Role of Citrate Ions in the Phosphonate-based Inhibitor System for Mild Steel in Aqueous Chloride Media

The corrosion inhibition efficiency of phosphonic acid and its derivatives for the inhibition of corrosion of mild steel in neutral chloride media is decided by its ability to form protectivefilm over the surface. In this context, the effect of addition of metal cations and certain organic compounds, such as citrate in conjugation with phosphonic acid to impart synergistic corrosion inhibition has been explored. The experiments were carried out using various concentrations of trisodium citrate and zinc ions in an aqueous solution of 2-carboxyethyl phosphonic acid (2CEPA) at 25 ppm. The corrosion characteristics have been determined using electrochemical impedance spectroscopy together with determination of corrosion rate by weight-loss method. It has been observed that a combination of inhibitive ions, namely citrate, ZCEPA, and zinc ions at 25 ppm gives 96 per cent inhibition efficiency and this corrosion inhibition is due to the formation of a protective film. By increasing the concentration of citrate beyond 25 ppm, the corrosion inhibition efficiency decreases. This paper discusses the role of citrate and zinc ions in imparting added corrosion inhibition ability using 2CEPA on the basis of experimental results

Deep multimodal biometric recognition using contourlet derivative weighted rank fusion with human face, fingerprint and iris images

The goal of multimodal biometric recognition system is to make a decision by identifying their physiological behavioural traits. Nevertheless, the decision-making process by biometric recognition system can be extremely complex due to high dimension unimodal features in temporal domain. This paper explains a deep multimodal biometric system for human recognition using three traits, face, fingerprint and iris. With the objective of reducing the feature vector dimension in the temporal domain, first pre-processing is performed using Contourlet Transform Model. Next, Local Derivative Ternary Pattern model is applied to the pre-processed features where the feature discrimination power is improved by obtaining the coefficients that has maximum variation across pre-processed multimodality features, therefore improving recognition accuracy. Weighted Rank Level Fusion is applied to the extracted multimodal features, that efficiently combine the biometric matching scores from several modalities (i.e. face, fingerprint and iris). Finally, a deep learning framework is presented for improving the recognition rate of the multimodal biometric system in temporal domain. The results of the proposed multimodal biometric recognition framework were compared with other multimodal methods. Out of these comparisons, the multimodal face, fingerprint and iris fusion offers significant improvements in the recognition rate of the suggested multimodal biometric system

Continuum model of strong light-matter coupling for molecular polaritons

Strong coupling between light and matter generates hybrid polaritons. We present a continuum model that describes the polaritons by light and matter densities of states (DOS) that only depend on the refractive index of the material. This model is applied to molecular polaritons derived from molecules with broad spectral absorption. While the photonic DOS has a complex spectral distribution, the matter DOS is largely unmodified by strong coupling. We argue that bright states cannot be partitioned from dark states, and instead the photonic DOS is shared over a vast number of matter states

Conceptualizing a circular framework of supply chain resource sustainability

Purpose: In response to calls for conceptual frameworks and generic theory building towards the advancement of sustainability in supply chain resource utilization and management, this paper advances a circular framework for Supply Chain Resource Sustainability (SCRS), and a decision support methodology for assessing SCRS against the backdrop of five foundational premises deduced from the literature on resource sustainability. Design/ Approach: Taking a conceptual theory building approach, the paper advances a set of SCRS decision-support criteria for each of the theoretical premises advanced, and applies the Theory of Constraints to illustrate the conceptual and practical applications of the framework in SCRS decision-making. Findings: This study uses recent conceptualizations of supply chains as ‘complex adaptive systems’ to provide a robust and novel frame and a set of decision rules with which to assess the interconnectedness of environmental, economic, and social capital of supply chain resources from pre-production to post-production. Research Implications: The paper contributes to theory building in sustainability research, and the SCRS decision framework developed could be applied in tandem with existing quantitative hybrid lifecycle and input-output approaches to facilitate targeted resource sustainability assessments, with implications for research and practice. Originality/Value: The novel SCRS framework proposed serves as a template for evaluating SCRS and provides a decision support methodology for assessing SCRS against the five theorized foundational premises

Enhancement of TbIII-CuII single-molecule magnet performance through structural modification

We report a series of 3d–4f complexes {Ln2Cu3(H3L)2Xn} (X=OAc−, Ln=Gd, Tb or X=NO3−, Ln=Gd, Tb, Dy, Ho, Er) using the 2,2′-(propane-1,3-diyldiimino)bis[2-(hydroxylmethyl)propane-1,3-diol] (H6L) pro-ligand. All complexes, except that in which Ln=Gd, show slow magnetic relaxation in zero applied dc field. A remarkable improvement of the energy barrier to reorientation of the magnetisation in the {Tb2Cu3(H3L)2Xn} complexes is seen by changing the auxiliary ligands (X=OAc− for NO3−). This leads to the largest reported relaxation barrier in zero applied dc field for a Tb/Cu-based single-molecule magnet. Ab initio CASSCF calculations performed on mononuclear TbIII models are employed to understand the increase in energy barrier and the calculations suggest that the difference stems from a change in the TbIII coordination environment (C4v versus Cs)

Antecedents of low carbon emissions supply chains

Purpose: A low-carbon economy is the pressing need of the hour. Despite several efforts taken by the government and large corporations, there is still research to be conducted exploring the role of top management commitment in translating external pressures into responses that help to build low-carbon emissions in supply chains. Design/methodology/approach: The authors have grounded their framework in institutional theory, agency theory and contingency theory. On the basis of existing literature, four hypotheses were drawn. To test these hypotheses, a questionnaire was developed and pre-tested. Finally, statistical analyses were performed to test the research hypotheses using 176 samples gathered using a pre-tested questionnaire following Dillman’s (2007) total design test method. Findings: The results suggest that coercive pressures and mimetic pressures under the mediating effect of top management commitment have a significant influence on organizational response to low-carbon emissions. The authors further note that supply base complexity has moderating effects on the link between top management commitment and organizational response towards low-carbon emissions. Originality/value: This study offers valuable insights to those managers and environmental consultants who view supply base complexity as a limitation. However, the results indicate that supply base complexity may help to enhance the effectiveness of the top management commitment on organizational response towards low-carbon emissions

World Class Sustainable Supply Chain Management: critical review and further research directions

Purpose Sustainable supply chain management (SSCM) has attracted considerable interest among academics and practitioners. The purpose of this paper is to present a critical review of the literature, to identify missing links, to argue for the use of world class SSCM (WCSSCM) through a framework, and suggest further research directions. Design/methodology/approach In the paper the authors have undertaken an extensive review of literature and classified articles using a novel classification scheme. Findings Through the extensive review and identification of research gaps, the paper identifies significant differences between definitions and methodologies in the SSCM literature; and argues for “WCSSCM.” This term is elaborated on via a theoretical framework in which 18 dimensions are classified under six constructs of SSCM. Furthermore, a list of potential research directions for WCSSCM is discussed. Research limitations/implications The research is an attempt to critically review literature, argue for WCSSCM, and develop a theoretical framework. Originality/value The paper offers a new approach to SSCM literature, arguing for WCSSCM through a framework, and providing further research directions

(±)-trans-5-Benzoyl-2-(1H-indol-3-yl)-4-phenyl-4,5-dihydro­furan-3-carbonitrile

The furan ring in the title compound, C26H18N2O2, is twisted about the C(H)—C(H) bond. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O inter­action, which generates an S(6) ring motif. The presence of N—H⋯N hydrogen bonds leads to inversion dimers, which are stabilized in the crystal packing by C—H⋯O and C—H⋯π inter­actions, forming layers that stack along the a axis

On elementary extensions in Fuzzy Predicate Logics

10 páginas.-- Comunicación presentada a la International Conference on Information Processing and Management of Uncertainty in Knowledge-Based Systems (IPMU) celebrada en Dortmund (Alemania) del 28 de Junio al 2 de Julio de 2010.Our work is a contribution to the model-theoretic study of equality-free fuzzy predicate logics. We give a characterization of ele- mentary equivalence in fuzzy predicate logics using elementary exten- sions and introduce an strengthening of this notion, the so-called strong elementary equivalence. Using the method of diagrams developed in [5] and elementary extensions we present a counterexample to Conjectures 1 and 2 of [8].Research partially funded by the spanish projects CONSOLIDER (CSD2007- 0022), MULOG2 (TIN2007-68005-C04-01) and ARINF (TIN2009-14704-C03-03) by the ESF Eurocores-LogICCC/MICINN project FFI2008-03126- E/FILO and by the Generalitat de Catalunya under the grants 2009-SGR 1433 and 1434.Peer reviewe