Vibrationally Induced Two-Level Systems in Single-Molecule Junctions

Single-molecule junctions are found to show anomalous spikes in dI/dV spectra. The position in energy of the spikes are related to local vibration mode energies. A model of vibrationally induced two-level systems reproduces the data very well. This mechanism is expected to be quite general for single-molecule junctions. It acts as an intrinsic amplification mechanism for local vibration mode features and may be exploited as a new spectroscopic tool.Comment: 4 pages, 4 figure

Evidence for an Additional Heat Source in the Warm Ionized Medium of Galaxies

Spatial variations of the [S II]/H-Alpha and [N II]/H-Alpha line intensity ratios observed in the gaseous halo of the Milky Way and other galaxies are inconsistent with pure photoionization models. They appear to require a supplemental heating mechanism that increases the electron temperature at low densities n_e. This would imply that in addition to photoionization, which has a heating rate per unit volume proportional to n_e^2, there is another source of heat with a rate per unit volume proportional to a lower power of n_e. One possible mechanism is the dissipation of interstellar plasma turbulence, which according to Minter & Spangler (1997) heats the ionized interstellar medium in the Milky Way at a rate ~ 1x10^-25 n_e ergs cm^-3 s^-1. If such a source were present, it would dominate over photoionization heating in regions where n_e < 0.1 cm^-3, producing the observed increases in the [S II]/H-Alpha and [N II]/H-Alpha intensity ratios at large distances from the galactic midplane, as well as accounting for the constancy of [S II]/[N II], which is not explained by pure photoionization. Other supplemental heating sources, such as magnetic reconnection, cosmic rays, or photoelectric emission from small grains, could also account for these observations, provided they supply to the warm ionized medium ~ 10^-5 ergs s^-1 per cm^2 of Galactic disk.Comment: 10 pages, 1 figur

Hierarchical Temporal Representation in Linear Reservoir Computing

Recently, studies on deep Reservoir Computing (RC) highlighted the role of layering in deep recurrent neural networks (RNNs). In this paper, the use of linear recurrent units allows us to bring more evidence on the intrinsic hierarchical temporal representation in deep RNNs through frequency analysis applied to the state signals. The potentiality of our approach is assessed on the class of Multiple Superimposed Oscillator tasks. Furthermore, our investigation provides useful insights to open a discussion on the main aspects that characterize the deep learning framework in the temporal domain.Comment: This is a pre-print of the paper submitted to the 27th Italian Workshop on Neural Networks, WIRN 201

Observation of electronic and atomic shell effects in gold nanowires

The formation of gold nanowires in vacuum at room temperature reveals a periodic spectrum of exceptionally stable diameters. This is identified as shell structure similar to that which was recently discovered for alkali metals at low temperatures. The gold nanowires present two competing `magic' series of stable diameters, one governed by electronic structure and the other by the atomic packing.Comment: 4 pages, 4 figure

Sexual selection and population divergence III : interspecific and intraspecific variation in mating signals

Funding: Orthopterists' Society, Natural Environment Research Council (Grant Number(s): NE/G00949X/1, NE/G014906/1, NE/L011255/1), ARC (Grant Number(s): DP180101708).A major challenge for studying the role of sexual selection in divergence and speciation is understanding the relative influence of different sexually selected signals on those processes in both intra‐ and interspecific contexts. Different signals may be more or less susceptible to co‐option for species identification depending on the balance of sexual and ecological selection acting upon them. To examine this, we tested three predictions to explain geographic variation in long‐ versus short‐range sexual signals across a 3,500 + km transect of two related Australian field cricket species (Teleogryllus spp.): (a) selection for species recognition, (b) environmental adaptation and (c) stochastic divergence. We measured male calling song and male and female cuticular hydrocarbons (CHCs) in offspring derived from wild populations, reared under common garden conditions. Song clearly differentiated the species, and no hybrids were observed suggesting that hybridization is rare or absent. Spatial variation in song was not predicted by geography, genetics or climatic factors in either species. In contrast, CHC divergence was strongly associated with an environmental gradient supporting the idea that the climatic environment selects more directly upon these chemical signals. In light of recently advocated models of diversification via ecological selection on secondary sexual traits, the different environmental associations we found for song and CHCs suggest that the impact of ecological selection on population divergence, and how that influences speciation, might be different for acoustic versus chemical signals.Publisher PDFPeer reviewe

DOTATOC: A powerful new tool for receptor-mediated radionuclide therapy

This study presents the first successful use of a peptidic vector, DOTATOC, labelled with the β-emitting radioisotope yttrium-90, for the treatment of a patient with somatostatin receptor-positive abdominal metastases of a neuroendocrine carcinoma of unknown localization. Tumour response and symptomatic relief were achieved. In addition, the new substance DOTA-TOC was labelled with the diagnostic chemical analogue indium-111 and studied in three patients with histopathologically verified neuroendocrine abdominal tumours for its diagnostic sensitivity and compared with the commercially available OctreoScan. In all patients the kidney-to-tumour uptake ratio (in counts per pixel) was on average 1.9-fold lower with111In-DOTATOC than with OctreoScan. DOTATOC could be a potential new diagnostic and therapeutic agent in the management of neuroendocrine tumour

Energy influx from an rf plasma to a substrate during plasma processing

The energy influx delivered by an rf plasma to a metal substrate has been studied by a calorimetric method with a thermal probe. By changing the substrate voltage, the influence of the kinetic energy of the charge carriers to the thermal power could be determined. The measured energy influx for an argon plasma can be explained mainly by ions, electrons, and their recombination. In the case of an oxygen plasma, where the energy influx is under comparable conditions about 50% higher, also other transfer mechanisms such as surface-aided atom association and relaxation of rovibrational states have to be taken into consideration