3,798 research outputs found
Optical properties of high quality Cu2ZnSnSe4 thin films
Cu2ZnSnSe4 thin films, fabricated on bare or molybdenum coated glass substrates by magnetron sputtering and selenisation, were studied by a range of techniques. Photoluminescence spectra reveal an excitonic peak and two phonon replicas of a donor-acceptor pair (DAP) recombination. Its acceptor and donor ionisation energies are 27 and 7 meV, respectively. This demonstrates that high-quality Cu2ZnSnSe4 thin films can be fabricated. An experimental value for the longitudinal optical phonon energy of 28 meV was estimated. The band gap energy of 1.01 eV at room temperature was determined using optical absorption spectr
Extended performance solar electric propulsion thrust system study. Volume 4: Thruster technology evaluation
Several thrust system design concepts were evaluated and compared using the specifications of the most advanced 30 cm engineering model thruster as the technology base. Emphasis was placed on relatively high power missions (60 to 100 kW) such as a Halley's comet rendezvous. The extensions in thruster performance required for the Halley's comet mission were defined and alternative thrust system concepts were designed in sufficient detail for comparing mass, efficiency, reliability, structure, and thermal characteristics. Confirmation testing and analysis of thruster and power processing components were performed, and the feasibility of satisfying extended performance requirements was verified. A baseline design was selected from the alternatives considered, and the design analysis and documentation were refined. The baseline thrust system design features modular construction, conventional power processing, and a concentrator solar array concept and is designed to interface with the Space Shuttle
The Hopf modules category and the Hopf equation
We study the Hopf equation which is equivalent to the pentagonal equation,
from operator algebras. A FRT type theorem is given and new types of quantum
groups are constructed. The key role is played now by the classical Hopf
modules category. As an application, a five dimensional noncommutative
noncocommutative bialgebra is given.Comment: 30 pages, Letax2e, Comm. Algebra in pres
Optical spectroscopy studies of Cu2ZnSnSe4 thin films
Cu2ZnSnSe4 thin films were synthesised by selenisation of magnetron sputtered metal precursors. The band gap determined from the absorption spectra increases from 1.01 eV at 300 K to 1.05 eV at 4.2 K. In lower quality films photoluminescence spectra show a broad, low intensity asymmetric band associated with a recombination of free electrons and holes localised on acceptors in the presence of spatial potential fluctuations. In high quality material the luminescence band becomes intense and narrow resolving two phonon replicas. Its shifts at changing excitation power suggest donor–acceptor pair recombination mechanisms. The proposed model involving two pairs of donors and acceptors is supported by the evolution of the band intensity and spectral position with temperature. Energy levels of the donors and acceptors are estimated using Arrhenius quenching analysis
Braided racks, Hurwitz actions and Nichols algebras with many cubic relations
We classify Nichols algebras of irreducible Yetter-Drinfeld modules over
groups such that the underlying rack is braided and the homogeneous component
of degree three of the Nichols algebra satisfies a given inequality. This
assumption turns out to be equivalent to a factorization assumption on the
Hilbert series. Besides the known Nichols algebras we obtain a new example. Our
method is based on a combinatorial invariant of the Hurwitz orbits with respect
to the action of the braid group on three strands.Comment: v2: 35 pages, 6 tables, 14 figure
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Analysis of InAs/GaAs quantum dot solar cells using Suns-V<inf>oc</inf> measurements
This is the final published version. It first appeared at http://www.sciencedirect.com/science/article/pii/S0927024814003833#.The performance of InAs/GaAs quantum dot solar cells was investigated up to an optical concentration of
500-suns. A high temperature spacer layer between successive layers of quantum dots was used to
reduce the degradation in the open circuit voltage relative to a control device without quantum dots.
This improvement is explained using optical data while structural imaging of quantum dot stacks
confirm that the devices are not limited by strain. The evolution of the open circuit voltage as a function
of number of suns concentration was observed to be nearly ideal when compared with a high
performance single junction GaAs solar cell. Analysis of Suns-Voc measurements reveal diode ideality
factors as low as 1.16 which is indicative of a low concentration of defects in the devices.The authors acknowledge financial support from the European
Union under the Seventh Framework Programme under a contract
for an Integrated Infrastructure Initiative. Reference 312483 –
ESTEEM2
Dehydropolymerization of H3B·NMeH2 Using a [Rh(DPEphos)]+ Catalyst : The Promoting Effect of NMeH2
[Rh(κ2-PP-DPEphos){η2η2-H2B(NMe3)(CH2)2tBu}][BArF4] acts as an effective precatalyst for the dehydropolymerization of H3B·NMeH2 to form N-methylpolyaminoborane (H2BNMeH)n. Control of polymer molecular weight is achieved by variation of precatalyst loading (0.1-1 mol %, an inverse relationship) and use of the chain-modifying agent H2: with Mn ranging between 5 500 and 34 900 g/mol and between 1.5 and 1.8. H2 evolution studies (1,2-F2C6H4 solvent) reveal an induction period that gets longer with higher precatalyst loading and complex kinetics with a noninteger order in [Rh]TOTAL. Speciation studies at 10 mol % indicate the initial formation of the amino-borane bridged dimer, [Rh2(κ2-PP-DPEphos)2(μ-H)(μ-H2BN=HMe)][BArF4], followed by the crystallographically characterized amidodiboryl complex [Rh2(cis-κ2-PP-DPEphos)2(σ,μ-(H2B)2NHMe)][BArF4]. Adding ∼2 equiv of NMeH2 in tetrahydrofuran (THF) solution to the precatalyst removes this induction period, pseudo-first-order kinetics are observed, a half-order relationship to [Rh]TOTAL is revealed with regard to dehydrogenation, and polymer molecular weights are increased (e.g., Mn = 40 000 g/mol). Speciation studies suggest that NMeH2 acts to form the precatalysts [Rh(κ2-DPEphos)(NMeH2)2][BArF4] and [Rh(κ2-DPEphos)(H)2(NMeH2)2][BArF4], which were independently synthesized and shown to follow very similar dehydrogenation kinetics, and produce polymers of molecular weight comparable with [Rh(κ2-PP-DPEphos){ η2-H2B(NMe3)(CH2)2tBu}][BArF4], which has been doped with amine. This promoting effect of added amine in situ is shown to be general in other cationic Rh-based systems, and possible mechanistic scenarios are discussed
Auger Recombination in Semiconductor Quantum Wells
The principal mechanisms of Auger recombination of nonequilibrium carriers in
semiconductor heterostructures with quantum wells are investigated. It is shown
for the first time that there exist three fundamentally different Auger
recombination mechanisms of (i) thresholdless, (ii) quasi-threshold, and (iii)
threshold types. The rate of the thresholdless Auger process depends on
temperature only slightly. The rate of the quasi-threshold Auger process
depends on temperature exponentially. However, its threshold energy essentially
varies with quantum well width and is close to zero for narrow quantum wells.
It is shown that the thresholdless and the quasi-threshold Auger processes
dominate in narrow quantum wells, while the threshold and the quasi-threshold
processes prevail in wide quantum wells. The limiting case of a
three-dimensional (3D)Auger process is reached for infinitely wide quantum
wells. The critical quantum well width is found at which the quasi-threshold
and threshold Auger processes merge into a single 3D Auger process. Also
studied is phonon-assisted Auger recombination in quantum wells. It is shown
that for narrow quantum wells the act of phonon emission becomes resonant,
which in turn increases substantially the coefficient of phonon-assisted Auger
recombination. Conditions are found under which the direct Auger process
dominates over the phonon-assisted Auger recombination at various temperatures
and quantum well widths.Comment: 38 pages, 7 figure
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