Microelectrode study of pore size, ion size, and solvent effects on the charge/discharge behavior of microporous carbons for electrical double-layer capacitors

The capacitive behavior of TiC-derived carbon powders in two different electrolytes, NEt4BF4 in acetonitrile AN and NEt4BF4 in propylene carbonate PC, was studied using the cavity microelectrode CME technique. Comparisons of the cyclic voltammograms recorded at 10–1000 mV/s enabled correlation between adsorbed ion sizes and pore sizes, which is important for understanding the electrochemical capacitive behavior of carbon electrodes for electrical double-layer capacitor applications. The CME technique also allows a fast selection of carbon electrodes with matching pore sizes different sizes are needed for the negative and positive electrodes for the respective electrolyte system. Comparison of electrochemical capacitive behavior of the same salt, NEt4BF4, in different solvents, PC and AN, has shown that different pore sizes are required for different solvents, because only partial desolvation of ions occurs during the double-layer charging. Squeezing partially solvated ions into subnanometer pores, which are close to the desolvated ion size, may lead to distortion of the shape of cyclic voltammograms

Flight test and evaluation of Omega navigation in a general aviation aircraft. Volume 2: Appendices

Detailed documentation for each flight of the Omega Flight Evaluation study is presented, including flight test description sheets and actual flight data plots. Computer programs used for data processing and flight planning are explained and the data formats utilized by the Custom Interface Unit are summarized

Universality in one-dimensional fermions at finite temperature: Density, pressure, compressibility, and contact

We present finite-temperature, lattice Monte Carlo calculations of the particle number density, compressibility, pressure, and Tan's contact of an unpolarized system of short-range, attractively interacting spin-1/2 fermions in one spatial dimension, i.e., the Gaudin-Yang model. In addition, we compute the second-order virial coefficients for the pressure and the contact, both of which are in excellent agreement with the lattice results in the low-fugacity regime. Our calculations yield universal predictions for ultracold atomic systems with broad resonances in highly constrained traps. We cover a wide range of couplings and temperatures and find results that support the existence of a strong-coupling regime in which the thermodynamics of the system is markedly different from the noninteracting case. We compare and contrast our results with identical systems in higher dimensions.Comment: 6 pages, 7 figures; improved, published versio

Vast planes of satellites in a high resolution simulation of the Local Group: comparison to Andromeda

We search for vast planes of satellites (VPoS) in a high resolution simulation of the Local Group performed by the CLUES project, which improves significantly the resolution of former similar studies. We use a simple method for detecting planar configurations of satellites, and validate it on the known plane of M31. We implement a range of prescriptions for modelling the satellite populations, roughly reproducing the variety of recipes used in the literature, and investigate the occurence and properties of planar structures in these populations. The structure of the simulated satellite systems is strongly non-random and contains planes of satellites, predominantly co-rotating, with, in some cases, sizes comparable to the plane observed in M31 by Ibata et al.. However the latter is slightly richer in satellites, slightly thinner and has stronger co-rotation, which makes it stand out as overall more exceptional than the simulated planes, when compared to a random population. Although the simulated planes we find are generally dominated by one real structure, forming its backbone, they are also partly fortuitous and are thus not kinematically coherent structures as a whole. Provided that the simulated and observed planes of satellites are indeed of the same nature, our results suggest that the VPoS of M31 is not a coherent disc and that one third to one half of its satellites must have large proper motions perpendicular to the plane

High resolution simulations of the reionization of an isolated Milky Way - M31 galaxy pair

We present the results of a set of numerical simulations aimed at studying reionization at galactic scale. We use a high resolution simulation of the formation of the Milky Way-M31 system to simulate the reionization of the local group. The reionization calculation was performed with the post-processing radiative transfer code ATON and the underlying cosmological simulation was performed as part of the CLUES project. We vary the source models to bracket the range of source properties used in the literature. We investigate the structure and propagation of the galatic ionization fronts by a visual examination of our reionization maps. Within the progenitors we find that reionization is patchy, and proceeds locally inside out. The process becomes patchier with decreasing source photon output. It is generally dominated by one major HII region and 1-4 additional isolated smaller bubbles, which eventually overlap. Higher emissivity results in faster and earlier local reionization. In all models, the reionization of the Milky Way and M31 are similar in duration, i.e. between 203 Myr and 22 Myr depending on the source model, placing their zreion between 8.4 and 13.7. In all models except the most extreme, the MW and M31 progenitors reionize internally, ignoring each other, despite being relatively close to each other even during the epoch of reionization. Only in the case of strong supernova feedback suppressing star formation in haloes less massive than 10^9 M_sun, and using our highest emissivity, we find that the MW is reionized by M31.Comment: Accepted for publication in ApJ. 14 pages, 4 figures, 1 tabl

The physical determinants of the thickness of lamellar polymer crystals

Based upon kinetic Monte Carlo simulations of crystallization in a simple polymer model we present a new picture of the mechanism by which the thickness of lamellar polymer crystals is constrained to a value close to the minimum thermodynamically stable thickness. This description contrasts with those given by the two dominant theoretical approaches.Comment: 4 pages, 4 figures, revte