1,870 research outputs found
Bose-Einstein Correlations and the Equation of State of Nuclear Matter
Within a relativistic hydrodynamic framework, we use four different equations
of state of nuclear matter to compare to experimental spectra from CERN/SPS
experiments NA44 and NA49. Freeze-out hypersurfaces and Bose-Einstein
correlation functions for identical pion pairs are discussed. We find that
two-pion Bose-Einstein interferometry measures the relationship between the
temperature and the energy density in the equation of state during the late
hadronic stage of the fireball expansion. Little sensitivity of the
light-hadron data to a quark-gluon plasma phase-transition is seen.Comment: 4 pages, including 4 figures. You can also download a PostScript file
of the manuscript from http://p2hp2.lanl.gov/people/schlei/eprint.htm
Stresses in Smooth Flows of Dense Granular Media
The form of the stress tensor is investigated in smooth, dense granular flows
which are generated in split-bottom shear geometries. We find that, within a
fluctuation fluidized spatial region, the form of the stress tensor is directly
dictated by the flow field: The stress and strain-rate tensors are co-linear.
The effective friction, defined as the ratio between shear and normal stresses
acting on a shearing plane, is found not to be constant but to vary throughout
the flowing zone. This variation can not be explained by inertial effects, but
appears to be set by the local geometry of the flow field. This is in agreement
with a recent prediction, but in contrast with most models for slow grain
flows, and points to there being a subtle mechanism that selects the flow
profiles.Comment: 5 pages, 4 figure
Non-affine response: jammed packings versus spring networks
We compare the elastic response of spring networks whose contact geometry is
derived from real packings of frictionless discs, to networks obtained by
randomly cutting bonds in a highly connected network derived from a
well-compressed packing. We find that the shear response of packing-derived
networks, and both the shear and compression response of randomly cut networks,
are all similar: the elastic moduli vanish linearly near jamming, and
distributions characterizing the local geometry of the response scale with
distance to jamming. Compression of packing-derived networks is exceptional:
the elastic modulus remains constant and the geometrical distributions do not
exhibit simple scaling. We conclude that the compression response of jammed
packings is anomalous, rather than the shear response.Comment: 6 pages, 6 figures, submitted to ep
Critical scaling in linear response of frictionless granular packings near jamming
We study the origin of the scaling behavior in frictionless granular media
above the jamming transition by analyzing their linear response. The response
to local forcing is non-self-averaging and fluctuates over a length scale that
diverges at the jamming transition. The response to global forcing becomes
increasingly non-affine near the jamming transition. This is due to the
proximity of floppy modes, the influence of which we characterize by the local
linear response. We show that the local response also governs the anomalous
scaling of elastic constants and contact number.Comment: 4 pages, 3 figures. v2: Added new results; removed part of
discussion; changed Fig.
Packing geometry and statistics of force networks in granular media
Article / Letter to editorLeiden Instituut Onderzoek Natuurkund
Critical jamming of frictional grains in the generalized isostaticity picture
While frictionless spheres at jamming are isostatic, frictional spheres at
jamming are not. As a result, frictional spheres near jamming do not
necessarily exhibit an excess of soft modes. However, a generalized form of
isostaticity can be introduced if fully mobilized contacts at the Coulomb
friction threshold are considered as slipping contacts. We show here that, in
this framework, the vibrational density of states (DOS) of frictional discs
exhibits a plateau when the generalized isostaticity line is approached. The
crossover frequency to elastic behavior scales linearly with the distance from
this line. Moreover, we show that the frictionless limit, which appears
singular when fully mobilized contacts are treated elastically, becomes smooth
when fully mobilized contacts are allowed to slip.Comment: 4 pages, 4 figures, submitted to PR
Sources and sinks separating domains of left- and right-traveling waves: Experiment versus amplitude equations
In many pattern forming systems that exhibit traveling waves, sources and
sinks occur which separate patches of oppositely traveling waves. We show that
simple qualitative features of their dynamics can be compared to predictions
from coupled amplitude equations. In heated wire convection experiments, we
find a discrepancy between the observed multiplicity of sources and theoretical
predictions. The expression for the observed motion of sinks is incompatible
with any amplitude equation description.Comment: 4 pages, RevTeX, 3 figur
Spectral, crystallographic, theoretical and antibacterial studies of palladium(II)/platinum(II) complexes with unsymmetric diphosphine ylides
The reaction of alpha-keto-stabilized diphosphine ylides [Ph2P(CH2)(n)PPh2C(H)C(O)C6H4-p-CN] (n = 1 (Y-1); n = 2 (Y-2)) with dibromo(1,5-cyclooctadiene) palladium(II)/platinum(II) complexes, [Pd/PtBr2(cod)], in equimolar ratio gave the new cyclometalated Pd(II) and Pt(II) complexes [Br2Pd(kappa(2)-Y-1)] (1), [Br2Pt(kappa(2)-Y-1)] (2), [Br2Pd(kappa(2)-Y-2)] (3) and [Br2Pt(kappa(2)-Y-2)] (4). These compounds were screened in a search for novel antibacterial agents and characterized successfully using Fourier transfer infrared and NMR (H-1, C-13 and P-31) spectroscopic methods. Also, the structures of complexes 1 and 2 were characterized using X-ray crystallography. The results showed that the P,C-chelated complexes 1 and 2 have structures consisting of five-membered rings, while 3 and 4 have six-membered rings, formed by coordination of the ligand through the phosphine group and the ylidic carbon atom to the metal centre. Also, a theoretical study of the structures of complexes 1-4 was conducted at the BP86/def2-SVP level of theory. The nature of metal-ligand bonds in the complexes was investigated using energy decomposition analyses (EDA) and extended transition state combined with natural orbitals for chemical valence analyses. The results of EDA confirmed that the main portions of Delta E-int, about 57-58%, in the complexes are allocated to Delta E-elstat
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