Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal-organic framework

Thermally-densified hafnium terephthalate UiO-66(Hf) is shown to exhibit the strongest isotropic negative thermal expansion (NTE) effect yet reported for a metal-organic framework (MOF). Incorporation of correlated vacancy defects within the framework affects both the extent of thermal densification and the magnitude of NTE observed in the densified product. We thus demonstrate that defect inclusion can be used to tune systematically the physical behaviour of a MOF.Comment: 8 pages, 4 figures, revise

Ratio control in a cascade model of cell differentiation

We propose a kind of reaction-diffusion equations for cell differentiation, which exhibits the Turing instability. If the diffusivity of some variables is set to be infinity, we get coupled competitive reaction-diffusion equations with a global feedback term. The size ratio of each cell type is controlled by a system parameter in the model. Finally, we extend the model to a cascade model of cell differentiation. A hierarchical spatial structure appears as a result of the cell differentiation. The size ratio of each cell type is also controlled by the system parameter.Comment: 13 pages, 7 figure

The effect of seed moisture content and hot water treatment on carrot seed viability and Alternaria radicina control

Hot water treatment of seeds to control seedborne pathogens is an important tool for organic seed production. Reducing seed moisture content may have the potential to increase carrot (Daucus carota L. var. sativus D.C.) seed tolerance to treatment. Two hot water seed treatment experiments were conducted

The effect of seed moisture content and the duration and temperature of hot water treatment on carrot seed viability and the control of Alternaria Radicina

Hot water treatment of seeds to control seedborne pathogens is an important tool for organic seed production. Reducing seed moisture content may have the potential to increase carrot (Daucus carota L. var. sativus D.C.) seed tolerance to treatment. Two hot water seed treatment experiments were conducted. The first studied the effect of seed moisture content (SMC), treatment temperature and treatment duration on germination. Maximum safe treatment temperature and durations were established at 50°C and 30-40 min. Germination decreased slightly from 68% at 5% SMC to 63% at 20% SMC (LSD 1.2) for all durations. The second experiment studied the effect of initial SMC and treatment durations on infestation of seed by Alternaria radicina and seed germination. Treatment at 50°C for 30 min for all SMC compared to the control resulted in a decrease in A. radicina infestation from 69.2 to 1.7%. Reducing SMC from 20 to 5% for all durations resulted in a small decrease in infestation from 25% to 18% (LSD 1.5). Reducing SMC to 5% prior to hot water treatment may be a commercially viable means of minimising reductions in seed viability and decreasing fungal infestation levels

Counselling in primary care : a systematic review of the evidence

Primary objective: To undertake a systematic review which aimed to locate, appraise and synthesise evidence to obtain a reliable overview of the clinical effectiveness, cost-effectiveness and user perspectives regarding counselling in primary care. Main results: Evidence from 26 studies was presented as a narrative synthesis and demonstrated that counselling is effective in the short term, is as effective as CBT with typical heterogeneous primary care populations and more effective than routine primary care for the treatment of non-specific generic psychological problems, anxiety and depression. Counselling may reduce levels of referrals to psychiatric services, but does not appear to reduce medication, the number of GP consultations or overall costs. Patients are highly satisfied with the counselling they have received in primary care and prefer counselling to medication for depression. Conclusions and implications for future research: This review demonstrates the value of counselling as a valid choice for primary care patients and as a broadly effective therapeutic intervention for a wide range of generic psychological conditions presenting in the primary care setting. More rigorous clinical and cost-effectiveness trials are needed together with surveys of more typical users of primary care services

Mapping the ν⊙\nu_\odot Secular Resonance for Retrograde Irregular Satellites

Constructing dynamical maps from the filtered output of numerical integrations, we analyze the structure of the $\nu_\odot$ secular resonance for fictitious irregular satellites in retrograde orbits. This commensurability is associated to the secular angle $\theta = \varpi - \varpi_\odot$, where $\varpi$ is the longitude of pericenter of the satellite and $\varpi_\odot$ corresponds to the (fixed) planetocentric orbit of the Sun. Our study is performed in the restricted three-body problem, where the satellites are considered as massless particles around a massive planet and perturbed by the Sun. Depending on the initial conditions, the resonance presents a diversity of possible resonant modes, including librations of $\theta$ around zero (as found for Sinope and Pasiphae) or 180 degrees, as well as asymmetric librations (e.g. Narvi). Symmetric modes are present in all giant planets, although each regime appears restricted to certain values of the satellite inclination. Asymmetric solutions, on the other hand, seem absent around Neptune due to its almost circular heliocentric orbit. Simulating the effects of a smooth orbital migration on the satellite, we find that the resonance lock is preserved as long as the induced change in semimajor axis is much slower compared to the period of the resonant angle (adiabatic limit). However, the librational mode may vary during the process, switching between symmetric and asymmetric oscillations. Finally, we present a simple scaling transformation that allows to estimate the resonant structure around any giant planet from the results calculated around a single primary mass.Comment: 11 pages, 13 figure

A long-lived horseshoe companion to the Earth

We present a dynamical investigation of a newly found asteroid, 2010 SO16, and the discovery that it is a horseshoe companion of the Earth. The object's absolute magnitude (H=20.7) makes this the largest object of its type known to-date. By carrying out numerical integrations of dynamical clones, we find that (a) its status as a horseshoe is secure given the current accuracy of its ephemeris, and (b) the time spent in horseshoe libration with the Earth is several times 10^5 yr, two orders of magnitude longer than determined for other horseshoe asteroids of the Earth. Further, using a model based on Hill's approximation to the three-body problem, we show that, apart from the low eccentricity which prevents close encounters with other planets or the Earth itself, its stability can be attributed to the value of its Jacobi constant far from the regime that allows transitions into other coorbital modes or escape from the resonance altogether. We provide evidence that the eventual escape of the asteroid from horseshoe libration is caused by the action of planetary secular perturbations and the stochastic evolution of the eccentricity. The questions of its origin and the existence of as-yet-undiscovered co-orbital companions of the Earth are discussed.Comment: Accepted in MNRAS; 6 pages, 3 figures, 2 table

What Can We Conclude from Death Registration? Improved Methods for Evaluating Completeness

Julie Rajaratnam and colleagues evaluate the performance of a suite of demographic methods that estimate the fraction of deaths registered and counted by civil registration systems, and identify three variants that generally perform the best