A Convenient Synthetic Route to Partial-Cone p-Carboxylatocalix[4]arenes.

p-Carboxylatocalix[n]arenes have emerged as useful building blocks for the construction of a diverse range of supramolecular assemblies. A convenient route to a p-carboxylatocalix[4]arene that is locked in a partial-cone conformation is presented. The conformation gives the molecule markedly different topological directionality relative to those previously used in self- and metal-directed assembly studies

The direct evaluation of attosecond chirp from a streaking measurement

We derive an analytical expression, from classical electron trajectories in a laser field, that relates the breadth of a streaked photoelectron spectrum to the group-delay dispersion of an isolated attosecond pulse. Based on this analytical expression, we introduce a simple, efficient and robust procedure to instantly extract the attosecond pulse's chirp from the streaking measurement.Comment: 4 figure

Illuminating the Process of Youth Development: The Mediating Effect of Thriving on Youth Development Program Outcomes

This paper examines the relationship between the developmental contexts of youth programs and resultant developmental outcomes, and explores whether the developmental process of thriving mediates this relationship. Developmental context is proposed to consist of three elements: (1) youth sparks, (2) program quality, and (3) developmental relationships. Combined, these elements describe youth program context more precisely than in previous studies, allowing for a clearer understanding of effective program settings. Likewise, the process of youth thriving provides insight into the mechanism through which youth development occurs. Sufficient model fit, convergent validity, and discriminant validity of the 4-H Thriving scale were determined through a multi-phase confirmatory factor analysis. As hypothesized, structural equation modeling revealed a full mediational effect of youth thriving on developmental outcomes. The results of this study guide youth development practitioners to focus on the quality of the developmental context of youth programs and the ways in which programs can promote youth thriving

Fluid-Induced Propulsion of Rigid Particles in Wormlike Micellar Solutions

In the absence of inertia, a reciprocal swimmer achieves no net motion in a viscous Newtonian fluid. Here, we investigate the ability of a reciprocally actuated particle to translate through a complex fluid that possesses a network using tracking methods and birefringence imaging. A geometrically polar particle, a rod with a bead on one end, is reciprocally rotated using magnetic fields. The particle is immersed in a wormlike micellar (WLM) solution that is known to be susceptible to the formation of shear bands and other localized structures due to shear-induced remodeling of its microstructure. Results show that the nonlinearities present in this WLM solution break time-reversal symmetry under certain conditions, and enable propulsion of an artificial "swimmer." We find three regimes dependent on the Deborah number (De): net motion towards the bead-end of the particle at low De, net motion towards the rod-end of the particle at intermediate De, and no appreciable propulsion at high De. At low De, where the particle time-scale is longer then the fluid relaxation time, we believe that propulsion is caused by an imbalance in the fluid first normal stress differences between the two ends of the particle (bead and rod). At De~1, however, we observe the emergence of a region of network anisotropy near the rod using birefringence imaging. This anisotropy suggests alignment of the micellar network, which is "locked in" due to the shorter time-scale of the particle relative to the fluid

Exact Soliton-like Solutions of the Radial Gross-Pitaevskii Equation

We construct exact ring soliton-like solutions of the cylindrically symmetric (i.e., radial) Gross- Pitaevskii equation with a potential, using the similarity transformation method. Depending on the choice of the allowed free functions, the solutions can take the form of stationary dark or bright rings whose time dependence is in the phase dynamics only, or oscillating and bouncing solutions, related to the second Painlev\'e transcendent. In each case the potential can be chosen to be time-independent.Comment: 8 pages, 7 figures. Version 2: stability analysis of the dark solutio

Response of a native bamboo [Arundinaria gigantea (Walt.) Muhl.] in a wind-disturbed forest

Numerous bamboos are known to form extensive single-species stands, including species in the United States. Formerly prominent in the southeastern US, canebrakes are dense stands of the bamboos collectively called cane [Arundinaria (Michx)]. Canebrakes are now a critically endangered component of the bottomland hardwood forest ecosystem. Cane still occurs in its historic range, primarily in small remnant patches. A poor understanding of the ecological processes that generated large canebrakes limits their restoration and management. We hypothesize that cane\u27s spreading clonal structure enables these bamboos to persist beneath a forest canopy and then respond rapidly to large-scale wind disturbances. We quantified patterns of clonal growth in one cane species, giant cane [Arundinaria gigantea (Walt.) Muhl.], in a very large tornado-generated canopy gap and in surrounding bottomland hardwood forest in Louisiana. We tested these four hypotheses over a 12-month study period in the large canopy gap: (1) production of new culms should be greater, (2) clonal expansion should be greater, (3) culm damage rate should be reduced, and (4) culm size should be reduced compared to giant cane stands under forest canopy. We found that new culm production in tornado-blowdown plots was twice that in forest plots. Accordingly, culms were younger on average in the tornado blowdown than under forest. Rate of clonal expansion was similar between the two environments, suggesting clonal spread was not disturbance-dependent. With fewer branch-fall impacts, culms in the tornado blowdown were less often damaged. Culms were smaller in tornado-blowdown plots than in forest plots. Giant cane\u27s clonal plasticity should enable it to persist in old-growth bottomland forests by responding to local light conditions. Genets should increase culm production in small gaps and senesce as gaps fill in. Giant cane stands could thereby shift location over time. Wind disturbance that opens forest canopy should trigger redevelopment of denser stands that could merge with other expanding stands into expansive canebrakes. Giant cane\u27s clonal ecology may be a useful model for understanding spreading bamboos and other forest-growing clonal perennials. © 2007 Elsevier B.V. All rights reserved

Evaluating elbow osteoarthritis within the prehistoric Tiwanaku state using generalized estimating equations (GEE).

OBJECTIVES:Studies of osteoarthritis (OA) in human skeletal remains can come with scalar problems. If OA measurement is noted as present or absent in one joint, like the elbow, results may not identify specific articular pathology data and the sample size may be insufficient to address research questions. If calculated on a per data point basis (i.e., each articular surface within a joint), results may prove too data heavy to comprehensively understand arthritic changes, or one individual with multiple positive scores may skew results and violate the data independence required for statistical tests. The objective of this article is to show that the statistical methodology Generalized Estimating Equations (GEE) can solve scalar issues in bioarchaeological studies. MATERIALS AND METHODS:Using GEE, a population-averaged statistical model, 1,195 adults from the core and one colony of the prehistoric Tiwanaku state (AD 500-1,100) were evaluated bilaterally for OA on the seven articular surfaces of the elbow joint. RESULTS:GEE linked the articular surfaces within each individual specimen, permitting the largest possible unbiased dataset, and showed significant differences between core and colony Tiwanaku peoples in the overall elbow joint, while also pinpointing specific articular surfaces with OA. Data groupings by sex and age at death also demonstrated significant variation. A pattern of elbow rotation noted for core Tiwanaku people may indicate a specific pattern of movement. DISCUSSION:GEE is effective and should be encouraged in bioarchaeological studies as a way to address scalar issues and to retain all pathology information

Understanding the empirical literature on purchasing power parity: the post-Bretton Woods era

Foreign exchange ; Purchasing power

Experimental investigation of Lord Kelvins isentropic cooling and heating expression in tensile bars for two engineering alloys

Solids when rapidly and elastically stressed change temperature, the effect proposed by Lord Kelvin is adiabatic thermo-elastic cooling or heating depending on the sign of the stress. A fast sensitive IR camera has measured temperature both decreasing and increasing. Temperature measurements made from the reversible, elastic part of the stress-strain curve during fast uniaxial tensile loading have been investigated. The isentropic temperature cooling from the loading curve is recovered by heating after the specimen fractures when the load is released. These measurements establish for the first time isentropic thermal recovery in two engineering alloys. The materials tested are an AISI 4340 steel and an aluminum 2024 alloy. Measurements of the isentropic thermo-elastic stress cooling are -0.61 K/GPa for steel and -1.7 K/GPa for aluminum alloy. The isentropic thermo-elastic stress heating is -1.16 K/GPa for steel and -1.6 K/GPa for aluminum alloy. The isentropic, elastic part of the temperature is fully recoverable even after extensive plastic deformation upon fracture