Quantum Arrival and Dwell Times via Idealised Clocks

A number of approaches to the problem of defining arrival and dwell time probabilities in quantum theory make use of idealised models of clocks. An interesting question is the extent to which the probabilities obtained in this way are related to standard semiclassical results. In this paper we explore this question using a reasonably general clock model, solved using path integral methods. We find that in the weak coupling regime where the energy of the clock is much less than the energy of the particle it is measuring, the probability for the clock pointer can be expressed in terms of the probability current in the case of arrival times, and the dwell time operator in the case of dwell times, the expected semiclassical results. In the regime of strong system-clock coupling, we find that the arrival time probability is proportional to the kinetic energy density, consistent with an earlier model involving a complex potential. We argue that, properly normalized, this may be the generically expected result in this regime. We show that these conclusions are largely independent of the form of the clock Hamiltonian.Comment: 19 pages, 4 figures. Published versio

Materials genes of heterogeneous catalysis from clean experiments and artificial intelligence

The performance in heterogeneous catalysis is an example of a complex materials function, governed by an intricate interplay of several processes (e.g., the different surface chemical reactions, and the dynamic restructuring of the catalyst material at reaction conditions). Modeling the full catalytic progression via first-principles statistical mechanics is impractical, if not impossible. Instead, we show here how a tailored artificial-intelligence approach can be applied, even to a small number of materials, to model catalysis and determine the key descriptive parameters (“materials genes”) reflecting the processes that trigger, facilitate, or hinder catalyst performance. We start from a consistent experimental set of “clean data,” containing nine vanadium-based oxidation catalysts. These materials were synthesized, fully characterized, and tested according to standardized protocols. By applying the symbolic-regression SISSO approach, we identify correlations between the few most relevant materials properties and their reactivity. This approach highlights the underlying physicochemical processes, and accelerates catalyst design

“Divide and conquer”. Anti-racist and minority organising under austerity

This paper examines the effects of austerity on anti-racist and community organizing. We focus on three key shifts: changes to public funding, the push to entrepreneurialism and the mainstreaming of Equalities legislation. The paper contributes to critical understandings of the changing relationship between civil society and the state and the challenges this creates for working against racism. We highlight how austerity acts as an alibi to further diminish race as a policy concern. Organizations and activists are encouraged to act as entrepreneurs and confront each other as competitors, rather than allies in a political struggle. This leads to a very real sense that solidarities are being deliberately ruptured in order to “divide and conquer” and diminish collective organizing capacity. We illustrate how this is compounded by the cumulative affective consequences of austerity measures, often at considerable costs in terms of a broader collective agenda

The electronic structure of iridium oxide electrodes active in water splitting

Iridium oxide based electrodes are among the most promising candidates for electrocatalyzing the oxygen evolution reaction, making it imperative to understand their chemical/electronic structure. However, the complexity of iridium oxide's electronic structure makes it particularly difficult to experimentally determine the chemical state of the active surface species. To achieve an accurate understanding of the electronic structure of iridium oxide surfaces, we have combined synchrotron-based X-ray photoemission and absorption spectroscopies with ab initio calculations. Our investigation reveals a pre-edge feature in the O K-edge of highly catalytically active X-ray amorphous iridium oxides that we have identified as O 2p hole states forming in conjunction with IrIII. These electronic defects in the near-surface region of the anionic and cationic framework are likely critical for the enhanced activity of amorphous iridium oxides relative to their crystalline counterparts

Developing healthy communities Achieving a consensus

SIGLEAvailable from British Library Document Supply Centre-DSC:m02/32551 / BLDSC - British Library Document Supply CentreGBUnited Kingdo

Real Randomized Benchmarking

Randomized benchmarking provides a tool for obtaining precise quantitative estimates of the average error rate of a physical quantum channel. Here we define real randomized benchmarking, which enables a separate determination of the average error rate in the real and complex parts of the channel. This provides more fine-grained information about average error rates with approximately the same cost as the standard protocol. The protocol requires only averaging over the real Clifford group, a subgroup of the full complex Clifford group, and makes use of the fact that it forms an orthogonal 2-design. It therefore allows benchmarking of fault-tolerant gates for an encoding which does not contain the full Clifford group transversally. Furthermore, our results are especially useful when considering quantum computations on rebits (or real encodings of complex computations), in which case the real Clifford group now plays the role of the complex Clifford group when studying stabilizer circuits

Involving local people in community planning in Scotland

SIGLEAvailable from British Library Document Supply Centre-DSC:m02/36960 / BLDSC - British Library Document Supply CentreGBUnited Kingdo