10,235 research outputs found
Electronic and magnetic properties of the kagome systems YBaCo4O7 and YBaCo3MO7 (M=Al, Fe)
We present a combined experimental and theoretical x-ray absorption
spectroscopy (XAS) study of the new class of cobaltates YBaCo4O7 and YBaCo3MO7
(M= Al, Fe). The focus is on the local electronic and magnetic properties of
the transition metal ions in these geometrically frustrated kagome compounds.
For the mixed valence cobaltate YBaCo4O7, both the Co2+ and Co3+ are found to
be in the high spin state. The stability of these high spin states in
tetrahedral coordination is compared with those in the more studied case of
octahedral coordination. For the new compound YBaCo3FeO7, we find exclusively
Co2+ and Fe3+ as charge states
Controlling orbital moment and spin orientation in CoO layers by strain
We have observed that CoO films grown on different substrates show dramatic
differences in their magnetic properties. Using polarization dependent x-ray
absorption spectroscopy at the Co L edges, we revealed that the
magnitude and orientation of the magnetic moments strongly depend on the strain
in the films induced by the substrate. We presented a quantitative model to
explain how strain together with the spin-orbit interaction determine the 3d
orbital occupation, the magnetic anisotropy, as well as the spin and orbital
contributions to the magnetic moments. Control over the sign and direction of
the strain may therefore open new opportunities for applications in the field
of exchange bias in multilayered magnetic films
Scientific basis for safely shutting in the Macondo Well after the April 20, 2010 Deepwater Horizon blowout
As part of the government response to the Deepwater Horizon blowout, a Well Integrity Team evaluated the geologic hazards of shutting in the Macondo Well at the seafloor and determined the conditions under which it could safely be undertaken. Of particular concern was the possibility that, under the anticipated high shut-in pressures, oil could leak out of the well casing below the seafloor. Such a leak could lead to new geologic pathways for hydrocarbon release to the Gulf of Mexico. Evaluating this hazard required analyses of 2D and 3D seismic surveys, seafloor bathymetry, sediment properties, geophysical well logs, and drilling data to assess the geological, hydrological, and geomechanical conditions around the Macondo Well. After the well was successfully capped and shut in on July 15, 2010, a variety of monitoring activities were used to assess subsurface well integrity. These activities included acquisition of wellhead pressure data, marine multichannel seismic pro- files, seafloor and water-column sonar surveys, and wellhead visual/acoustic monitoring. These data showed that the Macondo Well was not leaking after shut in, and therefore, it could remain safely shut until reservoir pressures were suppressed (killed) with heavy drilling mud and the well was sealed with cement
Highly Efficient Midinfrared On-Chip Electrical Generation of Graphene Plasmons by Inelastic Electron Tunneling Excitation
Inelastic electron tunneling provides a low-energy pathway for the excitation
of surface plasmons and light emission. We theoretically investigate tunnel
junctions based on metals and graphene. We show that graphene is potentially a
highly efficient material for tunneling excitation of plasmons because of its
narrow plasmon linewidths, strong emission, and large tunability in the
midinfrared wavelength regime. Compared to gold and silver, the enhancement can
be up to 10 times for similar wavelengths and up to 5 orders at their
respective plasmon operating wavelengths. Tunneling excitation of graphene
plasmons promises an efficient technology for on-chip electrical generation and
manipulation of plasmons for graphene-based optoelectronics and nanophotonic
integrated circuits.Comment: 12 pages, 7 figure
The spin state transition in LaCoO; revising a revision
Using soft x-ray absorption spectroscopy and magnetic circular dichroism at
the Co- edge we reveal that the spin state transition in LaCoO
can be well described by a low-spin ground state and a triply-degenerate
high-spin first excited state. From the temperature dependence of the spectral
lineshapes we find that LaCoO at finite temperatures is an inhomogeneous
mixed-spin-state system. Crucial is that the magnetic circular dichroism signal
in the paramagnetic state carries a large orbital momentum. This directly shows
that the currently accepted low-/intermediate-spin picture is at variance.
Parameters derived from these spectroscopies fully explain existing magnetic
susceptibility, electron spin resonance and inelastic neutron data
Local electronic structure and magnetic properties of LaMn0.5Co0.5O3 studied by x-ray absorption and magnetic circular dichroism spectroscopy
We have studied the local electronic structure of LaMn0.5Co0.5O3 using
soft-x-ray absorption spectroscopy at the Co-L_3,2 and Mn-L_3,2 edges. We found
a high-spin Co^{2+}--Mn^{4+} valence state for samples with the optimal Curie
temperature. We discovered that samples with lower Curie temperatures contain
low-spin nonmagnetic Co^{3+} ions. Using soft-x-ray magnetic circular dichroism
we established that the Co^{2+} and Mn^{4+} ions are ferromagnetically aligned.
We revealed also that the Co^{2+} ions have a large orbital moment:
m_orb/m_spin ~ 0.47. Together with model calculations, this suggests the
presence of a large magnetocrystalline anisotropy in the material and predicts
a non-trivial temperature dependence for the magnetic susceptibility.Comment: 8 pages, 7 figure
Spin blockade, orbital occupation and charge ordering in La_(1.5)Sr_(0.5)CoO4
Using Co-L_(2,3) and O-K x-ray absorption spectroscopy, we reveal that the
charge ordering in La_(1.5)Sr_(0.5)CoO4 involves high spin (S=3/2) Co^2+ and
low spin (S=0) Co^3+ ions. This provides evidence for the spin blockade
phenomenon as a source for the extremely insulating nature of the
La_(2-x)Sr_(x)CoO4 series. The associated e_g^2 and e_g^0 orbital occupation
accounts for the large contrast in the Co-O bond lengths, and in turn, the high
charge ordering temperature. Yet, the low magnetic ordering temperature is
naturally explained by the presence of the non-magnetic (S=0) Co^3+ ions. From
the identification of the bands we infer that La_(1.5)Sr_(0.5)CoO4 is a narrow
band material.Comment: 5 pages, 3 figure
Valence, spin, and orbital state of the Co ions in the one-dimensional Ca3Co2O6: an x-ray absorption and magnetic circular dichroism study
We have investigated the valence, spin, and orbital state of the Co ions in
the one-dimensional cobaltate Ca3Co2O6 using x-ray absorption and x-ray
magnetic circular dichroism at the Co-L2,3 edges. The Co ions at both the
octahedral Co_oct and trigonal Co_trig sites are found to be in a 3+ state.
From the analysis of the dichroism we established a low-spin state for the
Co_oct and a high-spin state with an anomalously large orbital moment of 1.7
muB at the Co3+ trig ions. This large orbital moment along the c-axis chain and
the unusually large magnetocrystalline anisotropy can be traced back to the
double occupancy of the d2 orbital in trigonal crystal field.Comment: 5 pages, 4 figure
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