Double resonant absorption measurement of acetylene symmetric vibrational states probed with cavity ring down spectroscopy

A novel mid-infrared/near-infrared double resonant absorption setup for studying infrared-inactive vibrational states is presented. A strong vibrational transition in the mid-infrared region is excited using an idler beam from a singly resonant continuous-wave optical parametric oscillator, to populate an intermediate vibrational state. High output power of the optical parametric oscillator and the strength of the mid-infrared transition result in efficient population transfer to the intermediate state, which allows measuring secondary transitions from this state with a high signal-to-noise ratio. A secondary, near-infrared transition from the intermediate state is probed using cavity ring down spectroscopy, which provides high sensitivity in this wavelength region. Due to the narrow linewidths of the excitation sources, the rovibrational lines of the secondary transition are measured with sub-Doppler resolution. The setup is used to access a previously unreported symmetric vibrational state of acetylene, $\nu_1+\nu_2+\nu_3+\nu_4^1+\nu_5^{-1}$ in the normal mode notation. Single-photon transitions to this state from the vibrational ground state are forbidden. Ten lines of the newly measured state are observed and fitted with the linear least-squares method to extract the band parameters. The vibrational term value was measured to be at 9775.0018(45) $\text{cm}^{-1}$, the rotational parameter $B$ was 1.162222 $\text{cm}^{-1}$, and the quartic centrifugal distortion parameter $D$ was 3.998(62)$\times 10^{-6} \text{cm}^{-1}$, where the numbers in the parenthesis are one-standard errors in the least significant digits

Dutch gas distribution grid goes green:decision support tool for local biogas utilization

A Decision Support Tool (DST) has been developed that will aid Distribution Service Operators (DSOs) in their decision making process on which investments to make in the gas distribution grid in order to facilitate the use of biogas. The DST considers both the conversion of biogas to electricity as well as upgrading the biogas to green gas and consequently injecting it into the gas grid. Based on a starting configuration - i.e. a gas grid, gas consumers connected to this grid, and biomass locations -, in combination with several building blocks - e.g. a digester installation, an upgrading plant, and a CHP installation -, the tool generates several solutions to utilize the biomass. The DST generates solutions and determines for each solution two performance criteria: CO2 emission reduction and costs. Showing these solutions, gives the DSOs insight in the available options and which trade-offs can be made. A case study has been performed for the gas grid of the Dutch municipality of Zutphen. This case study showed that cost-wise there is a preference for centralization, i.e. digesting biomass at a central location and upgrading the biogas at a central location to green gas. Furthermore, conversion of biogas to electricity led to the highest CO2 emission reduction, but also to the highest cost.Furthermore, the case study showed that the DST basically works, and that it is a good way to explore the possible investment options. The tool however needs further improvements. For instance, more performance indicators (e.g. energy usage and reliability) will be included. Furthermore, the interaction with the electricity grid will be incorporated and multiple gas qualities in the distribution grid will be introduced. Also more boundary conditions should be added to the DST, for instance taking the topology of the area into account when laying pipeline

The Electron Glass in a Switchable Mirror: Relaxation, Aging and Universality

The rare earth hydride YH$_{3-\delta}$ can be tuned through the metal-insulator transition both by changing $\delta$ and by illumination with ultraviolet light. The transition is dominated by strong electron-electron interactions, with transport in the insulator sensitive to both a Coulomb gap and persistent quantum fluctuations. Via a systematic variation of UV illumination time, photon flux, Coulomb gap depth, and temperature, we demonstrate that polycrystalline YH$_{3-\delta}$ serves as a model system for studying the properties of the interacting electron glass. Prominent among its features are logarithmic relaxation, aging, and universal scaling of the conductivity

Multiwavelength Mass Comparisons of the z~0.3 CNOC Cluster Sample

Results are presented from a detailed analysis of optical and X-ray observations of moderate-redshift galaxy clusters from the Canadian Network for Observational Cosmology (CNOC) subsample of the EMSS. The combination of extensive optical and deep X-ray observations of these clusters make them ideal candidates for multiwavelength mass comparison studies. X-ray surface brightness profiles of 14 clusters with 0.17<z<0.55 are constructed from Chandra observations and fit to single and double beta-models. Spatially resolved temperature analysis is performed, indicating that five of the clusters in this sample exhibit temperature gradients within their inner 60-200 kpc. Integrated spectra extracted within R_2500 provide temperature, abundance, and luminosity information. Under assumptions of hydrostatic equilibrium and spherical symmetry, we derive gas and total masses within R_2500 and R_200. We find an average gas mass fraction within R_200 of 0.136 +/- 0.004, resulting in Omega_m=0.28 +/- 0.01 (formal error). We also derive dynamical masses for these clusters to R_200. We find no systematic bias between X-ray and dynamical methods across the sample, with an average M(dyn)/M(X-ray) = 0.97 +/- 0.05. We also compare X-ray masses to weak lensing mass estimates of a subset of our sample, resulting in a weighted average of M(lens)/M(X-ray) of 0.99 +/- 0.07. We investigate X-ray scaling relationships and find powerlaw slopes which are slightly steeper than the predictions of self-similar models, with an E(z)^(-1) Lx-Tx slope of 2.4 +/- 0.2 and an E(z) M_2500-Tx slope of 1.7 +/- 0.1. Relationships between red-sequence optical richness (B_gc,red) and global cluster X-ray properties (Tx, Lx and M_2500) are also examined and fitted.Comment: Astrophysical Journal, 48 pages, 11 figures, LaTeX. Added correction to surface brightness normalization of MS1512.4+3647, corrections to sample gas mass fractions and calculated value of Omega_m. Figure resolution has been reduced to comply with astro-ph upload requirement

The origin of peak-offsets in weak-lensing maps

Centroid positions of peaks identified in weak lensing mass maps often show offsets with respect to other means of identifying halo centres, like position of the brightest cluster galaxy or X-ray emission centroid. Here we study the effect of projected large-scale structure (LSS), smoothing of mass maps, and shape noise on the weak lensing peak positions. Additionally we compare the offsets in mass maps to those found in parametric model fits. Using ray-tracing simulations through the Millennium Run $N$-body simulation, we find that projected LSS does not alter the weak-lensing peak position within the limits of our simulations' spatial resolution, which exceeds the typical resolution of weak lensing maps. We conclude that projected LSS, although a major contaminant for weak-lensing mass estimates, is not a source of confusion for identifying halo centres. The typically reported offsets in the literature are caused by a combination of shape noise and smoothing alone. This is true for centroid positions derived both from mass maps and model fits.Comment: 6 pages, 4 figures, accepted for publication in MNRAS, significant additions to v

Galaxy Masses

Galaxy masses play a fundamental role in our understanding of structure formation models. This review addresses the variety and reliability of mass estimators that pertain to stars, gas, and dark matter. The different sections on masses from stellar populations, dynamical masses of gas-rich and gas-poor galaxies, with some attention paid to our Milky Way, and masses from weak and strong lensing methods, all provide review material on galaxy masses in a self-consistent manner.Comment: 145 pages, 28 figures, to appear in Reviews of Modern Physics. Figure 22 is missing here, and Figs. 15, 26-28 are at low resolution. This version has a slightly different title and some typos fixed in Chapter 5. For the full review with figures, please consult: http://www.astro.queensu.ca/~courteau/GalaxyMasses_28apr2014.pd