Rotational stabilization and destabilization of an optical cavity

We investigate the effects of rotation about the axis of an astigmatic two-mirror cavity on its optical properties. This simple geometry is the first example of an optical system that can be destabilized and, more surprisingly, stabilized by rotation. As such, it has some similarity with both the Paul trap and the gyroscope. We illustrate the effects of rotational (de)stabilization of a cavity in terms of the spatial structure and orbital angular momentum of its modes.Comment: 5 pages, 3 figures. Accepted for publication in Physical Review

L'-band AGPM vector vortex coronagraph's first light on LBTI/LMIRCam

We present the first observations obtained with the L'-band AGPM vortex coronagraph recently installed on LBTI/LMIRCam. The AGPM (Annular Groove Phase Mask) is a vector vortex coronagraph made from diamond subwavelength gratings. It is designed to improve the sensitivity and dynamic range of high-resolution imaging at very small inner working angles, down to 0.09 arcseconds in the case of LBTI/LMIRCam in the L' band. During the first hours on sky, we observed the young A5V star HR\,8799 with the goal to demonstrate the AGPM performance and assess its relevance for the ongoing LBTI planet survey (LEECH). Preliminary analyses of the data reveal the four known planets clearly at high SNR and provide unprecedented sensitivity limits in the inner planetary system (down to the diffraction limit of 0.09 arcseconds).Comment: 9 pages, 4 figures, SPIE proceeding

Polypeptide-grafted macroporous polyHIPE by surface-initiated N-Carboxyanhydride (NCA) polymerization as a platform for bioconjugation

A new class of functional macroporous monoliths from polymerized high internal phase emulsion (polyHIPE) with tunable surface functional groups was developed by direct polypeptide surface grafting. In the first step, amino-functional polyHIPEs were obtained by the addition of 4-vinylbenzyl or 4-vinylbenzylphthalimide to the styrenic emulsion and thermal radical polymerization. The obtained monoliths present the expected open-cell morphology and a high surface area. The incorporated amino group was successfully utilized to initiate the ring-opening polymer- ization of benzyl-L-glutamate N-carboxyanhydride (BLG NCA) and benzyloxycarbonyl-L-lysine (Lys(Z)) NCA, which resulted in a dense homogeneous coating of polypeptides throughout the internal polyHIPE surfaces as confirmed by SEM and FTIR analysis. The amount of polypeptide grafted to the polyHIPE surfaces could be modulated by varying the initial ratio of amino acid NCA to amino-functional polyHIPE. Subsequent removal of the polypeptide protecting groups yielded highly functional polyHIPE-g-poly(glutamic acid) and polyHIPE-g- poly(lysine). Both types of polypeptide-grafted monoliths responded to pH by changes in their hydrohilicity. The possibility to use the high density of function (−COOH or −NH2) for secondary reaction was demonstrated by the successful bioconjugation of enhanced green fluorescent protein (eGFP) and fluorescein isocyanate (FITC) on the polymer 3D-scaffold surface. The amount of eGFP and FITC conjugated to the polypeptide-grafted polyHIPE was significantly higher than to the amino- functional polyHIPE, signifying the advantage of polypeptide grafting to achieve highly functional polyHIPEs

Quantum decoherence of phonons in Bose–Einstein condensates

We apply modern techniques from quantum optics and quantum information science to Bose–Einstein condensates(BECs)in order to study, for the first time, the quantum decoherence of phonons of isolated BECs. In the last few years, major advances in the manipulation and control of phonons have highlighted their potential as carriers of quantum information in quantum technologies, particularly in quantum processing and quantum communication. Although most of these studies have focused on trapped ion and crystalline systems, another promising system that has remained relatively unexplored is BECs. The potential benefits in using this system have been emphasized recently with proposals of relativistic quantum devices that exploit quantum states of phonons in BECs to achieve, in principle, superior performance over standard non-relativistic devices. Quantum decoherence is often the limiting factor in the practical realization of quantum technologies, but here we show that quantum decoherence of phonons is not expected to heavily constrain the performance of these proposed relativistic quantum devices

The Giant Radio Array for Neutrino Detection (GRAND) Project

The GRAND project aims to detect ultra-high-energy neutrinos, cosmic rays and gamma rays, with an array of 200,000 radio antennas over 200,000km$^2$, split into ∼20 sub-arrays of ∼10,000km$^2$ deployed worldwide. The strategy of GRAND is to detect air showers above 10$^{17}$eV that are induced by the interaction of ultra-high-energy particles in the atmosphere or in the Earth crust, through its associated coherent radio-emission in the 50−200MHz range. In its final configuration, GRAND plans to reach a neutrino-sensitivity of ∼10$^{−10}$GeV cm$^{−2}$s$^{−1}$sr$^{−1}$ above 5×10$^{17}$eV combined with a sub-degree angular resolution. GRANDProto300, the 300-antenna pathfinder array, is planned to start data-taking in 2021. It aims at demonstrating autonomous radio detection of inclined air-showers, and study cosmic rays around the transition between Galactic and extra-Galactic sources. We present preliminary designs and simulation results, plans for the ongoing, staged approach to construction, and the rich research program made possible by the proposed sensitivity and angular resolution

The Giant Radio Array for Neutrino Detection (GRAND) Project

The GRAND project aims to detect ultra-high-energy neutrinos, cosmic rays and gamma rays, with an array of 200,000 radio antennas over 200,000km$^2$, split into ∼20 sub-arrays of ∼10,000km$^2$ deployed worldwide. The strategy of GRAND is to detect air showers above 10$^{17}$\,eV that are induced by the interaction of ultra-high-energy particles in the atmosphere or in the Earth crust, through its associated coherent radio-emission in the 50−200\,MHz range. In its final configuration, GRAND plans to reach a neutrino-sensitivity of ∼10$^{−10}$GeVcm$^{−2}$s$^{−1}$sr$^{−1}$ above 5×10$^{17}$\,eV combined with a sub-degree angular resolution. GRANDProto300, the 300-antenna pathfinder array, is planned to start data-taking in 2021. It aims at demonstrating autonomous radio detection of inclined air-showers, and study cosmic rays around the transition between Galactic and extra-Galactic sources. We present preliminary designs and simulation results, plans for the ongoing, staged approach to construction, and the rich research program made possible by the proposed sensitivity and angular resolution

Strengthening the morphological study of informal settlements

Methods of articulating the morphological structure of slums can have considerable potential in better planning for site-specific design or policy responses for these areas in the contemporary city. Although urban morphology traditionally studies landscapes as stratified residues with distinct divisions between lot and boundary, built and unbuilt, the authors find these definitions insufficient to address the complexity of slum morphology. Through this article, the authors’ identify that morphological analysis of informal settlements needs to be sensitive to the dynamics and the absence (or blurring) of physical boundaries. By analyzing the spatial impact of social, economic, and political factors, situational and site factors, building typologies, and configurations of circulation space, an attempt to articulate the morphological structure of slums is made. Aiming to overcome the current polarization in the literature between the formal and informal city, this article adds to the ongoing research on the study of challenges within contemporary cities, by providing new methodologies for studying the morphology of slum urbanization and shaping planning practice

Self-trigger radio prototype array for GRAND

The GRANDProto300 (GP300) array is a pathfinder for the Giant Radio Array for Neutrino Detection (GRAND) project. The deployment of the array, consisting of 300 antennas, will start in 2021 in a radio-quiet area of ~200 km2 near Lenghu (~3000 m a.s.l.) in China. Serving as a test bench, the GP300 array is expected to pioneer techniques of autonomous radio detection including identification and reconstruction of nearly horizontal cosmic-ray (CR) air showers. In addition, the GP300 array is at a privileged position to study the transition between Galactic and extragalactic origins of cosmic rays, due to its large effective area and the precise measurements of both energy and mass composition for CRs with energies ranging from 30 PeV to 1 EeV. Using the GP300 array we will also investigate the potential sensitivity for radio transients such as Giant Radio Pulses and Fast Radio Bursts in the 50-200 MHz range

Confinement increases the lifetimes of hydroxyapatite precursors

The mineral component of bone is a carbonated, nonstoichiometric hydroxyapatite (calcium phosphate) that forms in nanometer confinement within collagen fibrils, the principal organic constituent of bone. We here employ a model system to study the effects of confinement on hydroxyapatite precipitation from solution under physiological conditions. In common with earlier studies of calcium carbonate and calcium sulfate precipitation, we find that confinement significantly prolongs the lifetime of metastable phases, here amorphous calcium phosphate (ACP) and octacalcium phosphate (OCP). The effect occurs at surprisingly large separations of up to 1 μm, and at 0.2 μm the lifetime of ACP is extended by at least an order of magnitude. The soluble additive poly(aspartic acid), which in bulk stabilizes ACP, appears to act synergistically with confinement to give a greatly enhanced stability of ACP. The reason for the extended lifetime appears to be different from that found with CaCO3 and CaSO4, and underscores both the variety of mechanisms whereby confinement affects the growth and transformation of solid phases, and the necessity to study a wide range of crystalline systems to build a full understanding of confinement effects. We suggest that in the case of ACP and OCP the extended lifetime of these metastable phases is chiefly due to a slower transport of ions between a dissolving metastable phase, and the more stable, growing phase. These results highlight the potential importance of confinement on biomineralization processes

Versatile Synthesis of Stable, Functional Polypeptides via Reaction with Epoxides

Methodology was developed for efficient alkylation of methionine residues using epoxides as a general strategy to introduce a wide range of functional groups onto polypeptides. Use of a spacer between epoxide and functional groups further allowed addition of sterically demanding functionalities. Contrary to other methods to alkylate methionine residues, epoxide alkylations allow the reactions to be conducted in wet protic media and give sulfonium products that are stable against dealkylation. These functionalizations are notable since they are chemoselective, utilize stable and readily available epoxides, and allow facile incorporation of an unprecedented range of functional groups onto simple polypeptides using stable linkages