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Deformation of crosslinked semiflexible polymer networks
Networks of filamentous proteins play a crucial role in cell mechanics. These
cytoskeletal networks, together with various crosslinking and other associated
proteins largely determine the (visco)elastic response of cells. In this letter
we study a model system of crosslinked, stiff filaments in order to explore the
connection between the microstructure under strain and the macroscopic response
of cytoskeletal networks. We find two distinct regimes as a function primarily
of crosslink density and filament rigidity: one characterized by affine
deformation and one by non-affine deformation. We characterize the crossover
between these two.Comment: Typos fixed and some technical details clarified. To appear in Phys.
Rev. Let
State, capital and migrant labour in Zambezia, Mozambique : a study of the labour force of the Sena Sugar Estates Limited.
SIGLEAvailable from British Library Document Supply Centre- DSC:D33786/81 / BLDSC - British Library Document Supply CentreGBUnited Kingdo
Compressed intramolecular dispersion interactions.
The feasibility of the compression of localized virtual orbitals is explored in the context of intramolecular long-range dispersion interactions. Singular value decomposition (SVD) of coupled cluster doubles amplitudes associated with the dispersion interactions is analyzed for a number of long-chain systems, including saturated and unsaturated hydrocarbons and a silane chain. Further decomposition of the most important amplitudes obtained from these SVDs allows for the analysis of the dispersion-specific virtual orbitals that are naturally localized. Consistent with previous work on intermolecular dispersion interactions in dimers, it is found that three important geminals arise and account for the majority of dispersion interactions at the long range, even in the many body intramolecular case. Furthermore, it is shown that as few as three localized virtual orbitals per occupied orbital can be enough to capture all pairwise long-range dispersion interactions within a molecule
Electron-vibration interaction in transport through atomic gold wires
We calculate the effect of electron-vibration coupling on conduction through
atomic gold wires, which was measured in the experiments of Agra\"it et al.
[Phys. Rev. Lett. 88, 216803 (2002)]. The vibrational modes, the coupling
constants, and the inelastic transport are all calculated using a tight-binding
parametrization and the non-equilibrium Green function formalism. The
electron-vibration coupling gives rise to small drops in the conductance at
voltages corresponding to energies of some of the vibrational modes. We study
systematically how the position and height of these steps vary as a linear wire
is stretched and more atoms are added to it, and find a good agreement with the
experiments. We also consider two different types of geometries, which are
found to yield qualitatively similar results. In contrast to previous
calculations, we find that typically there are several close-lying drops due to
different longitudinal modes. In the experiments, only a single drop is usually
visible, but its width is too large to be accounted for by temperature.
Therefore, to explain the experimental results, we find it necessary to
introduce a finite broadening to the vibrational modes, which makes the
separate drops merge into a single, wide one. In addition, we predict how the
signatures of vibrational modes in the conductance curves differ between linear
and zigzag-type wires.Comment: 19 pages, 12 figure
A mean field description of jamming in non-cohesive frictionless particulate systems
A theory for kinetic arrest in isotropic systems of repulsive,
radially-interacting particles is presented that predicts exponents for the
scaling of various macroscopic quantities near the rigidity transition that are
in agreement with simulations, including the non-trivial shear exponent. Both
statics and dynamics are treated in a simplified, one-particle level
description, and coupled via the assumption that kinetic arrest occurs on the
boundary between mechanically stable and unstable regions of the static
parameter diagram. This suggests the arrested states observed in simulations
are at (or near) an elastic buckling transition. Some additional numerical
evidence to confirm the scaling of microscopic quantities is also provided.Comment: 9 pages, 3 figs; additional clarification of different elastic moduli
exponents, plus typo fix. To appear in PR
Volume-controlled buckling of thin elastic shells: Application to crusts formed on evaporating partially-wetted droplets
Motivated by the buckling of glassy crusts formed on evaporating droplets of
polymer and colloid solutions, we numerically model the deformation and
buckling of spherical elastic caps controlled by varying the volume between the
shell and the substrate. This volume constraint mimics the incompressibility of
the unevaporated solvent. Discontinuous buckling is found to occur for
sufficiently thin and/or large contact angle shells, and robustly takes the
form of a single circular region near the boundary that `snaps' to an inverted
shape, in contrast to externally pressurised shells. Scaling theory for shallow
shells is shown to well approximate the critical buckling volume, the
subsequent enlargement of the inverted region and the contact line force.Comment: 7 pages in J. Phys. Cond. Mat. spec; 4 figs (2 low-quality to reach
LANL's over-restrictive size limits; ask for high-detailed versions if
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SCOS2: ESA's new generation of mission control systems
The paper describes the next generation Spacecraft Control System infrastructure (SCOSII) which is being developed at the Operations Centre (ESOC) of the European Space Agency (ESA). The objectives of the new system and selected areas of the proposed hardware and software approach are described
Non-orthogonal configuration interaction with single substitutions for core-excited states: An extension to doublet radicals
In this paper, we present an open-shell extension of the non-orthogonal configuration interaction singles (NOCIS) method for the calculation of core-excited states, intended for peak assignment in XAS spectra of doublet radicals. This extension requires the consideration of additional configurations due to the singly occupied open-shell orbital, and the addition of essential orbital relaxation effects is found to provide a significant improvement on standard CIS, while maintaining the desirable properties of spin purity, variationality, and size consistency. We apply this method to the calculation of core excitations for several open-shell molecules and demonstrate that it performs competitively with other available methods, despite a lack of dynamic correlation. In particular, relative to CVS-ADC(2)-x, RMS error is reduced by a factor of 6 over usual orthogonal CIS and is comparable to time-dependent density functional theory with the best short-range corrected functionals
Fluctuation-dissipation relations in trap models
Trap models are intuitively appealing and often solvable models of glassy
dynamics. In particular, they have been used to study aging and the resulting
out-of-equilibrium fluctuation-dissipation relations between correlations and
response functions. In this note I show briefly that one such relation, first
given by Bouchaud and Dean, is valid for a general class of mean-field trap
models: it relies only on the way a perturbation affects the transition rates,
but is independent of the distribution of trap depths and the form of the
unperturbed transition rates, and holds for all observables that are
uncorrelated with the energy. The model with Glauber dynamics and an
exponential distribution of trap depths, as considered by Barrat and Mezard,
does not fall into this class if the perturbation is introduced in the standard
way by shifting all trap energies. I show that a similar relation between
response and correlation nevertheless holds for the out-of-equilibrium dynamics
at low temperatures. The results point to intriguing parallels between trap
models with energetic and entropic barriers.Comment: Extended introduction and discussion of relation to results of
cond-mat/0303445. 13 pages, 2 figures, IOP styl
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