Dependence of drop speed on nozzle diameter, viscosity and drive amplitude in drop-on-demand ink-jet printing

Results of recent experiments and numerical simulations are presented, which have been used to establish empirical rules for the dependence of drop speed on nozzle diameter and drive amplitude for Newtonian and non-Newtonian fluids printed with a range of different ink-jet print-head technologies. Experiments were carried out with Xaar, MicroFab and Spectra Dimatix print heads and with solutions of polystyrene in diethyl phthalate as model fluids. These results are compared with predictions from recent numerical codes developed by collaborators in the University of Leeds, and from simple models for drop-on-demand fluid jetting resulting from physical law

How PEDOT:PSS solutions produce satellite-free inkjets

This work is sponsored by EPSRC grant number RG5560

Meniscus Motion Inside A DoD Inkjet Print-Head Nozzle

This is the author accepted manuscript. The final version is available from the Society for Imaging Sciences and Technology via http://www.ingentaconnect.com/contentone/ist/nipdf/2016/00002016/00000001/art00087A new study of the jetting performance for drop-on-demand (DoD) inkjet print heads investigated meniscus motions inside the transparent nozzles of MicroFab inkjet print heads. A composite image representation of the observed meniscus motions, imaged at high resolution using a spark flash light source, was developed for our subsequent analyses of the influences of drive voltage and pulse dwell time and also the ink properties. At higher drive voltages a slow damped refill (following de-pinning of the meniscus from the very edge of the nozzle exit) was also clearly observed. This and many other interesting phenomena were observed with the composite images: internal bubbles that progressed through the nozzle region over relatively long timescales, internal break-off of the jet from the meniscus surface, satellite formation and merging, and the contact line de-pinning not previously observed before.This research was performed by CSR under the Undergraduate Research Opportunities Program (UROP) scheme, within the University of Cambridge Inkjet Research Centre, funded by Xaar Ltd. SDH supervised and held an EPSRC Impact Acceleration Knowledge Transfer Fellowship (grant no. EP/K5037574/1) for working with a Xaar R&D team during the initial part of this project

Droplet Misalignment Limit for Inkjet Printing into Cavities on Textured Surfaces

The control of droplets deposited onto textured surfaces is of great importance for both engineering and medical applications. This research investigates the dynamics of a single droplet deposited into a confined space and its final equilibrium morphology, with emphasis given to droplet deposition under print head misalignment, the effect of nonuniform wettability, and deposition of droplets with varying sizes. A multiphase pseudopotential lattice Boltzmann methodology is used to simulate the process of deposition. The print quality is characterized in terms of a parameter referred to as the wetted fraction, which describes the proportion of the cavity that is wetted by the droplet. Our results show how single and multiple axis misalignment affect the final equilibrium morphology, and it was found for comparable configurations that multiaxis misalignment resulted in a higher wetted fraction. Investigations into wettabilities of the substrate and cavity wall revealed how larger ratios of the contact angles between the two enhance the ability for the droplet to self-align within the cavity. Additionally, a range of uniform wettabilities between the substrate and cavity were found, which mitigate against misalignment. Investigations into varying droplet sizes relative to the cavity revealed how misalignment can be compensated for with larger droplets, and limits for filling a cavity with a single drop are defined. Finally, we explore the deposition with misalignment into closely positioned cavities where it is found that the spacing between cavities is a key factor in determining the maximum permissible misalignment

Oscillations of aqueous PEDOT:PSS fluid droplets and the properties of complex fluids in drop-on-demand inkjet printing

Shear-thinning aqueous poly(3,4-ethylenedioxythiophene): poly(styrene sulphonate) (PEDOT:PSS) fluids were studied under the conditions of drop-on-demand inkjet printing. Ligament retraction caused oscillation of the resulting drops, from which values of surface tension and viscosity were derived. Effective viscosities of <4 mPa s at drop oscillation frequencies of 13–33 kHz were consistent with conventional high-frequency rheometry, with only a small possible contribution from viscoelasticity with a relaxation time of about 6 μs. Strong evidence was found that the viscosity, reduced by shear-thinning in the printhead nozzle, recovered as the drop formed. The low viscosity values measured for the drops in flight were associated with the strong oscillation induced by ligament retraction, while for a weakly perturbed drop the viscosity remained high. Surface tension values in the presence of surfactant were significantly higher than the equilibrium values, and consistent with the surface age of the drops. [Graphical abstract - see article]This work was supported by EPSRC and a consortium of industrial partners (EPSRC Grant no. EP/H018913/1: Innovation in industrial inkjet technology). The high-speed camera and high power flash lamp were provided by the EPSRC Engineering Instrument Pool and we thank Adrian Walker for his help.This is the final version of the article. It first appeared from Elsevier via http://dx.doi.org/10.1016/j.jnnfm.2015.05.00

The Egyptian Nile: Human Transformation of an Ancient River

This is the final version. Available on open access from UNESCO via the DOI in this recordThe Nile, the longest river of the world, connects Northeast Africa from its headwaters near Lake Victoria to the Mediterranean Sea. This chapter focuses on the Nile in Egypt, where the river's annual inundation (until the building of the two modern dams at Aswan) was the source of the country's fecundity and guarantor of its civilization since the 6th millennium BCE. While the historical population of Egypt remained at a maximum of c. four million people until the mid-19th century when Vice-Roy Muhammad Ali modernized the country, in 2019 the number passed the threshold of 100 million people. Increased demographic pressure, the alteration of the country's ecology through the mega-impact of the construction of the Aswan High Dam, and industrialization have led to a massive transformation of the Nile River system. One of the consequences has been an almost complete extinction of the country's native fauna and flora. The overuse of the water (rice and cotton irrigation projects) and the absence of the river's historical natural sedimentation have had irreversible effects on Egypt's agriculture and heritage (salination; disappearance of archaeological sites) and caused land loss to rising sea levels in the delta. In view of the environmental degradation in the Nile valley, and the dangers to Egypt's water security posed by overpopulation and the construction of the Merowe dams in Sudan and the Renaissance dam in Ethiopia, sustainable water management is of critical importance

Texture Analysis of Fractional Water Content Images Acquired during PET/MRI: Initial Evidence for an Association with Total Lesion Glycolysis, Survival and Gene Mutation Profile in Primary Colorectal Cancer.

To assess the capability of fractional water content (FWC) texture analysis (TA) to generate biologically relevant information from routine PET/MRI acquisitions for colorectal cancer (CRC) patients. Thirty consecutive primary CRC patients (mean age 63.9, range 42-83 years) prospectively underwent FDG-PET/MRI. FWC tumor parametric images generated from Dixon MR sequences underwent TA using commercially available research software (TexRAD). Data analysis comprised (1) identification of functional imaging correlates for texture features (TF) with low inter-observer variability (intraclass correlation coefficient: ICC > 0.75), (2) evaluation of prognostic performance for FWC-TF, and (3) correlation of prognostic imaging signatures with gene mutation (GM) profile. Of 32 FWC-TF with ICC > 0.75, 18 correlated with total lesion glycolysis (TLG, highest: rs = -0.547, p = 0.002). Using optimized cut-off values, five MR FWC-TF identified a good prognostic group with zero mortality (lowest: p = 0.017). For the most statistically significant prognostic marker, favorable prognosis was significantly associated with a higher number of GM per patient (medians: 7 vs. 1.5, p = 0.009). FWC-TA derived from routine PET/MRI Dixon acquisitions shows good inter-operator agreement, generates biological relevant information related to TLG, GM count, and provides prognostic information that can unlock new clinical applications for CRC patients

Formulation, characterisation and flexographic printing of novel Boger fluids to assess the effects of ink elasticity on print uniformity

Model elastic inks were formulated, rheologically characterised in shear and extension, and printed via flexography to assess the impact of ink elasticity on print uniformity. Flexography is a roll-to-roll printing process with great potential in the mass production of printed electronics for which understanding layer uniformity and the influence of rheology is of critical importance. A new set of flexo-printable Boger fluids was formulated by blending polyvinyl alcohol and high molecular weight polyacrylamide to provide inks of varying elasticity. During print trials, the phenomenon of viscous fingering was observed in all prints, with those of the Newtonian ink exhibiting a continuous striping in the printing direction. Increasing elasticity significantly influenced this continuity, disrupting it and leading to a quantifiable decrease in the overall relative size of the printed finger features. As such, ink elasticity was seen to have a profound effect on flexographic printing uniformity, showing the rheological tuning of inks may be a route to obtaining specific printed features

Evolution of Gaussian wave packets in capillary jets

A temporal analysis of the evolution of Gaussian wave packets in cylindrical capillary jets is presented through both a linear two-mode formulation and a one-dimensional nonlinear numerical scheme. These analyses are normally applicable to arbitrary initial conditions but our study focuses on pure-impulsive ones. Linear and nonlinear findings give consistent results in the stages for which the linear theory is valid. The inverse Fourier transforms representing the formal linear solution for the jet shape is both numerically evaluated and approximated by closed formulas. After a transient, these formulas predict an almost Gaussian-shape deformation with (i) a progressive drift of the carrier wave number to that given by the maximum of the Rayleigh dispersion relation, (ii) a progressive increase of its bell width, and (iii) a quasi-exponential growth of its amplitude. These parameters agree with those extracted from the fittings of Gaussian wave packets to the numerical simulations. Experimental results are also reported on near-Gaussian pulses perturbing the exit velocity of a 2 mm diameter water jet. The possibility of controlling the breakup location along the jet and other features, such as pinch-off simultaneity, are demonstrated