Theoretical and methodological grounds for the modernization of the tax administration system

The article stands for the theoretical underpinning of economic grounds of tax system and its building on the basis of social- and business-oriented socioeconomic features. Authors proved the need for tax process management that represent the features of government-society-taxpayer relations with taxpayer’s leading role as macroeconomic tool for economic regulation process as well as providing the sustainable and balanced economic growth and innovative modernization of Russian economy.peer-reviewe

Multi-Cyclic and Isotopically Diverse Silicic Magma Generation in an Arc Volcano: Gorely Eruptive Center, Kamchatka, Russia

The Kamchatka Peninsula is home to some of the most frequent and prolific subduction-related volcanic activity in the world, with the largest number of caldera-forming eruptions per length of the volcanic arc. Among those, Gorely volcano has a topographically prominent Late Pleistocene caldera (13 km × 12 km, estimated to have produced >100 km3 of magma), which is now almost completely filled by a central cone. We report new 40Ar/39Ar ages and geochemical and isotopic data for newly recognized Mid-Pleistocene ignimbrite units of large but unknown volume sourced from the Gorely eruptive center, most of which were deposited in marginal glacial conditions. These ignimbrites have crystallinities of 9-24% and most are quartz-, amphibole-, and zircon-undersaturated. Additionally, we studied 32 eruptive units, including stratigraphically constrained Holocene tephra, and pre- and post-caldera lava sequences, to understand the petrogenetic and temporal evolution of this long-lived, multi-cyclic, arc volcano. Material erupted prior to the formation of the modern Gorely edifice, including the voluminous ignimbrites and eruptions of the ‘pra-Gorely' stage, consist primarily of dacite and andesite, whereas sequences of the modern Gorely edifice are represented by basalt to basaltic andesite. MELTS and EC-AFC modeling shows that it is possible to obtain silicic compositions near those of the evolved ignimbrite compositions through 60-75% fractional crystallization at 1 kbar and nickel-nickel oxide (NNO) oxygen fugacity. However, our newly compiled major and trace element data for Gorely yield two separate bimodal peaks in a SiO2-frequency diagram, showing a prominent Daly Gap, with a deficiency in andesite. Trace element concentrations define two separate trends, one for more silicic and another for more mafic sequences. Additionally, δ18Omelt values reconstructed from coexisting plagioclase and clinopyroxene phenocrysts range from a low value of 4·85‰ to a normal value of 6·22‰. The low δ18O values range throughout the known lifespan of Gorely, with the lowest value being from the first known ignimbrite to erupt, indicating episodic but temporally decreasing crustal assimilation of previously hydrothermally altered material. 87Sr/86Sr and 143Nd/144Nd ratios show wide ranges from 0·70328 to 0·70351 and from 0·51303 to 0·51309 respectively, also suggesting incorporation of surrounding crust, although there are less clear trends throughout the lifespan of Gorely. The combination of light and diverse δ18O values with elevated 87Sr/86Sr and low 143Nd/144Nd ratios suggests contamination by older and isotopically diverse, low-δ18O country-rocks, such as the neighboring 11 Ma Akhomten granitic massif, which shows ranges in δ18O, 87Sr/86Sr, and 144Nd/143Nd values overlapping with the Gorely magmas. In addition, the presence of glomerocrysts and mafic enclaves in the majority of Gorely dacites indicates a period of crystal settling and subsequent intrusion of hot, primitive basalt that probably triggered eruption. Finally, elevated Nb concentrations relative to other Kamchatkan volcanoes suggest that Gorely magmas may involve an enriched component, probably caused by delamination of a lower crustal root. Our results argue for an incremental view of silicic magma generation at so-called ‘long-term eruptive centers', in Kamchatka and worldwide, consisting of alternating episodes of magmatic and hydrothermal activity, and glacial advances and retreats. We demonstrate that large-volume, isotopically distinct, silicic magma can be generated rapidly between cone-building phases of volcanic activity through a combination of fractional crystallization, assimilation of older country rocks, and shallow assimilation of hydrothermally altered but otherwise petrochemically similar older intracaldera tuffs and intrusions. These transient shallow silicic magma chambers empty nearly completely in ignimbrite-forming eruptions after 103-105 years of assembly, partially triggered by glacial surface dynamic

Classification of double flag varieties of complexity 0 and 1

A classification of double flag varieties of complexity 0 and 1 is obtained. An application of this problem to decomposing tensor products of irreducible representations of semisimple Lie groups is considered

Arc Magmas from Slab to Eruption: The Case of Kliuchevskoy Volcano

Arc magmas are generated by a number of mantle and crustal processes. Our multidisciplinary, long-term research is aimed at deciphering these processes for a single arc volcano, Kliuchevskoy volcano in Kamchatka. Some key results of the study follow: 1) Modeling of trace element and H2O contents in melt inclusions suggests that the primary magmas originate via hydrous flux-melting of the mantle wedge at temperatures close to the dry peridotite solidus. The role of decompression melting is minor or absent at Kliuchevskoy and other arc volcanoes built on relatively thick crust. 2) Geochemistry of high-Mg olivine suggests that primary Kliuchevskoy magmas have substantial contribution from olivine-free pyroxenite (up to 30 %), which could be formed by reaction of slab melts (or supercritical fluids) with mantle wedge peridotite. 3) Parental Kliuchevskoy melts start to crystallize as deep as the Moho boundary, and the erupted magmas reflect multistage and complex processes of crystallization, magma mixing and crustal assimilation. None of the Kliuchevskoy rocks analyzed thus far represent true primary melt compositions. 4) The Kliuchevskoy Holocene eruptive history is not steady-state in terms of eruption rate and geochemistry. There are two millenial cycles with major and trace element and OSr- Nd-Pb and U-series isotope compositions of the magmas changing gradually from more to less affected by crustal (?) assimilation. The onset of the cycles correlates with periods of enhanced volcanic activity in Kamchatka, suggesting that the extent of magma-crust interaction is inversely related to magma production rate and thus magma flux from the mantle

Technology of Active Involvement as Means of Formation of Ecological Culture of Youth

В статье рассматривается возможность применения технологии активного вовлечения студентов для формирования у них экологической культуры.The article discusses the possibility of using the technology of active involvement of students to form their ecological culture

Prostaglandin H synthase kinetics in the two-phase aqueous-micellar system

AbstractReaction mixture for PGHS (prostaglandin-H-synthase) is a two-phase system including micellar hydrophobic phase and hydrophilic aqueous phase. Reagents added to the mixture are distributed between phases, thus concentrations of reagents dissolved in phases can differ significantly from their overall contents.Using dynamic light scattering we found that the hydrophobic phase produced by tween-20 consists of micelles, which radius (4–5nm) does not depend on either tween-20 overall content (0.1%–1% v/v) or arachidonic acid (AA) addition (10–1000μM) or PGHS addition (1μM).Tween-20 overall content changing from 0.1% to 2% v/v dramatically affected COX kinetic, but accounting AA distribution between phases allowed us to estimate “true” parameters, independent of the tween-20 overall content and the concentration of another substrate: KMOx equals 9.8μM O2 in the aqueous phase or 0.0074bar in the gaseous phase, KMAA equals 5400μM AA in the phase of tween-20 micelles and 5400/PμM AA in the aqueous phase (P is the distribution ratio for the AA between the aqueous phase and the hydrophobic phase (P≫1000)). This approach allowed to evaluate PS, the distribution ratio for the AA between the hydrophobic phase and the PGHS active center (PS ~310). This coefficient indicates the AA selectivity toward the cyclooxygenase active center

Round table technology in university educational process

The process of building students' competence must meet modern requirements and include the use of innovative technologies. The development trends of modern society have led to the emergence of a competency-based approach in vocational education. In the process of building professional competence, it is necessary to use technologies that meet the requirements of the Federal state educational standards which contribute to the development of practical focus of training. Among such technologies we single out technologies for holding a round table. The technologies of the round table are not new, but due to combination with various innovative technologies, they become more relevant. The implementation of the round table in the training of vocational education teachers is a discussion process that speculates about a relevant topic requiring a comprehensive analysis. Modern conditions provide arrangements of round tables with their own specifics. The purpose of the article is to identify the effectiveness of holding round tables in students’ preparation in higher educational institutions. The article presents basic principles on which the technology of the round table is based, its ideas and essence, as well as the features of its holding. A study conducted at a pedagogical university during the training of vocational education teachers is presented. It showed the need for implementing round-table technologies in preparing students for future professional activities, as the ones allowing students to build effective discussions, negotiate based on arguments and facts. We have identified the effectiveness of the "round tables" in the training of students in higher educational institutions. The study made it possible to establish the level of students’ preparedness for conducting effective discussions for the implementation of future professional activities in secondary vocational educational institutions. The technology of the round table allows to increase the knowledge level of students. The results can be used in students’ training in various faculties