Into the Mystic: ALMA ACA observations of the Mystic Mountains in Carina

We present new observations of the Mystic Mountains cloud complex in the Carina Nebula using the ALMA Atacama Compact Array (ACA) to quantify the impact of strong UV radiation on the structure and kinematics of the gas. Our Band 6 observations target CO, 13CO, and C18O; we also detect DCN J=3–2 and 13CS J=5–4. A dendrogram analysis reveals that the Mystic Mountains are a coherent structure, with continuous emission over −10.5 km s−1 < v < −2 km s−1. We perform multiple analyses to isolate non-thermal motions in the Mystic Mountains including computing the turbulent driving parameter, b, which indicates whether compressive or solenoidal modes dominate. Each analysis yields values similar to other pillars in Carina that have been observed in a similar way but are subject to an order of magnitude less intense ionizing radiation. We find no clearcorrelation between the velocity or turbulent structure of the gas and the incident radiation, in contrast to other studies targeting different regions of Carina. This may reflect differences in the initial densities of regions that go on to collapse into pillars and those that still look like clouds or walls in the present day. Pre-existing over-densities that enable pillar formation may also explain why star formation in the pillars appears more evolved (from the presence of jets) than in other heavily irradiated but non-pillar-like regions. High resolution observations of regions subject to an array of incident radiation are required to test this hypothesis

Illuminating evaporating protostellar outflows: ERIS/SPIFFIER reveals the dissociation and ionization of HH 900

Protostellar jets and outflows are signposts of active star formation. In H II regions, molecular tracers like CO only reveal embedded portions of the outflow. Outside the natal cloud, outflows are dissociated, ionized, and eventually completely ablated, leaving behind only the high-density jet core. Before this process is complete, there should be a phase where the outflow is partially molecular and partially ionized. In this paper, we capture the HH 900 outflow while this process is in action. New observations from the ERIS/SPIFFIER near-IR integral field unit (IFU) spectrograph using the K-middle filter ($\lambda$=2.06-2.34 $\mu$m) reveal H$_2$ emission from the dissociating outflow and Br-$\gamma$ tracing its ionized skin. Both lines trace the wide-angle outflow morphology but H$_2$ only extends $\sim$5000 au into the H II region while Br-$\gamma$ extends the full length of the outflow ($\sim$12,650 au), indicating rapid dissociation of the molecules. H$_2$ has higher velocities further from the driving source, consistent with a jet-driven outflow. Diagnostic line ratios indicate that photoexcitation, not just shocks, contributes to the excitation in the outflow. We argue that HH 900 is the first clear example of an evaporating molecular outflow and predict that a large column of neutral material that may be detectable with ALMA accompanies the dissociating molecules. Results from this study will help guide the interpretation of near-IR images of externally irradiated jets and outflows such as those obtained with the James Webb Space Telescope (JWST) in high-mass star-forming regions where these conditions may be common.Comment: MNRAS, accepte

Illuminating evaporating protostellar outflows: ERIS/SPIFFIER reveals the dissociation and ionization of HH 900

Protostellar jets and outflows are signposts of active star formation. In H II regions, molecular tracers like CO only reveal embedded portions of the outflow. Outside the natal cloud, outflows are dissociated, ionized, and eventually completely ablated, leaving behind only the high-density jet core. Before this process is complete, there should be a phase where the outflow is partially molecular and partially ionized. In this paper, we capture the HH 900 outflow while this process is in action. New observations from the Enhanced Resolution Imager and Spectrograph/SPIFFIER near-infrared (IR) integral field unit spectrograph using the K-middle filter (λ = 2.06–2.34 μm) reveal H2 emission from the dissociating outflow and Br-γ tracing its ionized skin. Both lines trace the wide-angle outflow morphology but H2 only extends ∼5000 au into the H II region while Br-γ extends the full length of the outflow (∼12 650 au), indicating rapid dissociation of the molecules. H2 has higher velocities further from the driving source, consistent with a jet-driven outflow. Diagnostic line ratios indicate that photoexcitation, not just shocks, contributes to the excitation in the outflow. We argue that HH 900 is the first clear example of an evaporating molecular outflow and predict that a large column of neutral material that may be detectable with Atacama Large Millimeter Array accompanies the dissociating molecules. Results from this study will help guide the interpretation of near-IR images of externally irradiated jets and outflows such as those obtained with the JWST in high-mass star-forming regions where these conditions may be common

Widespread Microbial Adaptation to l‑Glutamate‑<i>N</i>,<i>N</i>‑diacetate (L-GLDA) Following Its Market Introduction in a Consumer Cleaning Product

l-Glutamate-<i>N</i>,<i>N</i>-diacetate (L-GLDA) was recently introduced in the United States (U.S.) market as a phosphate replacement in automatic dishwashing detergents (ADW). Prior to introduction, L-GLDA exhibited poor biodegradation in OECD 301B Ready Biodegradation Tests inoculated with sludge from U.S. wastewater treatment plants (WWTPs). However, OECD 303A Activated Sludge WWTP Simulation studies showed that with a lag period to allow for growth (40–50 days) and a solids retention time (SRT) that allows establishment of L-GLDA degraders (>15 days), significant biodegradation (>80% dissolved organic carbon removal) would occur. Corresponding to the ADW market launch, a study was undertaken to monitor changes in the ready biodegradability of L-GLDA using activated sludge samples from various U.S. WWTPs. Initially all sludge inocula showed limited biodegradation ability, but as market introduction progressed, both the rate and extent of degradation increased significantly. Within 22 months, L-GLDA was ready biodegradable using inocula from 12 WWTPs. In an OECD 303A study repeated 18 months post launch, significant and sustained carbon removal (>94%) was observed after a 29-day acclimation period. This study systematically documented field adaptation of a new consumer product chemical across a large geographic region and confirmed the ability of laboratory simulation studies to predict field adaptation