Rapid pyrolysis of cellulose

Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 1981.MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCEIncludes bibliographical references.by Mohammad R. Hajaligol.Ph.D

Products from the high temperature pyrolysis of RDF at slow and rapid heating rates

The high-temperature pyrolysis behaviour of a sample of refuse derived fuel (RDF) as a model of municipal solid waste (MSW) was investigated in a horizontal tubular reactor between 700 and 900 °C, at varying heating rates, and at an extended vapour residence time. Experiments were designed to evaluate the influence of process conditions on gas yields as well as gas and oil compositions. Pyrolysis of RDF at 800 °C and at rapid heating rate resulted in the gas yield with the highest CV of 24.8 MJ m-3 while pyrolysis to 900 °C at the rapid heating rate generated the highest gas yield but with a lower CV of 21.3 MJ m-3. A comparison of the effect of heating rates on oil products revealed that the oil from slow pyrolysis, contained higher yields of more oxygenates, alkanes (C8-C39) and alkenes (C8-C20), while the oil from rapid pyrolysis contained more aromatics, possibly due to the promotion of Diels-Alder-type reactions

Kinetics of coal pyrolysis

This report contains results of a coordinated, multi-laboratory investigation of coal devolatilization. Data is reported pertaining to the devolatilization for bituminous coals over three orders of magnitude in apparent heating rate (100 to 100,000 + {degree}C/sec), over two orders of magnitude in particle size (20 to 700 microns), final particle temperatures from 400 to 1600{degree}C, heat transfer modes ranging from convection to radiative, ambient pressure ranging from near vacuum to one atmosphere pressure. The heat transfer characteristics of the reactors are reported in detail. It is assumed the experimental results are to form the basis of a devolatilization data base. Empirical rate expressions are developed for each phase of devolatilization which, when coupled to an awareness of the heat transfer rate potential of a particular devolatilization reactor, indicate the kinetics emphasized by a particular system reactor plus coal sample. The analysis indicates the particular phase of devolatilization that will be emphasized by a particular reactor type and, thereby, the kinetic expressions appropriate to that devolatilization system. Engineering rate expressions are developed from the empirical rate expressions in the context of a fundamental understanding of coal devolatilization developed in the course of the investigation. 164 refs., 223 figs., 44 tabs

Application of Nanoparticle Iron Oxide in Cigarette for Simultaneous CO and NO Removal in the Mainstream Smoke

Based on the unique temperature and oxygen profiles in a burning cigarette, a novel approach is proposed in this paper to use a single oxidant/catalyst in the cigarette filler for simultaneous removal of carbon monoxide (CO) and nitric oxide (NO) in mainstream smoke. A nanoparticle iron oxide is identified as a very active material for this application due to its multiple functions as a CO catalyst, as a CO oxidant, and in its reduced forms as a NO catalyst. The multiple functions of the nanoparticle iron oxide are characterized in a flow tube reactor and the working mechanisms of these multiple functions for CO and NO removal in a burning cigarette are explained. The effect of smoke condensate on the catalyst are examined and discussed. The advantage of in situ generation of the catalyst during the cigarette burning process is illustrated. The test results of nanoparticle iron oxide for CO and NO removal in cigarettes are presented