Existence of negative differential thermal conductance in one-dimensional diffusive thermal transport

We show that in a finite one-dimensional (1D) system with diffusive thermal transport described by the Fourier's law, negative differential thermal conductance (NDTC) cannot occur when the temperature at one end is fixed. We demonstrate that NDTC in this case requires the presence of junction(s) with temperature dependent thermal contact resistance (TCR). We derive a necessary and sufficient condition for the existence of NDTC in terms of the properties of the TCR for systems with a single junction. We show that under certain circumstances we even could have infinite (negative or positive) differential thermal conductance in the presence of the TCR. Our predictions provide theoretical basis for constructing NDTC-based devices, such as thermal amplifiers, oscillators and logic devices

A method to extract pure Raman spectrum of epitaxial graphene on SiC

A method is proposed to extract pure Raman spectrum of epitaxial graphene on SiC by using a Non-negative Matrix Factorization. It overcomes problems of negative spectral intensity and poorly resolved spectra resulting from a simple subtraction of a SiC background from the experimental data. We also show that the method is similar to deconvolution, for spectra composed of multiple sub- micrometer areas, with the advantage that no prior information on the impulse response functions is needed. We have used this property to characterize the Raman laser beam. The method capability in efficient data smoothing is also demonstrated.Comment: 3 figures, regular pape

Dietary flavonoid intake and weight maintenance: three prospective cohorts of 124,086 US men and women followed for up to 24 years

Objective: To examine whether dietary intake of specific flavonoid sub-classes is associated with weight change over time, including flavonols, flavones, flavanones, flavan-3-ols, anthocyanins, and flavonoid polymers. Design: Three prospective cohort studies. Setting: Health professionals in the United States. Participants: 124,086 men and women participating in the Health Professionals Follow-up Study (HPFS), Nurses’ Health Study (NHS), and Nurses’ Health Study II (NHS II). Main outcome measure: Self-reported change in weight over multiple 4-year time intervals between 1986 and 2011. Results: Increased consumption of most flavonoid sub-classes, including flavonols, flavan-3-ols, anthocyanins, and flavonoid polymers was inversely associated with weight change over 4-year time intervals, after adjustment for simultaneous changes in other lifestyle factors including other aspects of diet, smoking status, and physical activity. In the pooled results, the greatest magnitude of association was observed for anthocyanins (-0.22 lbs, 95% CI -0.30 to -0.15 lbs per additional SD/day, 10 mg), flavonoid polymers (-0.18 lbs, 95% CI -0.28 to -0.08 lbs per additional SD/day, 138 mg), and flavonols (-0.16 lbs, 95% CI -0.26 to -0.06 lbs per additional SD/day, 7 mg). After additional adjustment for fiber intake associations remained significant for anthocyanins, proanthocyanidins, and total flavonoid polymers but were attenuated and no longer statistically significant for other sub-classes. Conclusions: Higher intake of foods rich in flavonols, flavan-3-ols, anthocyanins, and flavonoid polymers, may contribute to weight maintenance in adulthood, and may help to refine dietary recommendations for the prevention of obesity and its potential sequelae

Detecting the Most Distant (z>7) Objects with ALMA

Detecting and studying objects at the highest redshifts, out to the end of Cosmic Reionization at z>7, is clearly a key science goal of ALMA. ALMA will in principle be able to detect objects in this redshift range both from high-J (J>7) CO transitions and emission from ionized carbon, [CII], which is one of the main cooling lines of the ISM. ALMA will even be able to resolve this emission for individual targets, which will be one of the few ways to determine dynamical masses for systems in the Epoch of Reionization. We discuss some of the current problems regarding the detection and characterization of objects at high redshifts and how ALMA will eliminate most (but not all) of them.Comment: to appear in Astrophysics and Space Science, "Science with ALMA: a new era for Astrophysics", ed. R. Bachille

Earth-Abundant Tin Sulfide-Based Photocathodes for Solar Hydrogen Production.

Tin-based chalcogenide semiconductors, though attractive materials for photovoltaics, have to date exhibited poor performance and stability for photoelectrochemical applications. Here, a novel strategy is reported to improve performance and stability of tin monosulfide (SnS) nanoplatelet thin films for H2 production in acidic media without any use of sacrificial reagent. P-type SnS nanoplatelet films are coated with the n-CdS buffer layer and the TiO2 passivation layer to form type II heterojunction photocathodes. These photocathodes with subsequent deposition of Pt nanoparticles generate a photovoltage of 300 mV and a photocurrent density of 2.4 mA cm-2 at 0 V versus reversible hydrogen electrode (RHE) for water splitting under simulated visible-light illumination (λ > 500 nm, Pin = 80 mW cm-2). The incident photon-to-current efficiency at 0 V versus RHE for H2 production reach a maximum of 12.7% at 575 nm with internal quantum efficiency of 13.8%. The faradaic efficiency for hydrogen evolution remains close to unity after 6000 s of illumination, confirming the robustness of the heterojunction for solar H2 production

The molecular gas content of z > 6.5 Lyman-alpha emitters

We present results from a sensitive search for CO J=1-0 line emission in two z> 6.5 Lyman-alpha emitters (LAEs) with the Green Bank Telescope. CO J=1-0 emission was not detected from either object. For HCM 6A, at z ~ 6.56, the lensing magnification factor of ~4.5 implies that the CO non-detection yields stringent constraints on the CO J=1-0 line luminosity and molecular gas mass of the LAE, L'(CO) < 6.1x10^9 x (dV/300)^(1/2) K km/s pc^2 and M(H_2) < 4.9x10^9 x (dV/300)^(1/2) x (X(CO)/0.8) Msun. These are the strongest limits obtained so far for a z >~ 6 galaxy. For IOK-1, the constraints are somewhat less sensitive, L'(CO) < 2.3x10^10 x (dV/300)^(1/2) K km/s pc^2 and M(H_2) < 1.9x10^10 x (dV/300)^(1/2) x (X(CO)/0.8) Msun. The non-detection of CO J=1-0 emission in HCM~6A, whose high estimated star formation rate, dust extinction, and lensing magnification make it one of the best high-z LAEs for such a search, implies that typical z >~ 6 LAEs are likely to have significantly lower CO line luminosities than massive sub-mm galaxies and hyperluminous infrared quasars at similar redshifts, due to either a significantly lower molecular gas content or a higher CO-to-H_2 conversion factor.Comment: Accepted for publication in ApJ Letter

The non-Markovian stochastic Schrodinger equation for open systems

We present the non-Markovian generalization of the widely used stochastic Schrodinger equation. Our result allows to describe open quantum systems in terms of stochastic state vectors rather than density operators, without approximation. Moreover, it unifies two recent independent attempts towards a stochastic description of non-Markovian open systems, based on path integrals on the one hand and coherent states on the other. The latter approach utilizes the analytical properties of coherent states and enables a microscopic interpretation of the stochastic states. The alternative first approach is based on the general description of open systems using path integrals as originated by Feynman and Vernon.Comment: 9 pages, RevTe

Human Fecal Metabolism of Soyasaponin I

The metabolism of soyasaponin I (3-O-[alpha-L-rhamnopyranosyl-beta-D-galactopyranosyl-beta-D-glucuronopyranosyl]olean-12-ene-3beta,22beta,24-triol) by human fecal microorganisms was investigated. Fresh feces were collected from 15 healthy women and incubated anaerobically with 10 mmol soyasaponin I/g feces at 37 degrees C for 48 h. The disappearance of soyasaponin I in this in vitro fermentation system displayed apparent first-order rate loss kinetics. Two distinct soyasaponin I degradation phenotypes were observed among the subjects: rapid soyasaponin degraders with a rate constant k = 0.24 +/- 0.04 h(-)(1) and slow degraders with a k = 0.07 +/- 0.02 h(-)(1). There were no significant differences in the body mass index, fecal moisture, gut transit time, and soy consumption frequency between the two soyasaponin degradation phenotypes. Two primary gut microbial metabolites of soyasaponin I were identified as soyasaponin III (3-O-[beta-D-galactopyranosyl-beta-D-glucuronopyranosyl]olean-12-ene-3beta,22beta,24-triol) and soyasapogenol B (olean-12-ene-3beta,22beta,24-triol) by NMR and electrospray ionized mass spectroscopy. Soyasaponin III appeared within the first 24 h and disappeared by 48 h. Soyasapogenol B seemed to be the final metabolic product during the 48 h anaerobic incubation. These results indicate that dietary soyasaponins can be metabolized by human gut microorganisms. The sugar moieties of soyasaponins seem to be hydrolyzed sequentially to yield smaller and more hydrophobic metabolites

Airborne Molecular Contamination: Recent Developments in the Understanding and Minimization for Advanced Semiconductor Device Manufacturing

This review paper focuses on the recent knowledge about airborne molecular contamination (AMC) and its impacts on 300-mm wafer fabrication processes. The adverse impacts on process materials by both organic and inorganic micro-contaminants, and evidence of cross-contamination between processed wafers and the mainstream wafer handling tools, are two areas of discussion for the study. The review also aims to re-frame the industrial guideline for AMC from chemical-based to risk-based approach, which substantiates the potential impacts of individual families of AMCs that have been well-documented. This approach resonates well with the new AMC classification method recently proposed by the International Roadmap of Devices and Systems (IRDS), building on new knowledge of AMC emerged over time with the advances of analytical and testing capability. The review also brings forth the impact of moisture, the mere presence of which can compromise the integrity of device structures. However, moisture is especially detrimental in the presence of other inorganic ions to trigger unwanted reactions with surface materials. Methods developed to minimize the micro-contaminants and moisture during wafer handling and storage are also reviewed