<i>In situ</i> diagnostics of the crystal-growth process through neutron imaging:application to scintillators

Neutrons are known to be unique probes in situations where other types of radiation fail to penetrate samples and their surrounding structures. In this paper it is demonstrated how thermal and cold neutron radiography can provide time-resolved imaging of materials while they are being processed (e.g. while growing single crystals). The processing equipment, in this case furnaces, and the scintillator materials are opaque to conventional X-ray interrogation techniques. The distribution of the europium activator within a BaBrCl:Eu scintillator (0.1 and 0.5% nominal doping concentrations per mole) is studied in situ during the melting and solidification processes with a temporal resolution of 5-7 s. The strong tendency of the Eu dopant to segregate during the solidification process is observed in repeated cycles, with Eu forming clusters on multiple length scales (only for clusters larger than ∼50 µm, as limited by the resolution of the present experiments). It is also demonstrated that the dopant concentration can be quantified even for very low concentration levels (∼0.1%) in 10 mm thick samples. The interface between the solid and liquid phases can also be imaged, provided there is a sufficient change in concentration of one of the elements with a sufficient neutron attenuation cross section. Tomographic imaging of the BaBrCl:0.1%Eu sample reveals a strong correlation between crystal fractures and Eu-deficient clusters. The results of these experiments demonstrate the unique capabilities of neutron imaging for in situ diagnostics and the optimization of crystal-growth procedures

Improved scintillation proportionality and energy resolution of LaBr3LaBr_3:Ce at 80 K

Using highly monochromatic synchrotron X-rays in the energy range from 10.5 keV to 100 keV the temperature dependence of nonproportionality and energy resolution of LaBr3 scintillators doped with 5% Ce3+ were studied at 80K, 295K, and 450K. Improvement of the proportionality and better energy resolution was observed on lowering the temperature. This effect suggests that the already outstanding energy resolution of LaBr3:Ce can be improved even further. It also may provide new clues to better understand the processes that cause nonproportionality of inorganic scintillator response.Comment: 5 pages, 2 figures submitted for publication at Nucl. Instr. Meth.