Stability and photochemistry of ClO dimers formed at low temperature in the gas phase

The recent observations of elevated concentrations of the ClO radical in the austral spring over Antarctica have implicated catalytic destruction by chlorine in the large depletions seen in the total ozone column. One of the chemical theories consistent with an elevated concentration of the ClO is a cycle involving the formation of the ClO dimer through the association reaction: ClO + ClO = Cl2O2 and the photolysis of the dimer to give the active Cl species necessary for O3 depletion. Here, researchers report experimental studies designed to characterize the dimer of ClO formed by the association reaction at low temperatures. ClO was produced by static photolysis of several different precursor systems: Cl sub 2 + O sub 3; Cl sub 2 O sub 2; OClO + Cl sub 2 O spectroscopy in the U.V. region, which allowed the time dependence of Cl sub 2, Cl sub 2 O, ClO, OClO, O sub 3 and other absorbing molecules to be determined

Letter, Addressed to Hughey P. Long, 1935

A letter written by W.D. Hayman addressed to Hughey P. Long on August 8, 1935

Understanding the 21st Century Practical Implication of Chaplaincy Ministry in the City of Milwaukee, WI

This research project acknowledges that God’s command for Christian hospital chaplains is to serve humanity. Jesus calls a chaplain. He then forms, transforms, and conforms them to His image of oneness. Hospital chaplains like pastors are part of care ministries that extend to various work settings, Christian and secular. The hospital-certified chaplain, by definition, can support the whole workforce in the hospital, including their patients and the patient’s families. The hospital-certified chaplain is the main focus of this research. These hospital chaplains must be qualified, endorsed, licensed, certified, or ordained to be on the frontline in the community. A hospital-certified chaplain performs their duties within the context of their assigned institution. Some chaplains function as community pastors. Grace Christian Fellowship Church was a partner in this research project. As a result, the researchers attempted to increase their knowledge through presentations on the matter. The presentations were somewhat successful. The chaplaincy ministry was considered secular. Through research, the goal was to compare-and-contrast Christian hospital chaplains with pastors. Focusing on Christianity, the world between the two caregivers becomes smaller and more harmonious

Letter, W.D. Hayman to His Granddaughter, 1935

A letter written by W.D. Hayman to his grandaughter on August 9, 1935. This letter mentions another is being sent for Hughey P. Long

Experimental Demonstration of Focal Plane Array Beamforming in a Prototype Radiotelescope

Focal plane arrays are being developed to provide dishes with a wide field of view for both the next generation of radiotelescopes and to retrofit existing large radiotelescopes. We describe a prototype radiotelescope, comprising a two dish interferometer with real-time digital beamformer that was built to study focal plane array systems. Two beamformer weightings were applied to the system: A normalized conjugate match and the maximum sensitivity (G/T). Both incorporate the uncorrelated noise from the receiver chains and the latter includes correlated noise from spillover and coupling in the array. A black box approach is taken where the assembled system is considered and the only accessible data is that typically available from an operational radiotelescope. This approach is particularly suitable for complex active antennas where there is insufficient knowledge of the system for beamformer weights to be set a priori. It also allows adaptation to changes such as electronic gain drift, partial failures and alterations in the environment

Compound-specific isotope analysis of diesel fuels in a forensic investigation

Compound-specific isotope analysis (CSIA) offers great potential as a tool to provide chemical evidence in a forensic investigation. Many attempts to trace environmental oil spills were successful where isotopic values were particularly distinct. However, difficulties arise when a large data set is analyzed and the isotopic differences between samples are subtle. In the present study, discrimination of diesel oils involved in a diesel theft case was carried out to infer the relatedness of the samples to potential source samples. This discriminatory analysis used a suite of hydrocarbon diagnostic indices, alkanes, to generate carbon and hydrogen isotopic data of the compositions of the compounds which were then processed using multivariate statistical analyses to infer the relatedness of the data set. The results from this analysis were put into context by comparing the data with the δ13C and δ2H of alkanes in commercial diesel samples obtained from various locations in the South Island of New Zealand. Based on the isotopic character of the alkanes, it is suggested that diesel fuels involved in the diesel theft case were distinguishable. This manuscript shows that CSIA when used in tandem with multivariate statistical analysis provide a defensible means to differentiate and source-apportion qualitatively similar oils at the molecular level. This approach was able to overcome confounding challenges posed by the near single-point source of origin, i.e., the very subtle differences in isotopic values between the samples

Forensic differentiation of diesel fuels using hydrocarbon isotope fingerprints

Abstract Compound-specific isotope analysis (CSIA) is fast becoming an important tool to provide chemical evidence in a forensic investigation. Attempts to trace environmental oil spills were successful where isotopic values were particularly distinct. However, difficulties arise when a large dataset is analyzed and the isotopic differences between samples are subtle. Thus, this study intends to demonstrate any linkages between diesel fuels in a large number of datasets where subtlety in the isotopic values is accentuated by the near single-point source of origin. Diesel fuels were obtained from various locations in the South Island of New Zealand. Aliquots of these samples were diluted with n-pentane and subsequently analyzed with gas chromatography-isotope ratio mass spectrometry (GC-IRMS) for carbon and hydrogen isotope values. The data obtained were subjected to principal component analysis (PCA) and hierarchical clustering. A wide range of δ13C and δ2H values were determined for the ubiquitous alkane compounds (the greatest values being −4.5‰ and −40‰, respectively). Based on the isotopic character of the alkanes it is suggested that diesel fuels from different locations were distinguishable and that the key components in the differentiation are the δ2H values of the shorter chain-length alkanes. However, while the stable isotope measurements may provide information to classify a sample at a broad scale, much more detailed information is required on the temporal and spatial variability of diesel compositions. The subtle differences of the stable isotope values within the alkanes of different diesel fuels highlighted the power of CSIA as a means of differentiating petroleum products of different origins, even more so when two or more stable isotopes data are combined. This paper shows that CSIA when used in tandem with multivariate statistical methods can provide suitable tools for source apportionment of hydrocarbons by demonstrating a straightforward approach, thus eliminating lengthy analytical processes

Continuous cough monitoring using ambient sound recording during convalescence from a COPD exacerbation

Purpose Cough is common in chronic obstructive pulmonary disease (COPD) and is associated with frequent exacerbations and increased mortality. Cough increases during acute exacerbations (AE-COPD), representing a possible metric of clinical deterioration. Conventional cough monitors accurately report cough counts over short time periods. We describe a novel monitoring system which we used to record cough continuously for up to 45 days during AE-COPD convalescence. Methods This is a longitudinal, observational study of cough monitoring in AE-COPD patients discharged from a single teaching-hospital. Ambient sound was recorded from two sites in the domestic environment and analysed using novel cough classifier software. For comparison, the validated hybrid HACC/LCM cough monitoring system was used on days 1, 5, 20 and 45. Patients were asked to record symptoms daily using diaries. Results Cough monitoring data were available for 16 subjects with a total of 568 monitored days. Daily cough count fell significantly from mean±SEM 272.7±54.5 on day 1 to 110.9±26.3 on day 9 (p<0.01) before plateauing. The absolute cough count detected by the continuous monitoring system was significantly lower than detected by the hybrid HACC/LCM system but normalised counts strongly correlated (r=0.88, p<0.01) demonstrating an ability to detect trends. Objective cough count and subjective cough scores modestly correlated (r=0.46). Conclusions Cough frequency declines significantly following AE-COPD and the reducing trend can be detected using continuous ambient sound recording and novel cough classifier software. Objective measurement of cough frequency has the potential to enhance our ability to monitor the clinical state in patients with COPD

Maximally and non-maximally fast escaping points of transcendental entire functions

We partition the fast escaping set of a transcendental entire function into two subsets, the maximally fast escaping set and the non-maximally fast escaping set. These sets are shown to have strong dynamical properties. We show that the ntersection of the Julia set with the non-maximally fast escaping set is never empty. The proof uses a new covering result for annuli, which is of wider interest. It was shown by Rippon and Stallard that the fast escaping set has no bounded components. In contrast, by studying a function considered by Hardy, we give an example of a transcendental entire function for which the maximally and non-maximally fast escaping sets each have uncountably many singleton components