Correction of diffraction effects in confocal raman microspectroscopy

A mathematical approach developed to correct depth profiles of wet-chemically modified polymer films obtained by confocal Raman microscopy is presented which takes into account scattered contributions originated from a diffraction-limited laser focal volume. It is demonstrated that the problem can be described using a linear Fredholm integral equation of the first kind which correlates apparent and true Raman intensities with the depth resolution curve of the instrument. The calculations of the corrected depth profiles show that considerable differences between apparent and corrected depth profiles exist at the surface, especially when profiles with strong concentration gradients are dealt with or an instrument with poor depth resolution is used. Degrees of modification at the surface obtained by calculation of the corrected depth profiles are compared with those measured by FTIR-ATR and show an excellent concordance.</p

Prediking as pastorale uitnodiging tot deelname: ‘n Kultureel-linguistiese beskouing

Preaching as a pastoral invitation to participate: A cultural-linguistic viewAs a practical theologian, the author of this article adopts a social-constructionist approach, namely Lindbeck&rsquo;s cultural-linguistic method, which focuses on narratives and grammar as vehicles of identity, and individuals&rsquo; choice to be part of a group by accepting the group&rsquo;s traditions. This article discusses preaching as a pastoral action by examining the specific role that preaching has to fulfil in order to be pastoral within a cultural-linguistic model. The role of narratives, the Bible, the context of the group and individual, and the tradition of the group are also discussed. The article concludes by citing two specific homiletic proposals for narrative pastoral preaching.Keywords: narrative preaching; pastoral; culturallinguistic; intratextually played; narrative identityThis article is in Afrikaan

A whole farm model for quantifying total greenhouse gas emissions on South African dairy farms

This paper presents a model to quantify total greenhouse gas (GHG) emissions from dairy farms. The model, which is based on a whole farm management approach, accounts for the variability that occurs in GHG emissions among farm production and management practices. The variation is accommodated in six dairy farm management systems (FMS), which broadly include typical dairy production systems in South Africa. These are pasture-based with high or low stocking rates, total mixed ration with high or low stocking rates, and partial mixed ration with high or low stocking rates. Three variations of functional units that were used to evaluate the environmental impacts of various FMS are defined as per animal unit = kg CO2-eq head-1 yr-1; per unit of farm area = kg CO2-eq ha-1 yr-1, and per unit of product = kg CO2-eq kg FPCM-1, where FPCM is fat and protein corrected milk. The results show a range of GHG emissions in CO2-eq among the FMS with various methodological approaches because of the large impact from different emission factors, which vary between accounting methods. The more detailed equations were recommended to effectively improve environmental impacts. These more detailed non-linear equations tended to predict more biologically realistic emissions when compared with the linear equations in which over or under-predictions of GHG were observed. The most prominent drivers for GHG emissions across all FMS were from enteric methane (CH4) and nitrous oxide (N2O) from soil management. Rankings among FMS varied according to output methodology and functional units. GHG emissions expressed per animal or per unit area differ greatly from those expressed from a given level of product. In conclusion, the accounting methodologies that are described in this paper to predict GHG emissions of animal-related origin performed sufficiently across all FMS, and could be applied to quantify the carbon footprint of dairy production systems in South Africa.Keywords: Carbon dioxide equivalents, dairy production, methane, nitrous oxid

Detailed Spectral Modeling of a 3-D Pulsating Reverse Detonation Model: Too Much Nickel

We calculate detailed NLTE synthetic spectra of a Pulsating Reverse Detonation (PRD) model, a novel explosion mechanism for Type Ia supernovae. While the hydro models are calculated in 3-D, the spectra use an angle averaged hydro model and thus some of the 3-D details are lost, but the overall average should be a good representation of the average observed spectra. We study the model at 3 epochs: maximum light, seven days prior to maximum light, and 5 days after maximum light. At maximum the defining Si II feature is prominent, but there is also a prominent C II feature, not usually observed in normal SNe Ia near maximum. We compare to the early spectrum of SN 2006D which did show a prominent C II feature, but the fit to the observations is not compelling. Finally we compare to the post-maximum UV+optical spectrum of SN 1992A. With the broad spectral coverage it is clear that the iron-peak elements on the outside of the model push too much flux to the red and thus the particular PRD realizations studied would be intrinsically far redder than observed SNe Ia. We briefly discuss variations that could improve future PRD models.Comment: 15 pages, 4 figures, submitted to Ap

An experimental comparison of three typical Mars entry body shapes on the basis of total equilibrium shock-layer radiation

Comparative study of total equilibrium shock layer radiation for three potential Mars entry body shape

Does export dependency hurt economic development? Empirical evidence from Singapore

A rapid export growth in East Asia was once identified as a source of the sustainable economic development that the region enjoyed. However, the current global recession has turned exports from an economic virtue to a vice. There is a growing awareness that a heavy reliance on exports has caused a serious economic downturn in the region. The present paper chooses Singapore as a case study to examine the relationship between the origin of the East Asian Miracle (i.e. export dependency) and the economic growth. For this purpose, the study employs a causality test developed by Toda and Yamamoto. The empirical findings indicate that despite a negative long-run relationship between export dependency and economic growth, Singapore's heavy reliance on exports does not seem to have produced negative effects on the nation's economic growth. This is because the increase in export dependency was an effect, and not a cause, of the country's output expansion.

Aerothermodynamic radiation studies

We have built and made operational a 6 in. electric arc driven shock tube which alloys us to study the non-equilibrium radiation and kinetics of low pressure (0.1 to 1 torr) gases processed by 6 to 12 km/s shock waves. The diagnostic system allows simultaneous monitoring of shock radiation temporal histories by a bank of up to six radiometers, and spectral histories with two optical multi-channel analyzers. A data set of eight shots was assembled, comprising shocks in N2 and air at pressures between 0.1 and 1 torr and velocities of 6 to 12 km/s. Spectrally resolved data was taken in both the non-equilibrium and equilibrium shock regions on all shots. The present data appear to be the first spectrally resolved shock radiation measurements in N2 performed at 12 km/s. The data base was partially analyzed with salient features identified

Application of beam deconvolution technique to power spectrum estimation for CMB measurements

We present two novel methods for the estimation of the angular power spectrum of cosmic microwave background (CMB) anisotropies. We assume an absolute CMB experiment with arbitrary asymmetric beams and arbitrary sky coverage. The methods differ from the earlier ones in that the power spectrum is estimated directly from the time-ordered data, without first compressing the data into a sky map, and they take into account the effect of asymmetric beams. In particular, they correct the beam-induced leakage from temperature to polarization. The methods are applicable to a case where part of the sky has been masked out to remove foreground contamination, leaving a pure CMB signal, but incomplete sky coverage. The first method (deconvolution quadratic maximum likelihood) is derived as the optimal quadratic estimator, which simultaneously yields an unbiased spectrum estimate and minimizes its variance. We successfully apply it to multipoles up to l = 200. The second method is derived as a weak-signal approximation from the first one. It yields an unbiased estimate for the full multipole range, but relaxes the requirement of minimal variance. We validate the methods with simulations for the 70 GHz channel of Planck surveyor, and demonstrate that we are able to correct the beam effects in the TT, EE, BB and TE spectra up to multipole l = 1500. Together, the two methods cover the complete multipole range with no gap in between.Peer reviewe

Similarity and contrasts between thermodynamic properties at the critical point of liquid alkali metals and of electron-hole droplets

The recent experimental study by means of time-resolved luminescence measurements of an electron-hole liquid (EHL) in diamond by Shimano et al. [Phys. Rev. Lett. 88 (2002) 057404] prompts us to compare and contrast critical temperature T_c and critical density n_c relations in liquid alkali metals with those in electron-hole liquids. The conclusion drawn is that these systems have similarities with regard to critical properties. In both cases the critical temperature is related to the cube root of the critical density. The existence of this relation is traced to Coulomb interactions and to systematic trends in the dielectric constant of the electron-hole systems. Finally a brief comparison between the alkalis and EHLs of the critical values for the compressibility ratio Z_c is also given

Quasilinear Drift Of Cosmic Rays In Weak Turbulent Electromagnetic Fields

A general quasilinear transport parameter for particle drift in arbitrary turbulence geometry is presented. The new drift coefficient is solely characterized by a nonresonant term and is evaluated for slab and two-dimensional turbulence geometry. The calculations presented here demonstrate that fluctuating electric fields are a key quantity for understanding quasilinear particle drift in slab geometry. It is shown that particle drift does not exist in unpolarized and purely magnetic slab fluctuations. This is in stark contrast to previous models, which are restricted to slab geometry and the field line random walk limit. The evaluation of the general transport parameter for two-dimensional turbulence geometry, presented here for the first time for dynamical magnetic turbulence, results in a drift coefficient valid for a magnetic power spectrum and turbulence decay rate varying arbitrarily in wavenumber. For a two-component, slab/two-dimensional turbulence model, numerical calculations are presented. The new quasilinear drift, induced by the magnetic perturbations, is compared with a standard drift expression related to the curvature and gradient of an unperturbed heliospheric background magnetic field. The considerations presented here offer a solid ground and natural explanation for the hitherto puzzling observation that drift models often describe observations much better when drift effects are reduced.Comment: 23 pages, 6 figures, accepted for publication in Ap