Theory of dark resonances for alkali vapors in a buffer-gas cell

We develop an analytical theory of dark resonances that accounts for the full atomic-level structure, as well as all field-induced effects such as coherence preparation, optical pumping, ac Stark shifts, and power broadening. The analysis uses a model based on relaxation constants that assumes the total collisional depolarization of the excited state. A good qualitative agreement with experiments for Cs in Ne is obtained.Comment: 16 pages; 7 figures; revtex4. Accepted for publication in PR

EIT and diffusion of atomic coherence

We study experimentally the effect of diffusion of Rb atoms on Electromagnetically Induced Transparency (EIT) in a buffer gas vapor cell. In particular, we find that diffusion of atomic coherence in-and-out of the laser beam plays a crucial role in determining the EIT resonance lineshape and the stored light lifetime.Comment: 5 pages, 8 figure

Experimental implementation of a four-level N-type scheme for the observation of Electromagnetically Induced Transparency

A nondegenerate four-level N-type scheme was experimentally implemented to observe electromagnetically induced transparency (EIT) at the $^{87}$Rb D$_{2}$ line. Radiations of two independent external-cavity semiconductor lasers were used in the experiment, the current of one of them being modulated at a frequency equal to the hyperfine-splitting frequency of the excited 5P$_{3/2}$ level. In this case, apart from the main EIT dip corresponding to the two-photon Raman resonance in a three-level $\Lambda$-scheme, additional dips detuned from the main dip by a frequency equal to the frequency of the HF generator were observed in the absorption spectrum. These dips were due to an increase in the medium transparency at frequencies corresponding to the three-photon Raman resonances in four-level N-type schemes. The resonance shapes are analyzed as functions of generator frequency and magnetic field.Comment: 3 pages, 2 figure

On the unique possibility to increase significantly the contrast of dark resonances on D1 line of 87^{87}Rb

We propose and study, theoretically and experimentally, a new scheme of excitation of a coherent population trapping resonance for D1 line of alakli atoms with nuclear spin $I=3/2$ by bichromatic linearly polarized light ({\em lin}$||${\em lin} field) at the conditions of spectral resolution of the excited state. The unique properties of this scheme result in a high contrast of dark resonance for D1 line of $^{87}$Rb.Comment: 9 pages, 7 figures. This material has been partially presented on ICONO-2005, 14 May 2005, St. Petersburg, Russia. v2 references added; text is changed a bi

Buffer-gas induced absorption resonances in Rb vapor

We observe transformation of the electromagnetically induced transparency (EIT) resonance into the absorption resonance in a $\Lambda$ interaction configuration in a cell filled with $^{87}$Rb and a buffer gas. This transformation occurs as a one-photon detuning of the coupling fields is varied from the atomic transition. No such absorption resonance is found in the absence of a buffer gas. The width of the absorption resonance is several times smaller than the width of the EIT resonance, and the changes of absorption near these resonances are about the same. Similar absorption resonances are detected in the Hanle configuration in a buffered cell.Comment: 11 pages, 15 figures; 13 pages, 17 figures, added numerical simulatio

Ultra-precise measurement of optical frequency ratios

We developed a novel technique for frequency measurement and synthesis, based on the operation of a femtosecond comb generator as transfer oscillator. The technique can be used to measure frequency ratios of any optical signals throughout the visible and near-infrared part of the spectrum. Relative uncertainties of $10^{-18}$ for averaging times of 100 s are possible. Using a Nd:YAG laser in combination with a nonlinear crystal we measured the frequency ratio of the second harmonic $\nu_{SH}$ at 532 nm to the fundamental $\nu_0$ at 1064 nm, $\nu_{SH}/\nu_0 = 2.000 000 000 000 000 001 \times (1 \pm 7 \times 10^{-19})$.Comment: 4 pages, 4 figure

Hybrid Mechanical Systems

We discuss hybrid systems in which a mechanical oscillator is coupled to another (microscopic) quantum system, such as trapped atoms or ions, solid-state spin qubits, or superconducting devices. We summarize and compare different coupling schemes and describe first experimental implementations. Hybrid mechanical systems enable new approaches to quantum control of mechanical objects, precision sensing, and quantum information processing.Comment: To cite this review, please refer to the published book chapter (see Journal-ref and DOI). This v2 corresponds to the published versio

Resonant nonlinear magneto-optical effects in atoms

In this article, we review the history, current status, physical mechanisms, experimental methods, and applications of nonlinear magneto-optical effects in atomic vapors. We begin by describing the pioneering work of Macaluso and Corbino over a century ago on linear magneto-optical effects (in which the properties of the medium do not depend on the light power) in the vicinity of atomic resonances, and contrast these effects with various nonlinear magneto-optical phenomena that have been studied both theoretically and experimentally since the late 1960s. In recent years, the field of nonlinear magneto-optics has experienced a revival of interest that has led to a number of developments, including the observation of ultra-narrow (1-Hz) magneto-optical resonances, applications in sensitive magnetometry, nonlinear magneto-optical tomography, and the possibility of a search for parity- and time-reversal-invariance violation in atoms.Comment: 51 pages, 23 figures, to appear in Rev. Mod. Phys. in Oct. 2002, Figure added, typos corrected, text edited for clarit

Orbital redistribution in molecular nanostructures mediated by metal-organic bonds

Dicyanovinyl-quinquethiophene (DCV5T-Me) is a prototype conjugated oligomer for highly efficient organic solar cells. This class of oligothiophenes are built up by an electron-rich donor (D) backbone and terminal electron-deficient acceptor (A) moieties. Here, we investigated its structural and electronic properties when it is adsorbed on a Au(111) surface using low temperature scanning tunneling microscopy/spectroscopy (STM/STS) and atomic force microscopy (AFM). We find that DCV5T-Me self-assembles in extended chains, stabilized by intercalated Au atoms. The effect of metal-ligand hybridization with Au adatoms causes an energetic downshift of the DCV5T-Me lowest unoccupied molecular orbital (LUMO) with respect to the uncoordinated molecules on the surface. The asymmetric coordination of a gold atom to only one molecular end group leads to an asymmetric localization of the LUMO and LUMO+1 states at opposite sides. Using model density functional theory (DFT) calculations, we explain such orbital reshaping as a consequence of linear combinations of the original LUMO and LUMO+1 orbitals, mixed by the attachment of a bridging Au adatom. Our study shows that the alignment of molecular orbitals and their distribution within individual molecules can be modified by contacting them to metal atoms in specific sites