were used to investigate charge trapping in polymer field-effect transistors fabricated on a silicon gate. The hole density in the transistor channel was determined from the reduction in the transmitted terahertz radiation under an applied gate voltage. Prolonged device operation creates an exponential decay in the differential terahertz transmission, compatible with an increase in the density of trapped holes in the polymer channel. Taken in combination with scanning probe potentionmetry measurements, these results indicate that device degradation is largely a consequence of hole trapping, rather than of changes to the mobility of free holes in the polymer.Comment: 4 pages, 3 figure

Optimal Population Codes for Space: Grid Cells Outperform Place Cells

Rodents use two distinct neuronal coordinate systems to estimate their position: place fields in the hippocampus and grid fields in the entorhinal cortex. Whereas place cells spike at only one particular spatial location, grid cells fire at multiple sites that correspond to the points of an imaginary hexagonal lattice. We study how to best construct place and grid codes, taking the probabilistic nature of neural spiking into account. Which spatial encoding properties of individual neurons confer the highest resolution when decoding the animal’s position from the neuronal population response? A priori, estimating a spatial position from a grid code could be ambiguous, as regular periodic lattices possess translational symmetry. The solution to this problem requires lattices for grid cells with different spacings; the spatial resolution crucially depends on choosing the right ratios of these spacings across the population. We compute the expected error in estimating the position in both the asymptotic limit, using Fisher information, and for low spike counts, using maximum likelihood estimation. Achieving high spatial resolution and covering a large range of space in a grid code leads to a trade-off: the best grid code for spatial resolution is built of nested modules with different spatial periods, one inside the other, whereas maximizing the spatial range requires distinct spatial periods that are pairwisely incommensurate. Optimizing the spatial resolution predicts two grid cell properties that have been experimentally observed. First, short lattice spacings should outnumber long lattice spacings. Second, the grid code should be self-similar across different lattice spacings, so that the grid field always covers a fixed fraction of the lattice period. If these conditions are satisfied and the spatial “tuning curves” for each neuron span the same range of firing rates, then the resolution of the grid code easily exceeds that of the best possible place code with the same number of neurons

Statistical mechanics of temporal association in neural networks with transmission delays

We study the representation of static patterns and temporal sequences in neural networks with signal delays and a stochastic parallel dynamics. For a wide class of delay distributions, the asymptotic network behavior can be described by a generalized Gibbs distribution, generated by a novel Lyapunov functional for the determination dynamics. We extend techniques of equilibrium statistical mechanics so as to deal with time-dependent phenomena, derive analytic results for both retrieval quality and storage capacity, and compare them with numerical simulations

Mesoscopic order and the dimentionality of long-range resonance energy transfer in supramolecular semiconductors

We present time-resolved photoluminescence measurements on two series of oligo-p-phenylenevinylene materials that self-assemble into supramolecular nanostructures with thermotropic reversibility in dodecane. One set of derivatives form chiral, helical stacks while the second set form less organised, frustrated stacks. Here we study the effects of supramolecular organisation on the resonance energy transfer rates. We measure these rates in nanoassemblies formed with mixed blends of oligomers and compare them with the rates predicted by Foerster theory. Our results and analysis show that control of supramolecular order in the nanometre lengthscale has a dominant effect on the efficiency and dimentionality of resonance energy transfer.Comment: 17 Pages, 5 Figures, Submitted to J. Chem. Phy

Harmonic lattice behavior of two-dimensional colloidal crystals

Using positional data from video-microscopy and applying the equipartition theorem for harmonic Hamiltonians, we determine the wave-vector-dependent normal mode spring constants of a two-dimensional colloidal model crystal and compare the measured band-structure to predictions of the harmonic lattice theory. We find good agreement for both the transversal and the longitudinal mode. For $q\to 0$, the measured spring constants are consistent with the elastic moduli of the crystal.Comment: 4 pages, 3 figures, submitte

Collection of relevant results obtained with the Skylab images by the Institute for Space Research, INPE

There are no author-identified significant results in this report

Chaos-Polynome in der probabilistischen Sicherheitsanalyse von Stabtragwerken

Die Arbeit verbindet die im Konstruktiven Ingenieurbau beim Bemessen von Stabtragwerken allgemein übliche Deformationsmethode mit modernen Ergebnissen der Stochastik: Zufällige Unsicherheiten der Bemessungsgrößen (Materialparameter, Belastung) werden über WIENER-HERMITE-Polynome in orthonormierten GAUSSschen Zufallsgrößen erfasst. Der Vorzug des neuartigen Zugangs zur probabilistischen Sicherheitsanalyse von Stabtragwerken besteht vor allem darin, dass das Rechenverfahren der Deformationsmethode im Grundsatz erhalten bleibt. Dies kommt das den Bedürfnissen der Praxis entgegen. Das Verfahren liefert die analytische Darstellung der sicherheitsrelevanten Ausgangsgrößen (Knotenverschiebungen, Spannungen) als Polynome GAUSSscher Zufallsgrößen. Der Einfluss von Parameterunschärfen kann beurteilt werden. Ferner lassen sich die statistischen Momente der Ausgangsgrößen und die Versagenswahrscheinlichkeit ableiten. Dies ermöglicht eine breitere Sicht auf das Verhalten eines Tragwerks bei unsicheren Bemessungsgrößen. Die Methode wird durch Beispiele illustriert. Vom Standpunkt der Mechanik wird die Plausibilität der benutzten Ansätze untersucht. Ferner dienen die erweiterten Möglichkeiten der probabilistischen Analyse zu Aussagen darüber, wie Veränderungen von Konstruktionsparametern und die Lage der Schnittstelle auf die Tragwerkssicherheit wirken. Zur Bestimmung von bietet sich die Monte-Carlo-Methode an. Zur Varianzreduktion wird neben der importance-sampling-Technik ein KALMAN-Filter eingesetzt

Distances sets that are a shift of the integers and Fourier basis for planar convex sets

The aim of this paper is to prove that if a planar set $A$ has a difference set $\Delta(A)$ satisfying $\Delta(A)\subset \Z^++s$ for suitable $s$ than $A$ has at most 3 elements. This result is motivated by the conjecture that the disk has not more than 3 orthogonal exponentials. Further, we prove that if $A$ is a set of exponentials mutually orthogonal with respect to any symmetric convex set $K$ in the plane with a smooth boundary and everywhere non-vanishing curvature, then # (A \cap {[-q,q]}^2) \leq C(K) q where $C(K)$ is a constant depending only on $K$. This extends and clarifies in the plane the result of Iosevich and Rudnev. As a corollary, we obtain the result from \cite{IKP01} and \cite{IKT01} that if $K$ is a centrally symmetric convex body with a smooth boundary and non-vanishing curvature, then $L^2(K)$ does not possess an orthogonal basis of exponentials

Why, what, and how? case study on law, risk, and decision making as necessary themes in built environment teaching

The paper considers (and defends) the necessity of including legal studies as a core part of built environment undergraduate and postgraduate curricula. The writer reflects upon his own experience as a lawyer working alongside and advising built environment professionals in complex land remediation and site safety management situations in the United Kingdom and explains how themes of liability, risk, and decision making can be integrated into a practical simulation in order to underpin more traditional lecture-based law teaching. Through reflection upon the writer's experiments with simulation-based teaching, the paper suggests some innovations that may better orientate law teaching to engage these themes and, thereby, enhance the relevance of law studies to the future needs of built environment professionals in practice.</p

Parental bonding and identity style as correlates of self-esteem among adult adoptees and nonadoptees

Adult adoptees (n equals 100) and non-adoptees (n equals 100) were compared with regard to selfesteem, identity processing style, and parental bonding. While some differences were found with regard to self-esteem, maternal care, and maternal overprotection, these differences were qualified by reunion status such that only reunited adoptees differed significantly from nonadoptees. Moreover, hierarchical regression analyses indicated that parental bonding and identity processing style were more important than adoptive status per se in predicting self esteem. Implications for practitioners who work with adoptees are discussed