Material Morphology and energy barriers to electrical ageing

A distribution of the parameters representing activation energy of the ageing process within the Dissado-Montanari-Mazzanti (DMM) lifetime model has been shown to model experimental lifetime distributions of PET films well. The results imply small differences in the local environments of the moieties involved in the ageing process. Very small changes in the minimum activation energy values have a pronounced effect on the resultant lifetimes of polymer specimens. Changes in the distributions of activation energies with field and temperature can be explained by assuming the ageing process to be one whereby polymer segments on lamella surfaces crystallise to create free volume within the polymer

Improved diamond coring bits developed for dry and chip-flush drilling

Two rotary diamond bit designs, one operating with a chip-flushing fluid, the second including auger section to remove drilled chips, enhance usefulness of tool for exploratory and industrial core-drilling of hard, abrasive mineral deposits and structural masonry

Microgravity vibration isolation: An optimal control law for the one-dimensional case

Certain experiments contemplated for space platforms must be isolated from the accelerations of the platforms. An optimal active control is developed for microgravity vibration isolation, using constant state feedback gains (identical to those obtained from the Linear Quadratic Regulator (LQR) approach) along with constant feedforward (preview) gains. The quadratic cost function for this control algorithm effectively weights external accelerations of the platform disturbances by a factor proportional to (1/omega)(exp 4). Low frequency accelerations (less than 50 Hz) are attenuated by greater than two orders of magnitude. The control relies on the absolute position and velocity feedback of the experiment and the absolute position and velocity feedforward of the platform, and generally derives the stability robustness characteristics guaranteed by the LQR approach to optimality. The method as derived is extendable to the case in which only the relative positions and velocities and the absolute accelerations of the experiment and space platform are available

Effects of classification context on categorization in natural categories

The patterns of classification of borderline instances of eight common taxonomic categories were examined under three different instructional conditions to test two predictions: first, that lack of a specified context contributes to vagueness in categorization, and second, that altering the purpose of classification can lead to greater or lesser dependence on similarity in classification. The instructional conditions contrasted purely pragmatic with more technical/quasi-legal contexts as purposes for classification, and these were compared with a no-context control. The measures of category vagueness were between-subjects disagreement and within-subjects consistency, and the measures of similarity based categorization were category breadth and the correlation of instance categorization probability with mean rated typicality, independently measured in a neutral context. Contrary to predictions, none of the measures of vagueness, reliability, category breadth, or correlation with typicality were generally affected by the instructional setting as a function of pragmatic versus technical purposes. Only one subcondition, in which a situational context was implied in addition to a purposive context, produced a significant change in categorization. Further experiments demonstrated that the effect of context was not increased when participants talked their way through the task, and that a technical context did not elicit more all-or-none categorization than did a pragmatic context. These findings place an important boundary condition on the effects of instructional context on conceptual categorization

Modeling Concept Combinations in a Quantum-theoretic Framework

We present modeling for conceptual combinations which uses the mathematical formalism of quantum theory. Our model faithfully describes a large amount of experimental data collected by different scholars on concept conjunctions and disjunctions. Furthermore, our approach sheds a new light on long standing drawbacks connected with vagueness, or fuzziness, of concepts, and puts forward a completely novel possible solution to the 'combination problem' in concept theory. Additionally, we introduce an explanation for the occurrence of quantum structures in the mechanisms and dynamics of concepts and, more generally, in cognitive and decision processes, according to which human thought is a well structured superposition of a 'logical thought' and a 'conceptual thought', and the latter usually prevails over the former, at variance with some widespread beliefsComment: 5 pages. arXiv admin note: substantial text overlap with arXiv:1311.605

Model networks of end‐linked polydimethylsiloxane chains. II. Viscoelastic losses

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/71107/2/JCPSA6-68-4-2010-1.pd

Parkinson\u27s Disease in Louisiana, 1999-2012: Based on Hospital Primary Discharge Diagnoses, Incidence, and Risk in Relation to Local Agricultural Crops, Pesticides, and Aquifer Recharge

The two major causes of Parkinson\u27s disease (PD) are genetic susceptibility and exposure to agricultural pesticides. Access to 23,224 individuals\u27 hospital primary discharge diagnoses of PD allowed the mapping of cases against known crop distributions and pesticides. Our main objective was to map PD risks (cases per 10,000 people) against crops and their pesticides. The ZIP Code address locations, and the 2000 and 2010 census data, were used to map the risks of PD throughout Louisiana and in relation to United States Department of Agriculture (USDA)-recorded crops. The introduction of glyphosate-resistant crops appears to have initiated the PD disappearance from northeastern parishes on the west bank of the Mississippi river. Rice and sugar cane are seemingly unassociated with PD, as is the Mississippi itself, except for Jefferson and St. Charles Parishes, which are essentially urban or industrial. The present major PD-affected areas are associated with commercial forests, woodlands, and pastures, and thus with certain arbor-pastoral pesticides, 2,4-D, chlorpyrifos, and paraquat. Human populations at maximum risk are those living in areas of moderate and high aquifer-recharge potential. The levels of estimated pesticide exposure in these recharge areas we were able to access were of variable use, but significant amounts of 2,4-D were being used