The Effect of Randomness on the Mott State

We reinvestigate the competition between the Mott and the Anderson insulator state in a one-dimensional disordered fermionic system by a combination of instanton and renormalization group methods. Tracing back both the compressibility and the ac-conductivity to a vanishing kink energy of the electronic displacement field we do not find any indication for the existence of an intermediate (Mott glass) phase.Comment: 4 page

Perturbation theory for ac-driven interfaces in random media

We study $D$-dimensional elastic manifolds driven by ac-forces in a disordered environment using a perturbation expansion in the disorder strength and the mean-field approximation. We find, that for $D\le 4$ perturbation theory produces non-regular terms that grow unboundedly in time. The origin of these non-regular terms is explained. By using a graphical representation we argue that the perturbation expansion is regular to all orders for $D>4$. Moreover, for the corresponding mean-field problem we prove that ill-behaved diagrams can be resummed in a way, that their unbounded parts mutually cancel. Our analytical results are supported by numerical investigations. Furthermore, we conjecture the scaling of the Fourier coefficients of the mean velocity with the amplitude of the driving force $h$.Comment: 23 pages, substantial changes, replaced with the published versio

Perception of nonnative tonal contrasts by Mandarin-English and English-Mandarin sequential bilinguals

This study examined the role of acquisition order and crosslinguistic similarity in influencing transfer at the initial stage of perceptually acquiring a tonal third language (L3). Perception of tones in Yoruba and Thai was tested in adult sequential bilinguals representing three different first (L1) and second language (L2) backgrounds: L1 Mandarin-L2 English (MEBs), L1 English-L2 Mandarin (EMBs), and L1 English-L2 intonational/non-tonal (EIBs). MEBs outperformed EMBs and EIBs in discriminating L3 tonal contrasts in both languages, while EMBs showed a small advantage over EIBs on Yoruba. All groups showed better overall discrimination in Thai than Yoruba, but group differences were more robust in Yoruba. MEBs’ and EMBs’ poor discrimination of certain L3 contrasts was further reflected in the L3 tones being perceived as similar to the same Mandarin tone; however, EIBs, with no knowledge of Mandarin, showed many of the same similarity judgments. These findings thus suggest that L1 tonal experience has a particularly facilitative effect in L3 tone perception, but there is also a facilitative effect of L2 tonal experience. Further, crosslinguistic perceptual similarity between L1/L2 and L3 tones, as well as acoustic similarity between different L3 tones, play a significant role at this early stage of L3 tone acquisition.Published versio

Photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, in the 360–680 nm region

The photodissociation and photochemistry of V⁺ (H₂O)n, n = 1–4, was studied in the 360–680 nm region in a Fourier transform ion cyclotron resonance mass spectrometer. The light of a high pressure mercury arc lamp was filtered with band pass filters, with center wavelengths from 360 to 680 nm in steps of 20 nm. The bandwidth of the filters, defined as full width at half maximum, was 10 nm. Photodissociation channels are loss of water molecules, as well as loss of atomic or molecular hydrogen, which may be accompanied by loss of water molecules. The most intense absorptions are red shifted with increasing hydration. Theoretical spectra are calculated with time dependent density functional theory. Calculations reproduce all features of the experimental spectra, including the red shift with increasing hydration shell and the overall pattern of strong and weak absorptions

Genetic variation of the RASGRF1 regulatory region affects human hippocampus-dependent memory

The guanine nucleotide exchange factor RASGRF1 is an important regulator of intracellular signaling and neural plasticity in the brain. RASGRF1-deficient mice exhibit a complex phenotype with learning deficits and ocular abnormalities. Also in humans, a genome-wide association study has identified the single nucleotide polymorphism (SNP) rs8027411 in the putative transcription regulatory region of RASGRF1 as a risk variant of myopia. Here we aimed to assess whether, in line with the RASGRF1 knockout mouse phenotype, rs8027411 might also be associated with human memory function. We performed computer-based neuropsychological learning experiments in two independent cohorts of young, healthy participants. Tests included the Verbal Learning and Memory Test (VLMT) and the logical memory section of the Wechsler Memory Scale (WMS). Two sub-cohorts additionally participated in functional magnetic resonance imaging (fMRI) studies of hippocampus function. 119 participants performed a novelty encoding task that had previously been shown to engage the hippocampus, and 63 subjects participated in a reward-related memory encoding study. RASGRF1 rs8027411 genotype was indeed associated with memory performance in an allele dosage-dependent manner, with carriers of the T allele (i.e., the myopia risk allele) showing better memory performance in the early encoding phase of the VLMT and in the recall phase of the WMS logical memory section. In fMRI, T allele carriers exhibited increased hippocampal activation during presentation of novel images and during encoding of pictures associated with monetary reward. Taken together, our results provide evidence for a role of the RASGRF1 gene locus in hippocampus-dependent memory and, along with the previous association with myopia, point toward pleitropic effects of RASGRF1 genetic variations on complex neural function in humans.Peer Reviewe

Sentence entailment in compositional distributional semantics

Distributional semantic models provide vector representations for words by gathering co-occurrence frequencies from corpora of text. Compositional distributional models extend these from words to phrases and sentences. In categorical compositional distributional semantics, phrase and sentence representations are functions of their grammatical structure and representations of the words therein. In this setting, grammatical structures are formalised by morphisms of a compact closed category and meanings of words are formalised by objects of the same category. These can be instantiated in the form of vectors or density matrices. This paper concerns the applications of this model to phrase and sentence level entailment. We argue that entropy-based distances of vectors and density matrices provide a good candidate to measure word-level entailment, show the advantage of density matrices over vectors for word level entailments, and prove that these distances extend compositionally from words to phrases and sentences. We exemplify our theoretical constructions on real data and a toy entailment dataset and provide preliminary experimental evidence.Comment: 8 pages, 1 figure, 2 tables, short version presented in the International Symposium on Artificial Intelligence and Mathematics (ISAIM), 201

Storm event impact on organic matter flux, composition and reactivity in Taskinas Creek, VA

Carbon export from the land to the ocean are an important part of the global carbon cycle, linking terrestrial watersheds and the global carbon cycle. Burial of terrestrial organic carbon represents a long term sink for atmospheric CO2. Approximately 0.4 Pg Cy-1 is delivered to the global ocean from rivers, equally divided between POC and DOC. However, the amount of carbon entering the ocean is a small portion of the total amount entering rivers from the terrestrial environment, suggesting a large amount of processing in inland waters and estuaries. Most monitoring efforts have focused the processing of organic matter on baseflow conditions. However, recent studies have shown that POC and DOC exported during storm events, a small time period during a hydrologic year, can account for the majority of the annual carbon exported from small watersheds. This dissertation identifies the impact different magnitudes of storm events have on the source, composition and reactivity of organic carbon released to downstream waters from the terrestrial environment at Taskinas Creek, Virginia. The proximity of the Creek to the York River estuary, the changes in water table at the site, along with the small size of the watershed allowing opportunity to examine the connectivity between the watershed processes and delivery of organic matter made the site ideal for identifying how hydrology and environment alter POM and DOM export and reactivity. The sources, composition and flux of DOM and POM were measured during four storm events of different magnitudes to determine how events impacted the sources and fluxes of organic matter and the % reactive DOC exported. Events of different magnitudes with varying sources of DOC and POC had similar % reactive DOC that was not predicted using excitation emission spectroscopy. The events resulted in DOC fluxes 1.5-490 fold higher than baseflow. POC fluxes for storm were 6.7-55 times higher than DOC fluxes. Although the % reactive DOC did not increase during storm event conditions, coupled with the overall flux, storm events represent a considerable pulse of % reactive DOC to downstream waters, well above baseflow levels. When considered with increases in storm intensity due to climate change, storm event fluxes of reactive OM may have broad impacts on estuaries and the global carbon cycle through changes in carbon storage