A comprehensive analysis of the (R13xR13)R13.9{\deg} type II structure of silicene on Ag(111)

In this paper, using the same geometrical approach than for the (2R3x2R3) R30{\deg} structure (H. Jamgotchian et al., 2015, Journal of Physics. Condensed Matter 27 395002), for the (R13xR13)R13.9{\deg} type II structure, we propose an atomic model of the silicene layer based on a periodic relaxation of the strain epitaxy. This relaxation creates periodic arrangements of perfect areas of (R13xR13)R13.9{\deg} type II structure surrounded by defect areas. A detailed analysis of the main published experimental results, obtained by Scanning Tunneling Microscopy and by Low Energy Electron Diffraction, shows a good agreement with the geometrical model.Comment: 20 pages, 9 figure

Urinary Calculi: Review of Classification Methods and Correlations with Etiology

Current physical and chemical methods available for urinary stones analysis are critically reviewed. No one method is sufficient to provide all the clinically useful information on the structure and composition of the stones. We show that a combination of refined morphological and structural examination of stone with optical microscopy, complemented by compositional analysis using infrared spectroscopy of the core, cross-section and surface of calculi, provides a precise and reliable method for identifying the structure and crystalline composition, and permits quantification of stone components while being highly cost effective. Using such morphoconstitutional studies leads to a classification of urinary stones in seven distinctive types and twenty-one subtypes among monohydrate (whewellite) and dihydrate (weddellite) calcium oxalates, phosphates, uric acid, urates, protein, and cystine calculi. Furthermore, all of the recognized sub-types exhibit correlations with specific pathophysiologic conditions. We conclude that such morphoconstitutional refined analysis and classification of urinary calculi is of interest to properly identify the type of stone disease and provides clues to etiopathogeny

Methodological Aspects of Spontaneous Crystalluria Studies in Calcium Stone Formers

Despite nearly a half-century of study, the clinical value of spontaneous crystalluria (Cx) examinations in calcium stone formers (CaSF) is still uncertain. The analytical complexity of urine particle study is largely responsible for this situation. As a result, there is no consensus regarding technical methods in Cx with several techniques for urine sampling and three different instruments currently used for particle study, namely, particle counting (PC), light microscopy (LM) and petrographic microscopy (PM). In this work, we first examined urine sampling and instrument methods regarding their appropriateness for Cx studies. Then we performed a comparative analysis of Cx studies in CaSF. Despite many technical and clinical discrepancies, several studies agree that the frequency of all particles and of the weddellite and whewellite calcium oxalate (CaOx) crystalline phases are increased in CaSF as compared to normal subjects (NS). Particle sizes and aggregation ratio are also often increased. Altogether, these results reinforce the need for an efficient method for Cx studies in these patients. Examining each technique leads us to conclude that most particle parameters can be studied by direct LM observation of freshly voided urine samples, i.e., urine samples without any separation steps. For clinical applications, several examinations should be performed, first to define the specific Cx characteristics in a patient, then for the study of treatment efficiency on Cx control, and finally, during the patient follow-up. Due to Cx variability in each patient, the frequency of Cx examinations during each phase needs to be determined in long-term comparative prospective studies of CaSF

Current density maps, magnetizability, and nuclear magnetic shielding tensors of bis-heteropentalenes. II. Furo-furan Isomers

Magnetic susceptibility and nuclear magnetic shielding at the nuclei of bis-heteropentalenes formed by two furan units ([2,3-b], [3,2-b], [3,4-b], and [3,4-c] isomers) have been computed by several approximated techniques and a large Gaussian basis set to achieve near Hartree–Fock estimates. Ab initio models of the ring currents induced by a magnetic field normal to the molecular plane were obtained for the three isomeric systems of higher symmetry, showing that the π electrons give rise to intense diamagnetic circulation. The π currents are responsible for enhanced magnetic anisotropy and strong out-of-plane proton deshielding. The theoretical findings are used to build up a “diatropicity matrix” for two fused five-membered heterocyclic [email protected] ; [email protected]

A human coronavirus responsible for the common cold massively kills dendritic cells but not monocytes

Copyright @ 2012, American Society for Microbiology.Human coronaviruses are associated with upper respiratory tract infections that occasionally spread to the lungs and other organs. Although airway epithelial cells represent an important target for infection, the respiratory epithelium is also composed of an elaborate network of dendritic cells (DCs) that are essential sentinels of the immune system, sensing pathogens and presenting foreign antigens to T lymphocytes. In this report, we show that in vitro infection by human coronavirus 229E (HCoV-229E) induces massive cytopathic effects in DCs, including the formation of large syncytia and cell death within only few hours. In contrast, monocytes are much more resistant to infection and cytopathic effects despite similar expression levels of CD13, the membrane receptor for HCoV-229E. While the differentiation of monocytes into DCs in the presence of granulocyte-macrophage colony-stimulating factor and interleukin-4 requires 5 days, only 24 h are sufficient for these cytokines to sensitize monocytes to cell death and cytopathic effects when infected by HCoV-229E. Cell death induced by HCoV-229E is independent of TRAIL, FasL, tumor necrosis factor alpha, and caspase activity, indicating that viral replication is directly responsible for the observed cytopathic effects. The consequence of DC death at the early stage of HCoV-229E infection may have an impact on the early control of viral dissemination and on the establishment of long-lasting immune memory, since people can be reinfected multiple times by HCoV-229E

Technical design and characterization of a ground based solar metrology network on Reunion Island

Paper presented to the 3rd Southern African Solar Energy Conference, South Africa, 11-13 May, 2015.The roadmap of Reunion Island regarding energy is to reach autonomy by 2030. Obviously, renewable energies will play a key role in this ambitious project. However, a couple of years ago, a limit set by the French government relatively to the amount of lethal power injected on the electrical grid stopped the thrust: at any time, intermittent sources should not exceed 30 % of the whole production. This is due to the fragility of the grid: rugged topography, no interconnection. The University of La Reunion through the LE2P lab (Energy, Electronic and Process) decided to search a solution by predicting the solar resource in order to erase part of the intermittency of the production coming from the solar plants. Along this track, the first step is to evaluate precisely the resource and study its spatio-temporal variability. To do so, the LE2P gets engaged in deploying, at ground level, a network of monitoring stations. These units should be capable to produce field data responding to specific requirements in terms of acquisition frequency and quality, compatible with the clustering tools and mapping programs developed beside. Today, LE2P team manages a fleet of more than 15 stations, with various configurations, all over Reunion Island and plans to extend its network to neighboring territories. This article proposes to present in details the different components of a typical station, how they have been selected and how they are maintained. We will also see how the lab gets organized in order to propose top quality data to the solar scientific community.cf201

Technical design and characterization of a ground based solar metrology network on Reunion Island

Paper presented to the 3rd Southern African Solar Energy Conference, South Africa, 11-13 May, 2015.The roadmap of Reunion Island regarding energy is to reach autonomy by 2030. Obviously, renewable energies will play a key role in this ambitious project. However, a couple of years ago, a limit set by the French government relatively to the amount of lethal power injected on the electrical grid stopped the thrust: at any time, intermittent sources should not exceed 30 % of the whole production. This is due to the fragility of the grid: rugged topography, no interconnection. The University of La Reunion through the LE2P lab (Energy, Electronic and Process) decided to search a solution by predicting the solar resource in order to erase part of the intermittency of the production coming from the solar plants. Along this track, the first step is to evaluate precisely the resource and study its spatio-temporal variability. To do so, the LE2P gets engaged in deploying, at ground level, a network of monitoring stations. These units should be capable to produce field data responding to specific requirements in terms of acquisition frequency and quality, compatible with the clustering tools and mapping programs developed beside. Today, LE2P team manages a fleet of more than 15 stations, with various configurations, all over Reunion Island and plans to extend its network to neighboring territories. This article proposes to present in details the different components of a typical station, how they have been selected and how they are maintained. We will also see how the lab gets organized in order to propose top quality data to the solar scientific community.cf201