507 research outputs found
Predicting the influence of a p2-symmetric substrate on molecular self-organization with an interaction-site model
An interaction-site model can a priori predict molecular selforganisation on a new substrate in Monte Carlo simulations. This is experimentally confirmed with scanning tunnelling microscopy on FreÂŽchet dendrons of a pentacontane template. Local and global ordering motifs, inclusion molecules and a rotated unit cell are correctly predicted
Centrifugal terms in the WKB approximation and semiclassical quantization of hydrogen
A systematic semiclassical expansion of the hydrogen problem about the
classical Kepler problem is shown to yield remarkably accurate results. Ad hoc
changes of the centrifugal term, such as the standard Langer modification where
the factor l(l+1) is replaced by (l+1/2)^2, are avoided. The semiclassical
energy levels are shown to be exact to first order in with all higher
order contributions vanishing. The wave functions and dipole matrix elements
are also discussed.Comment: 5 pages, to appear in Phys. Rev.
Quantum Brownian Motion With Large Friction
Quantum Brownian motion in the strong friction limit is studied based on the
exact path integral formulation of dissipative systems. In this limit the
time-nonlocal reduced dynamics can be cast into an effective equation of
motion, the quantum Smoluchowski equation. For strongly condensed phase
environments it plays a similar role as master equations in the weak coupling
range. Applications for chemical, mesoscopic, and soft matter systems are
discussed and reveal the substantial role of quantum fluctuations.Comment: 11 pages, 6 figures, to appear in: Chaos: "100 years of Brownian
motion
Probing Scattering Wave Functions Close to the Nucleus
Recently, three-dimensional imaging of the ejected electrons following 100ââMeV/amu C6+ single ionization of helium led to the observation of a new structure not predicted by theory [M. Schulz et al., Nature (London) 422, 48 (2003)]. Instead of the usual ârecoil lobeâ centered on the momentum-transfer axis, a ring-shaped structure centered on the beam axis was observed. New measurements at 2ââMeV/amu exhibit a similar structure, which is now predicted by theory. We argue that the same theory failed at 100ââMeV/amu because the faster projectiles probe distances much closer to the nucleus, where our multiple-scattering model is expected to break down
Analysing horizontal equity in enrolment in Disease Management Programmes for coronary heart disease in Germany 2008â2010
Background: Disease Management Programmes (DMPs) have been introduced in Germany ten years ago with the aim to improve effectiveness and equity of care, but little is known about the degree to which enrolment in the programme meets the principles of equity in health care. We aimed to analyse horizontal equity in DMP enrolment among patients with coronary heart disease (CHD). Methods: Cross-sectional analysis of horizontal inequities in physician-reported enrolment in the DMP for CHD in a large population-based cohort-study in Germany (2008â2010). We calculated horizontal inequity indices (HII) and their 95% confidence intervals [95%CI] for predicted need-standardised DMP enrolment across two measures of socio-economic status (SES) (educational attainment, regional deprivation) stratified by sex. Need-standardised DMP enrolment was predicted in multi-level logistic regression models. Results Among Nâ=â1,280 individuals aged 55â84 years and diagnosed with CHD, DMP enrolment rates were 22.2% (women) and 35.0% (men). Education-related inequities in need-standardised DMP enrolment favoured groups with lower education, but HII estimates were not significant. Deprivation-related inequities among women significantly favoured groups with higher SES (HIIâ=â0.086 [0.007 ; 0.165]. No such deprivation-related inequities were seen among men (HIIâ=â0.014 [â0.048 ; 0.077]). Deprivation-related inequities across the whole population favoured groups with higher SES (HII estimates not significant). Conclusion: Need-standardised DMP enrolment was fairly equitable across educational levels. Deprivation-related inequities in DMP enrolment favoured women living in less deprived areas relative to those living in areas with higher deprivation. Further research is needed to gain a better understanding of the mechanisms that contribute to deprivation-related horizontal inequities in DMP enrolment among women
Systematic Analysis of Double-Ionization Dynamics Based on Four-Body Dalitz Plots
We report on an experimental and theoretical systematic study of double ionization of helium by ion impact in terms of four-particle Dalitz plots. Several collision systems covering abroad range of perturbation parameters η (projectile charge to speed ratio) were investigated. With increasing η we observe a systematic trend from features, characteristic to correlated double-ionization mechanisms, to signatures of higher-order processes not requiring electron-electron correlations [the mechanism called two-step-two projectile-electron interaction (TS-2)]. The data for the largest η can qualitatively be amazingly well described by a simple model only including the TS-2 mechanism
Tracing Multiple Scattering Patterns in Absolute (e, 2e) Cross Sections for Hâ and He over a 4Ï Solid Angle
Absolutely normalized (e,2e) measurements for H2 and He covering the full solid angle of one ejected electron are presented for 16 eV sum energy of both final state continuum electrons. For both targets rich cross-section structures in addition to the binary and recoil lobes are identified and studied as a function of the fixed electron\u27s emission angle and the energy sharing among both electrons. For H2 their behavior is consistent with multiple scattering of the projectile as discussed before. For He the binary and recoil lobes are significantly larger than for H2 and partly cover the multiple scattering structures. To highlight these patterns we propose a alternative representation of the triply differential cross section. Nonperturbative calculations are in good agreement with the He results and show discrepancies for H2 in the recoil peak region. For H2 a perturbative approach reasonably reproduces the cross-section shape but deviates in absolute magnitude
Flexible Work Time in Germany: Do Workers Like it and How Have Employers Exploited it Over the Cycle?
Semiclassical time evolution of the density matrix and tunneling
The time dependent density matrix of a system with potential barrier is
studied using path integrals. The characterization of the initial state, which
is assumed to be restricted to one side of the barrier, and the time evolution
of the density matrix lead to a three-fold path integral which is evaluated in
the semiclassical limit. The semiclassical trajectories are found to move in
the complex coordinate plane and barrier penetration only arises due to
fluctuations. Both the form of the semiclassical paths and the relevant
fluctuations change significantly as a function of temperature. The
semiclassical analysis leads to a detailed picture of barrier penetration in
the real time domain and the changeover from thermal activation to quantum
tunneling. Deep tunneling is associated with quasi-zero modes in the
fluctuation spectrum about the semiclassical orbits in the long time limit. The
connection between this real time description of tunneling and the standard
imaginary time instanton approach is established. Specific results are given
for a double well potential and an Eckart barrier.Comment: 27 pages, 8 figures, to be published in Phys. Rev.
Dissipative Quantum Systems with Potential Barrier. General Theory and Parabolic Barrier
We study the real time dynamics of a quantum system with potential barrier
coupled to a heat-bath environment. Employing the path integral approach an
evolution equation for the time dependent density matrix is derived. The time
evolution is evaluated explicitly near the barrier top in the temperature
region where quantum effects become important. It is shown that there exists a
quasi-stationary state with a constant flux across the potential barrier. This
state generalizes the Kramers flux solution of the classical Fokker-Planck
equation to the quantum regime. In the temperature range explored the quantum
flux state depends only on the parabolic approximation of the anharmonic
barrier potential near the top. The parameter range within which the solution
is valid is investigated in detail. In particular, by matching the flux state
onto the equilibrium state on one side of the barrier we gain a condition on
the minimal damping strength. For very high temperatures this condition reduces
to a known result from classical rate theory. Within the specified parameter
range the decay rate out of a metastable state is calculated from the flux
solution. The rate is shown to coincide with the result of purely thermodynamic
methods. The real time approach presented can be extended to lower temperatures
and smaller damping.Comment: 29 pages + 1 figure as compressed ps-file (uufiles) to appear in
Phys. Rev.
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