Friction Behavior of Engineering Polymers Treated by Atmospheric DBD Plasma

The frictional behavior of (PA6 E and PETP) engineering polymers commonly used in the industry were investigated implying 3D surface topography due to Dielectric Barrier Discharge (DBD) source, atmospheric cold plasma surface treatment and compared to the pristine surface results under the same test conditions. The 3D surface topography shows a decrease in the surface roughness after treatment and keeps good topographical stability with the function of time. The friction coefficient of treated samples were lower than the pristine one under “run-out” lubrication conditions in line with surface characterization results

Effects of atmospheric plasma treatment on adhesion and tribology of aromatic thermoplastic polymers

After cold plasma treatment of poly(ethylene terephthalate) and poly(ether-ether ketone) surfaces by dielectric barrier discharge (DBD) under atmospheric (air) conditions, variations in surface chemistry and morphology were investigated in relation with adhesion and tribological properties. According to XPS measurements, surface oxidation caused the formation of low molecular weight moieties of carboxylic acids. The latter resulted in more hydrophilic surfaces according to water contact angle measurements, with mainly a higher polar surface energy component. In parallel, the surface roughness of originally polished surfaces reduced due to flattening of local surface asperities after DBD. The DBD significantly improved the adhesive shear strength for different glue types in polymer/polymer and polymer/steel joints, while the best adhesion was observed for a two-component epoxy type adhesive. Under dry sliding conditions, the coefficients of friction were lower after DBD compared to pristine samples only under mild sliding conditions (v = 0.05 m/s; p < 1 MPa.m/s), while the higher normal loads caused an increase in coefficients of friction likely due to the higher contributions of surface deformation. Most interestingly, the lower coefficients of friction after DBD were observed under oil lubrication and after cleaning the sliding track (‘run-out’ condition), due to the better retention of oil at the sliding surface for plasma-treated polymers

Extruded and injection moulded virgin PA 6/6 as abrasion resistant material

Polyamide (PA6/6) is often used as a tribological pair in abrasion prevalent applications such as hinges and sliders. PA6/6 is frequently processed by injection moulding and extrusion process. It is known that these processes influence the polymers mechanical behaviour, but their influence on the polymers wear response has not been studied. Hence the present research attempts to study the influence of different manufacturing processes on tribological behaviour for PA6/6. Wear tests were performed on a pin abrading tester (DIN 50322). Abrasion resistance of both extruded and injection moulded PA6/6 were tested at different loads (20 and 35 N). Single-pass (nonoverlapping mode) and multipass testing (overlapping mode) were used to understand the influence of clogging of wear debris. It is evidenced that with increasing load the specific wear rate decreases; moreover, fine abrasives tend to reduce the wear rate. In multipass testing a transfer layer clogged on the counterface that acted as a protective agent and lowers wear rate. Poor mechanical strength of injection moulded polymers is apparently compensated by microstructural response for having a similar wear behaviour between extruded and injection moulded PA 6/6. Hence a proper balance between microstructural and mechanical characteristics is an absolute must in PA 6/6 for better wear performance

Energy and Exergy Analysis for Single Slope Passive Solar Still with Different Water Depth Located in Baghdad Center

In the present experimental work, the energy and exergy for single slope passive solar still with different basin water depths are experimentally investigated under the Baghdad climate condition. The analysis is performed using the governing equations formulated according to the first and second laws of thermodynamics. Compared to solar still with 1 cm water depth, the obtained results indicated that raising the water depth to 2 and 3 cm caused an appreciable drop in water basin temperature, and high levels of water basin reduction were about 4% and 9%, respectively, from 8:00 a.m. to 14:00 p.m., which significantly affects heat and mass transfer and ultimately hinders further water productivity. The maximum evaporation and convection heat transfer coefficients are found (32 W/m²·k) and (2.62 W/m²·k), respectively, while the maximum productivity of solar still is found to be 1468.84 mL/m² with 1 cm water depth. Conversely, stills with 2 and 3 cm water depth, exhibit an increment of the daily exergy efficiency after 14:00 p.m., this increment was the most for the still with 3 cm water depth. Therefore, we have concluded that the still with 1 cm of water depth attained the highest water productivity, while the still with 3 cm of water depth attained the best exergy efficiency with no additional costs

Burnout among surgeons before and during the SARS-CoV-2 pandemic: an international survey

Background: SARS-CoV-2 pandemic has had many significant impacts within the surgical realm, and surgeons have been obligated to reconsider almost every aspect of daily clinical practice. Methods: This is a cross-sectional study reported in compliance with the CHERRIES guidelines and conducted through an online platform from June 14th to July 15th, 2020. The primary outcome was the burden of burnout during the pandemic indicated by the validated Shirom-Melamed Burnout Measure. Results: Nine hundred fifty-four surgeons completed the survey. The median length of practice was 10&nbsp;years; 78.2% included were male with a median age of 37&nbsp;years old, 39.5% were consultants, 68.9% were general surgeons, and 55.7% were affiliated with an academic institution. Overall, there was a significant increase in the mean burnout score during the pandemic; longer years of practice and older age were significantly associated with less burnout. There were significant reductions in the median number of outpatient visits, operated cases, on-call hours, emergency visits, and research work, so, 48.2% of respondents felt that the training resources were insufficient. The majority (81.3%) of respondents reported that their hospitals were included in the management of COVID-19, 66.5% felt their roles had been minimized; 41% were asked to assist in non-surgical medical practices, and 37.6% of respondents were included in COVID-19 management. Conclusions: There was a significant burnout among trainees. Almost all aspects of clinical and research activities were affected with a significant reduction in the volume of research, outpatient clinic visits, surgical procedures, on-call hours, and emergency cases hindering the training. Trial registration: The study was registered on clicaltrials.gov "NCT04433286" on 16/06/2020

Tribological Behaviour of Polymers in Terms of Plasma Treatment: A Brief Review

A review to enrich the literature concerning the effect of various plasmas on the tribological behaviour of polymers and monitor the developments of plasma for the modification of polymer surfaces over recent decades using up-to-date data. A comparative study of plasmas was conducted to identify the most useful and efficient ones which facilitate optimal improvements with regard to the characterizations of polymer surfaces and tribological properties. The studies included in this review strongly suggest that (besides Plasma-Immersion Ion Implantation, PIII) atmospheric plasmas (dielectric barrier discharges, DBD) are an effective technique in terms of modifying the characterizations of polymer surfaces thereby enhancing the tribological behaviour of polymers under different operating conditions that extends the operating life of elements within the machine