The relation of the freezing procedure and the composition of the mixture to the physical and crystalline structure of ice cream

Publication authorized June 28, 1934."The data from this bulletin were taken from a paper submitted by the junior author in partial fulfillment of the requirements for the degree of Master of Arts in the Graduate School of the University of Missouri"--P. [3].Includes bibliographical references (page 20)

Composite Metal-hydrogen Electrodes for Metal-Hydrogen Batteries

The purpose of this project is to develop and conduct a feasibility study of metallic thin films (multilayered and alloy composition) produced by advanced sputtering techniques for use as anodes in Ni-metal hydrogen batteries. The anodes could be incorporated in thin film solid state Ni-metal hydrogen batteries that would be deposited as distinct anode, electrolyte and cathode layers in thin film devices. The materials could also be incorporated in secondary consumer batteries (i.e. type AF(4/3 or 4/5)) which use electrodes in the form of tapes. The project was based on pioneering studies of hydrogen uptake by ultra-thin Pd-capped metal-hydrogen ratios exceeding and fast hydrogen charging and Nb films, these studies suggested that materials with those of commercially available metal hydride materials discharging kinetics could be produced. The project initially concentrated on gas phase and electrochemical studies of Pd-capped niobium films in laboratory-scale NiMH cells. This extended the pioneering work to the wet electrochemical environment of NiMH batteries and exploited advanced synchrotron radiation techniques not available during the earlier work to conduct in-situ studies of such materials during hydrogen charging and discharging. Although batteries with fast charging kinetics and hydrogen-metal ratios approaching unity could be fabricated, it was found that oxidation, cracking and corrosion in aqueous solutions made pure Nb films-and multiiayers poor candidates for battery application. The project emphasis shifted to alloy films based on known elemental materials used for NiMH batteries. Although commercial NiMH anode materials contain many metals, it was found that 0.24 µm thick sputtered Zr-Ni films cycled at least 50 times with charging efficiencies exceeding 95% and [H]/[M] ratios of 0.7-1.0. Multilayered or thicker Zr-Ni films could be candidates for a thin film NiMH battery that may have practical applications as an integrated power source for modern electronic devices

Remnant Fermi surface in the presence of an underlying instability in layered 1T-TaS_2

We report high resolution angle-scanned photoemission and Fermi surface (FS) mapping experiments on the layered transition-metal dichalcogenide 1T-TaS_2 in the quasi commensurate (QC) and the commensurate (C) charge-density-wave (CDW) phase. Instead of a nesting induced partially removed FS in the CDW phase we find a pseudogap over large portions of the FS. This remnant FS exhibits the symmetry of the one-particle normal state FS even when passing from the QC-phase to the C-phase. Possibly, this Mott localization induced transition represents the underlying instability responsible for the pseudogapped FS

Revised Stellar Properties of Kepler Targets for the Quarter 1-16 Transit Detection Run

We present revised properties for 196,468 stars observed by the NASA Kepler Mission and used in the analysis of Quarter 1-16 (Q1-Q16) data to detect and characterize transiting exoplanets. The catalog is based on a compilation of literature values for atmospheric properties (temperature, surface gravity, and metallicity) derived from different observational techniques (photometry, spectroscopy, asteroseismology, and exoplanet transits), which were then homogeneously fitted to a grid of Dartmouth stellar isochrones. We use broadband photometry and asteroseismology to characterize 11,532 Kepler targets which were previously unclassified in the Kepler Input Catalog (KIC). We report the detection of oscillations in 2,762 of these targets, classifying them as giant stars and increasing the number of known oscillating giant stars observed by Kepler by ~20% to a total of ~15,500 stars. Typical uncertainties in derived radii and masses are ~40% and ~20%, respectively, for stars with photometric constraints only, and 5-15% and ~10% for stars based on spectroscopy and/or asteroseismology, although these uncertainties vary strongly with spectral type and luminosity class. A comparison with the Q1-Q12 catalog shows a systematic decrease in radii for M dwarfs, while radii for K dwarfs decrease or increase depending on the Q1-Q12 provenance (KIC or Yonsei-Yale isochrones). Radii of F-G dwarfs are on average unchanged, with the exception of newly identified giants. The Q1-Q16 star properties catalog is a first step towards an improved characterization of all Kepler targets to support planet occurrence studies.Comment: 20 pages, 14 figures, 5 tables; accepted for publication in ApJS; electronic versions of Tables 4 and 5 are available as ancillary files (see sidebar on the right), and an interactive version of Table 5 is available at the NASA Exoplanet Archive (http://exoplanetarchive.ipac.caltech.edu/

An Investigation of Equivalence Principle Violations Using Solar Neutrino Oscillations in a Constant Gravitational Potential

Neutrino oscillations induced by a flavor-dependent violation of the Einstein Equivalence Principle (VEP) have been recently considered as a suitable explanation of the solar electron-neutrino deficiency. Unlike the MSW oscillation mechanism, the VEP mechanism is dependent on a coupling to the local background gravitational potential $\Phi$. We investigate the differences which arise by considering three-flavor VEP neutrinos oscillating against fixed background potentials, and against the radially-dependent solar potential. This can help determine the sensitivity of the gravitationally-induced oscillations to both constancy and size (order of magnitude) of $\Phi$. In particular, we consider the potential of the local superculster, $|\Phi|=3\times 10^{-5}$, in light of recent work suggesting that the varying solar potential has no effect on the oscillations. The possibility for arbitrarily large background potentials in different cosmologies is discussed, and the effects of one such potential ($\Phi = 10^{-3}$) are considered.Comment: 12pp, LaTeX; 12 figures (bitmapped postscript); Submitted to Phys Rev

Superconductivity in Cu_xTiSe_2

Charge density waves (CDWs) are periodic modulations of the conduction electron density in solids. They are collective states that arise from intrinsic instabilities often present in low dimensional electronic systems. The layered dichalcogenides are the most well-studied examples, with TiSe_2 one of the first CDW-bearing materials known. The competition between CDW and superconducting collective electronic states at low temperatures has long been held and explored, and yet no chemical system has been previously reported where finely controlled chemical tuning allows this competition to be studied in detail. Here we report how, upon controlled intercalation of TiSe_2 with Cu to yield Cu_xTiSe_2, the CDW transition is continuously suppressed, and a new superconducting state emerges near x = 0.04, with a maximum T_c of 4.15 K found at x = 0.08. Cu_xTiSe_2 thus provides the first opportunity to study the CDW to Superconductivity transition in detail through an easily-controllable chemical parameter, and will provide new insights into the behavior of correlated electron systems.Comment: Accepted to Nature Physic

Data and Safety Monitoring of COVID-19 Vaccine Clinical Trials

To speed the development of vaccines against SARS-CoV-2, the United States Federal Government has funded multiple phase 3 trials of candidate vaccines. A single 11-member data and safety monitoring board (DSMB) monitors all government-funded trials to ensure coordinated oversight, promote harmonized designs, and allow shared insights related to safety across trials. DSMB reviews encompass 3 domains: (1) the conduct of trials, including overall and subgroup accrual and data quality and completeness; (2) safety, including individual events of concern and comparisons by randomized group; and (3) interim analyses of efficacy when event-driven milestones are met. Challenges have included the scale and pace of the trials, the frequency of safety events related to the combined enrollment of over 100 000 participants, many of whom are older adults or have comorbid conditions that place them at independent risk of serious health events, and the politicized environment in which the trials have taken place

Specific heat and magnetic measurements in Nd0.5Sr0.5MnO3, Nd0.5Ca0.5MnO3 and Ho0.5Ca0.5MnO3 samples

We studied the magnetization as a function of temperature and magnetic field in the compounds Nd0.5Sr0.5MnO3, Nd0.5Ca0.5MnO3 and Ho0.5Ca0.5MnO3. It allowed us to identify the ferromagnetic, antiferromagnetic and charge ordering phases in each case. The intrinsic magnetic moments of Nd3+ and Ho3+ ions experienced a short range order at low temperatures. We also did specific heat measurements with applied magnetic fields between 0 and 9 T and temperatures between 2 and 300 K in all three samples. Close to the charge ordering and ferromagnetic transition temperatures the specific heat curves showed peaks superposed to the characteristic response of the lattice oscillations. Below 10 K the specific heat measurements evidenced a Schottky-like anomaly for all samples. However, we could not successfully fit the curves to either a two level nor a distribution of two-level Schottky anomaly. Our results indicated that the peak temperature of the Schottky anomaly was higher in the compounds with narrower conduction band.Comment: submitted to PR

Rotational and Cyclical Variability in gamma Cassiopeia

We report results of a nine-year monitoring effort on the unusual classical Be with a robotic ground-based (APT) B,V-filtered telescope as well as simultaneous observations in 2004 November with this instrument and the RXTE (X-ray) telescope. Our observations disclosed no correlated optical response to the rapid X-ray flares in this star, nor did the star show any sustained flux changes during the course of either of the two monitored nights in either wavelength regime. Our optical light curves reveal that gamma Cas undergoes \~3%-amplitude cycles with lengths of 60--90 days. Over the nine days we monitored the star with the RXTE, the X-ray flux varied in phase with its optical cycle and with an amplitude predicted from correlated optical/X-ray data from an earlier paper. The amplitudes of the V magnitude cycles are 30--40% larger than the B amplitudes, suggesting the seat of the cycles is circumstellar. The cycle lengths constantly change and can damp or grow on timescales as short as 13 days. We have also discovered a coherent period of 1.21581 +/-0.00002 days in all our data, which is consistent only with rotation. The full amplitude of this variation is 0.0060 in both filters. The derived waveform, somewhat surprisingly, is almost sawtooth in shape. This variation probably originates on the star's surface. This circumstance hints at the existence of a strong magnetic field with a complex topology and an associated heterogeneous surface composition.Comment: 31 pages, 7 figures. Submitted to The Astrophysical Journa

X-ray and Optical Variations in the Classical Be Star gamma Cas

gamma Cas (B0.5e) is known to be a unique X-ray source because ot its moderate L_x, hard X-ray spectrum, and light curve punctuated by ubiquitous flares and slow undulations. Its X-ray peculiarities have led to a controversy concerning their origin: either from wind infall onto a putative degenerate companion, as for typical Be/X-ray binaries, or from the Be star per se. Recent progress has been made to address this: (1) the discovery that gamma Cas is an eccentric binary system (P = 203.59 d) with unknown secondary type, (2) the accumulation of RXTE data at 9 epochs in 1996-2000, and (3) the collation of robotic telescope B, V-band photometric observations over 4 seasons. The latter show a 3%, cyclical flux variation with cycle lengths 55-93 days. We find that X-ray fluxes at all 9 epochs show random variations with orbital phase. This contradicts the binary accretion model, which predicts a substantial modulation. However,these fluxes correlate well with the cyclical optical variations. Also, the 6 flux measurements in 2000 closely track the interpolated optical variations between the 2000 and 2001 observing seasons. Since the optical variations represent a far greater energy than that emitted as X-rays, the optical variability cannot arise from X-ray reprocessing. However, the strong correlation between the two suggests that they are driven by a common mechanism. We propose that this mechanism is a cyclical magnetic dynamo excited by a Balbus-Hawley instability located within the inner part of the circumstellar disk. In our model, variations in the field strength directly produce the changes in the magnetically related X-ray activity. Turbulence associated with the dynamo results in changes to the density distribution within the disk and creates the observed optical variations.Comment: 30 dbl-spaced pages, Latex, plus 11 figures. Accepted by Ap