Experimental confirmation of the low B isotope coefficient in MgB2

Recent investigations have shown that the first proposed explanations of the disagreement between experimental and theoretical value of isotope coefficient in MgB2 need to be reconsidered. Considering that in samples with residual resistivity of few mu-Ohm cm critical temperature variations produced by disorder effects can be comparable with variations due to the isotopic effect, we adopt a procedure in evaluating the B isotope coefficient which take account of these effects, obtaining a value which is in agreement with previous results and then confirming that there is something still unclear in the physics of MgB2.Comment: 8 pages, 3 figures Title has been changed A statement has been added in page 7 of the pdf file "Finally we would..." Reference 21 has been added Figure 1 anf Figure 2 have been change

Seebeck effect in the conducting LaAlO_{3}/SrTiO_{3} interface

The observation of metallic behavior at the interface between insulating oxides has triggered worldwide efforts to shed light on the physics of these systems and clarify some still open issues, among which the dimensional character of the conducting system. In order to address this issue, we measure electrical transport (Seebeck effect, Hall effect and conductivity) in LaAlO_{3}/SrTiO_{3} interfaces and, for comparison, in a doped SrTiO_{3} bulk single crystal. In these experiments, the carrier concentration is tuned, using the field effect in a back gate geometry. The combined analysis of all experimental data at 77 K indicates that the thickness of the conducting layer is ~7 nm and that the Seebeck effect data are well described by a two-dimensional (2D) density of states. We find that the back gate voltage is effective in varying not only the charge density, but also the thickness of the conducting layer, which is found to change by a factor of ~2, using an electric field between -4 and +4MV/m at 77K. No enhancement of the Seebeck effect due to the electronic confinement and no evidence for two-dimensional quantization steps are observed at the interfaces.Comment: 15 pages, 5 figure

Stress transmission in granular matter

The transmission of forces through a disordered granular system is studied by means of a geometrical-topological approach that reduces the granular packing into a set of layers. This layered structure constitutes the skeleton through which the force chains set up. Given the granular packing, and the region where the force is applied, such a skeleton is uniquely defined. Within this framework, we write an equation for the transmission of the vertical forces that can be solved recursively layer by layer. We find that a special class of analytical solutions for this equation are L\'evi-stable distributions. We discuss the link between criticality and fragility and we show how the disordered packing naturally induces the formation of force-chains and arches. We point out that critical regimes, with power law distributions, are associated with the roughness of the topological layers. Whereas, fragility is associated with local changes in the force network induced by local granular rearrangements or by changes in the applied force. The results are compared with recent experimental observations in particulate matter and with computer simulations.Comment: 14 pages, Latex, 5 EPS figure

Thermal conductivity of MgB2_{2} in the superconducting state

We present thermal conductivity measurements on very pure and dense bulk samples, as indicated by residual resistivity values as low as 0.5 mW cm and thermal conductivity values higher than 200 W/mK. In the normal state we found that the Wiedemann Franz law, in its generalized form, works well suggesting that phonons do not contribute to the heat transport. The thermal conductivity in the superconducting state has been analysed by using a two-gap model. Thank to the large gap anisotropy we were able to evaluate quantitatively intraband scattering relaxation times of $\pi$ and $\sigma$ bands, which depend on the disorder in different way; namely, as the disorder increases, it reduces more effectively the relaxation times of $\pi$ than of $\sigma$ bands, as suggested by a recent calculation [1].Comment: 12 pages, 5 figure

Biotransformation of β-Hydroxypyruvate and Glycolaldehyde to L-Erythrulose by Pichia pastoris strain GS115 overexpressing native Transketolase

Transketolase is a proven biocatalytic tool for asymmetric carbon-carbon bond formation, both as a purified enzyme and within bacterial whole-cell biocatalysts. The performance of Pichia pastoris as a host for transketolase whole-cell biocatalysis was investigated using a transketolase-overexpressing strain to catalyse formation of L-erythrulose from β- hydroxypyruvic acid and glycolaldehyde substrates. Pichia pastoris transketolase coding sequence from the locus PAS_chr1-4_0150 was subcloned downstream of the methanolinducible AOX1 promoter in a plasmid for transformation of strain GS115, generating strain TK150. Whole and disrupted TK150 cells from shake flasks achieved 62% and 65% conversion, respectively, under optimal pH and methanol induction conditions. In a 300µL reaction, TK150 samples from a 1L fed-batch fermentation achieved a maximum Lerythrulose space time yield (STY) of 46.58 g L -1 hr-1, specific activity of 155 U gCDW -1 , product yield on substrate (Yp/s) of 0.52 mol mol-1 and product yield on catalyst (Yp/x) of 2.23g gCDW -1. We have successfully exploited the rapid growth and high biomass characteristics of Pichia pastoris in whole cell biocatalysis. At high cell density, the engineered TK150 Pichia pastoris strain tolerated high concentrations of substrate and product to achieve high STY of the chiral sugar L-erythrulose

Intraband versus interband scattering rate effects in neutron irradiated MgB2

One of the most important predictions of the two-gap theory of superconductivity concerns the role of interband scattering (IBS) by impurities. IBS is expected to decrease the critical temperature, Tc, of MgB2 to a saturation value of about 20 K, where the two gaps merge to a single one. These predictions have been partially contradicted by experiments. In fact, Tc does not saturate in irradiated samples, but decreases linearly with residual resistivity and the merging of the gaps has been observed at a much lower Tc (11 K). In this paper we argue that, while at low level of disorder IBS is the leading mechanism that suppresses superconductivity, at higher disorder the experimental results can only be understood if the smearing of the density of states due to intraband electron lifetime effects is considered.Comment: 3 figure

The ac stark shift and space-borne rubidium atomic clocks

open7sìDue to its small size, low weight, and low power consumption, the Rb atomic frequency standard (RAFS) is routinely the first choice for atomic timekeeping in space. Consequently, though the device has very good frequency stability (rivaling passive hydrogen masers), there is interest in uncovering the fundamental processes limiting its long-term performance, with the goal of improving the device for future space systems and missions. The ac Stark shift (i. e., light shift) is one of the more likely processes limiting the RAFS' long-term timekeeping ability, yet its manifestation in the RAFS remains poorly understood. In part, this comes from the fact that light-shift induced frequency fluctuations must be quantified in terms of the RAFS' light-shift coefficient and the output variations in the RAFS' rf-discharge lamp, which is a nonlinear inductively-couple plasma (ICP). Here, we analyze the light-shift effect for a family of 10 on-orbit Block-IIR GPS RAFS, examining decade-long records of their on-orbit frequency and rf-discharge lamp fluctuations. We find that the ICP's light intensity variations can take several forms: deterministic aging, jumps, ramps, and non-stationary noise, each of which affects the RAFS' frequency via the light shift. Correlating these light intensity changes with RAFS frequency changes, we estimate the light-shift coefficient, K-LS, for the family of RAFS: K-LS = -(1.9 +/- 0.3) x 10(-12) /%. The 16% family-wide variation in K-LS indicates that while each RAFS may have its own individual K-LS, the variance of K-LS among similarly designed RAFS can be relatively small. Combining K-LS with our estimate of the ICP light intensity's non-stationary noise, we find evidence that random-walk frequency noise in high-quality space-borne RAFS is strongly influenced by the RAFS' rf-discharge lamp via the light shift effect. Published by AIP Publishing.openFormichella, V.; Camparo, J.; Sesia, I.; Signorile, G.; Galleani, L.; Huang, M.; Tavella, P.Formichella, V.; Camparo, J.; Sesia, Ilaria; Signorile, Giovanna; Galleani, L.; Huang, M.; Tavella, Patrizi

Probing the electron-phonon coupling in MgB2 through magnetoresistance measurements in neutron irradiated thin films

We report magnetoresistance (MR) measurements on MgB2 and the corresponding full account from ab-initio calculations; we suggest that this combination can be a useful tool to probe electron- phonon coupling. We obtain good quantitative agreement between high field measurements on neutron irradiated epitaxial thin films and calculations within Bloch-Boltzmann transport theory over a wide range of magnetic fields (0-28 T) and temperatures (40-300 K), and as a function of the field orientation. The crossovers between in-plane and out-of-plane MR, experimentally observed as a function of either disorder or temperature are well reproduced indicating that disorder and interaction with phonons strongly affect the scattering rate of s-carriers.Comment: 13 pages, 4 figures, 1 tabl

Two-band effects in transport properties of MgB2

We present resistivity and thermal conductivity measurements on bulk samples, prepared either by a standard method or by a one-step technique. The latter samples, due to their high density and purity, show residual resistivity values as low as 0.5 mW cm and thermal conductivity values as high as 215 W/mK, higher than the single crystal ones. Thermal and electrical data of all the samples are analysed in the framework of the Bloch-Gruneisen equation giving reliable parameter values. In particular the temperature resitivity coefficient, obtained both from resistivity and thermal conductivity, in the dirty sample comes out ten time larger than in the clean ones. This result supports the hypothesis of ref. [1] that p and s bands conduct in parallel, prevailing p conduction in clean samples and s conduction in dirty samples .Comment: 8 pages, 5 figures, Presented at the BOROMAG workshop, June 17-19 2002, Genoa, Ital

Magnetoresistivity in MgB2 as a probe of disorder in p- and s-bands

In this paper we present normal state magnetoresistivity data of magnesium diboride epitaxial thin films with different levels of disorder, measured at 42K in magnetic fields up to 45 Tesla. Disorder was introduced in a controlled way either by means of neutron irradiation or by carbon doping. From a quantitative analysis of the magnetoresistivity curves with the magnetic field either parallel or perpendicular to the plane of the film, we extract the ratio of the scattering times in p- and s-bands. We demonstrate that the undoped unirradiated thin film has p scattering times smaller than s ones; upon irradiation, both bands become increasingly more disordered; eventually the highly irradiated sample (neutron fluence 7.7X1017 cm-2) and the C-doped sample have comparable scattering times in the two types of bands. This description of the effect of disorder in the two kinds of bands on transport is consistent with the residual resistivity values and with the temperature dependence of the resistivity.Comment: 19 pages, 3 tables, 2 figure