968 research outputs found

    The Image of Achilles and Hector in Roman Poetry. Prolegomena

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    In this article the author tries to present the images of two great heroes of The Iliad, Achilles and Hector, that emerges from the Roman poetry and compare them with those present in the Greek tradition. In this analysis, focus is primarily put on The Aeneid of Virgil and on Ovid’s works, with minor remarks to the works of other authors. The article concludes that in the case of Achilles there is a huge difference between the image of this character in the Greek tradition and in Roman poetry. Achilles, who for Greeks was an object of universal esteem, in the eyes of Romans has become a synonym of a criminal, a ruthless murderer and the personification of the destroyer of Troy. The image of Hector in Roman literature is also different from the Greek perspective, since Roman authors idealized the prince of Troy to such an extent that they saw him as the greatest hero of the Trojan War

    Discrete Globalised Dual Heuristic Dynamic Programming in Control of the Two-Wheeled Mobile Robot

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    Network-based control systems have been emerging technologies in the control of nonlinear systems over the past few years. This paper focuses on the implementation of the approximate dynamic programming algorithm in the network-based tracking control system of the two-wheeled mobile robot, Pioneer 2-DX. The proposed discrete tracking control system consists of the globalised dual heuristic dynamic programming algorithm, the PD controller, the supervisory term, and an additional control signal. The structure of the supervisory term derives from the stability analysis realised using the Lyapunov stability theorem. The globalised dual heuristic dynamic programming algorithm consists of two structures: the actor and the critic, realised in a form of neural networks. The actor generates the suboptimal control law, while the critic evaluates the realised control strategy by approximation of value function from the Bellman’s equation. The presented discrete tracking control system works online, the neural networks’ weights adaptation process is realised in every iteration step, and the neural networks preliminary learning procedure is not required. The performance of the proposed control system was verified by a series of computer simulations and experiments realised using the wheeled mobile robot Pioneer 2-DX

    Degree of atomicity in the chemical bonding: Why to return to the H2 molecule?

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    We analyze two-particle binding factors for the case of \ch{H2} molecule with the help of our original Exact Diagonalization \textit{Ab Intio} (EDABI) approach. Explicitly, we redefine the many-particle covalency and ionicity factors as a function of interatomic distance. Insufficiency of those basic characteristics is stressed and the concept of \textit{atomicity} is introduced and corresponds to the Mott and Hubbard criteria concerning the localization in many-particle systems. This additional characteristic introduces atomic ingredient into the essentially molecular states and thus eliminates a spurious behavior of the standard covalency factor with the increasing interatomic distance, as well as provides a physical reinterpretation of the chemical bond's nature

    Degree of atomicity in the chemical bonding : why return to the H2 molecule?

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    We analyze two-particle binding factors for the case of the H2 molecule with the help of our original exact diagonalization ab initio approach. Explicitly, we redefine the many-particle covalency and ionicity factors as a function of interatomic distance. Insufficiency of those basic characteristics is stressed, and the concept of atomicity is introduced and corresponds to the Mott and Hubbard criteria concerning the electron localization in many-particle systems. This additional characteristic introduces atomic ingredients into the essentially molecular states and thus eliminates a spurious behavior of the standard covalency factor with the increasing interatomic distance, and also provides a physical reinterpretation of the chemical bond’s nature

    Many-particle covalency, ionicity, and atomicity revisited for a few simple example molecules

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    We analyze two-particle binding factors of H2H_{2}, LiHLiH, and HEH+HEH^{+} molecules/ions with the help of our original exact diagonalization ab initio approach. The interelectronic correlations are taken into account rigorously within the second quantization scheme for restricted basis of renormalized single-particle wave functions, i.e., with their size readjusted in the correlated state. This allows us to determine the many-particle covalency and ionicity factors in a natural and intuitive manner in terms of the microscopic single-particle and interaction parameters, also determined within our method. We discuss the limitations of those basic characteristics and introduce the concept of atomicity, corresponding to the Mott and Hubbard criterion concerning localization threshold in many-particle systems. This addition introduces an atomic ingredient into the electron states and thus removes a spurious behavior of covalency with the increasing interatomic distance, as well as provides a more complete physical interpretation of bonding

    Toward complementary characterization of the chemical bond

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    A precise discussion of a single bond requires consideration of two-particle wave function for the particles involved. Here we define and determine rigorously the intrinsic covalency and connected characteristics of the canonical example of the H2 molecule. This is achieved by starting from an analytic form for the two-particle wave function for electrons forming the bond, in which we single out the atomic contribution (atomicity) in an unequivocal manner. The presence of the atomicity and ionicity factors complements the existing attributes of the bond. In this way, a gradual evolution of the molecular state to its two-atom correspondent is traced systematically with increasing interatomic distance. In effect, a direct relation to the onset of incipient Mott-Hubbard atomicity (Mottness) to the intrinsic covalency and ionicity is established. This goal is achieved formally by combining the single-particle wave function readjustment in the entangled state with a simultaneous determination of two-particle states in the particle (second quantization) representation

    Modeling transcription factor binding events to DNA using a random walker/jumper representation on a 1D/2D lattice with different affinity sites

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    Surviving in a diverse environment requires corresponding organism responses. At the cellular level, such adjustment relies on the transcription factors (TFs) which must rapidly find their target sequences amidst a vast amount of non-relevant sequences on DNA molecules. Whether these transcription factors locate their target sites through a 1D or 3D pathway is still a matter of speculation. It has been suggested that the optimum search time is when the protein equally shares its search time between 1D and 3D diffusions. In this paper, we study the above problem using a Monte Carlo simulation by considering a very simple physical model. A 1D strip, representing a DNA, with a number of low affinity sites, corresponding to non-target sites, and high affinity sites, corresponding to target sites, is considered and later extended to a 2D strip. We study the 1D and 3D exploration pathways, and combinations of the two modes by considering three different types of molecules: a walker that randomly walks along the strip with no dissociation; a jumper that represents dissociation and then re-association of a TF with the strip at later time at a distant site; and a hopper that is similar to the jumper but it dissociates and then re-associates at a faster rate than the jumper. We analyze the final probability distribution of molecules for each case and find that TFs can locate their targets fast enough even if they spend 15% of their search time diffusing freely in the solution. This indeed agrees with recent experimental results obtained by Elf et al. 2007 and is in contrast with theoretical expectation.Comment: 24 pages, 9 figure
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